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221.
Propane fuel cells using H(3)PO(4)-doped polybenzimidazole polymer membranes produce low and unsustainable current densities at temperatures up to 250 degrees C under anhydrous conditions. Stable intermediate species blocked the surface of noble metal anode catalysts, and the intermediate species could not react further into desorbable final products. In contrast, when water was introduced by light humidification (S(r) 0.08%) of the propane stream, sustainable and higher current densities were achieved. Water participated in the reaction sequence to form surface-bound hydrocarbon and then oxygen-containing intermediates and thereby generated CO and CO(2) as the only carbon-containing products. 相似文献
222.
This paper presents a new simple and sensitive method for the micro-determination of protein containing SH– and –S–S– groups based on the single sweep polarographic wave of an electroactive derivative. In 0.04molL–1 Na3PO4 and 0.2% ascorbic acid solution, protein is heated in a boiling water bath for 15min, the reaction product giving a sensitive reduction wave at –0.70V (vs. SCE). The wave height is linearly proportional to the concentration of protein. The calibration curves of bovine serum albumin (BSA), human serum albumin (HSA), ovalbumin (OVA) and lysozyme (Lyso) are constructed under the optimal conditions. For BSA and HSA, the linear ranges and detection limits are 0.05–24mgL–1 and 0.02mgL–1, respectively. The method has been applied to the determination of protein in human serum samples with satisfactory results. The mechanism of the polarographic wave was also studied, and the results show that S2– ion is released from the protein molecule during the derivatization reaction, the wave being attributed to the reduction of HgS. 相似文献
223.
The reaction of scandium(III) with o-chlorophenylfluorone (o-CIPF) in the presence of cetyltrimethylammonium bromide (CTMAB) has been studied. In an acetate buffer at pH 4.4, a red-purple complex is obtained, with maximum absorption at 569 nm and a molar absorptivity of 1.31 x 10(5)1.mole(-1).cm(-1). The composition of the complex is found to be 1:2:2 Sc-o-CIPF-CTMAB. Beer's law is obeyed over the range 0-12 mug/25 ml scandium. The proposed method has been used for determination of trace scandium in tungsten ores after its prior separation by solvent extraction. 相似文献
224.
Study on the Phase Diagram of CsCl-CeCl3-HCl(11%)-H2O System and the Properties of the Compounds 总被引:2,自引:0,他引:2
The equilibrium solubility of CsCl-CeCl3-HCl(11%)-H2O qua-ternary system at 25℃ has been determined by the physicchemical analysis method ,and the phase diagram was plotted, Two new double salts 3CsCl.CeCl3.3H2O and CsCl.CeCl3.4H2O obtained from the complicated system were identified and characterized by XRD,TG-DTA ,DSC,UV and fluorescence spectroscopy, Studies on the fluorescence excitation and emission show that 3CsCl.CeCl3.3H2O and CsCl.CeCl3.4H2O have upconversion luminescence of infrared-visible range,and the upconversion emission intensity increases with the increase of ratio of CeCl3 in CsCl. 相似文献
225.
催化动力学光度法测定痕量锆 总被引:4,自引:0,他引:4
研究了在弱酸性介质中,锆(Ⅳ)催化过氧化氢氧化铬蓝黑R这一新的指示反应及其动力学条件,建立了一种高灵敏、高选择性测定痕量锆的新方法,方法检出限为3.74×10-11g/mL,线性范围0~1.1μg/25mLZr(Ⅳ).用于合金钢中痕量锆的测定,结果满意. 相似文献
226.
Zn—TppS4极谱络合物吸附波的研究:中草药天麻,川芎,当归中锌的测定 总被引:1,自引:0,他引:1
锌是人体必需的微量元素之一。它具有重要的生理功能和营养作用,是合成脱氧核糖核酸(DNA),核糖核酸(RNA)和蛋白质必需的金属离子。锌是DNA,RNA聚合酶等80多种酶的组成成分及激剂,直接影响细胞代谢,免疫过程,细胞分裂和再生。最近美国有人提出缺 相似文献
227.
Quan Xiang WE Xia LIU Yan Ping SHI 《中国化学快报》2005,16(11):1477-1480
A novel dimeric eremophilane, ligulolide B, was isolated from the alcoholic extract of the whole plant of Ligularia virgaurea spp. oligocephala. The structure was elucidated by various spectroscopic methods including intensive 2D NMR techniques (^1H-^1H COSY, gHMQC, gHMBC and ^1H-^1H NOESY) and HR-ESI-MS. 相似文献
228.
229.
A Novel Dihydroflavone from the Roots of Uvaria Macrophylla 总被引:1,自引:0,他引:1
A new dihydroflavone (1), named macrophyllol A, was isolated from the roots of Uvaria macrophylla. Its structure was elucidated on the basis of spectroscopic evidence. 相似文献
230.