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261.
Sinenxan A, a taxoid isolated from callus tissue cultures of Taxus yunnanensis was converted into 13-oxo-7,9-dideoxy-2-debenzoyl-2-acetyl-baccatin IV and 7,9-dideoxy-2-debenzoyl-4-deacetyl-baccatin IV, a key framework of 1,7,9-trideoxypaclitaxel. Several special steps in this transformation are worthy of note: (1) deoxygenation by treatment with hypophosphorous acid at C-14 position; (2) a highly regioselective O-deacetylation of taxanes at C-5 position; and (3) stereoselective reduction of the 13-carbonyl group by transannular assistance from the C-4-hydroxyl. 相似文献
262.
Qiang Li Pingfan Wu Yongge Wei Hongyou Guo 《Journal of organometallic chemistry》2006,691(6):1223-1228
An organic-inorganic hybrid compound, (Bu4N)2[Mo6O18(NAr)] (Ar = p-BrC6H4) has been synthesized via the DCC dehydrating protocol of the reaction of [α-Mo8O26]4− with 4-bromoaniline hydrochloride in anhydrous acetonitrile, which has been characterized by UV-Vis spectra, 1H NMR and single crystal X-ray diffraction study. By comparing the UV-Vis spectra, which were used to monitor the reaction, the optimum preparative condition for this compound was also determined. This compound crystallizes in the monoclinic space group P21/n, which is featured in a terminal para-bromophenylimido group linked to an Mo atom of a hexamolybdate cluster by a Mo-N triply bond. In addition, there are π-π dimerization of the neighboring cluster anions though the parallel aromatic rings in their crystals. 相似文献
263.
A new isocoumarin, 3-acetyl-3,4-dihydro-5,6-dimethoxy-1H-2-benzopyran-1-one, was isolated from the cortex of Phellodendron chinense schneid. The structure was determined on the basis of spectroscopic evidences. 相似文献
264.
Tao Liu Yong-Gang Wei Qi-Hua Wu Qing-Xiang Guo 《Research on Chemical Intermediates》2005,31(9):833-844
A series of adamantanamine-(OCH2CH2)n-phenothiazine (n = 0, 1, 2, 3) electron donors was synthesized. Photoinduced electron transfer was observed in the supramolecular complex
of the phenothiazine derivatives with p-nitrobenzoyl-β-cyclodextrin (NBCD) through binding of the adamantyl group by the NBCD cavity, which is stabilized clearly via hydrophobic interactions in aqueous solution. Detailed Stern–Volmer constants were measured and they were partitioned into
dynamic Stern–Volmer quenching constants and static binding constants. The results revealed an efficient electron transfer
process inside the supramolecular systems compared to that controlled by diffusion. This observation also indicates that the
chain length will influence the electron transfer efficiency of a supramolecular donor–acceptor system. 相似文献
265.
[reaction: see text] Treatment of 1,4-dilithio-1,3-butadiyne (1) with dichalcogenides RSSR or RSeSeR affords dithio- and diseleno-1,3-butadiynes (2, 3), perthio- and perseleno-[3]-cumulenes (4, 5), perthio- and perseleno-1,3-butadienes (6, 7), and/or perthio- and perseleno-but-1-ene-3-ynes (8, 9). The products can be controlled by stoichiometry and temperature, by the presence or absence of oxygen, and by choice of the "R" group. By X-ray crystallography, hexa(methylthio)-1,3-butadiene is highly twisted, with a torsion angle [Phi(CCCC)] of 84.7 degrees and an elongated C(2)-C(3) distance of 1.484(3) A. 相似文献
266.
偏钛酸型锂离子交换剂固相合成反应动力学 总被引:1,自引:1,他引:1
偏钛酸型锂离子交换剂固相合成反应动力学钟辉*郭灵虹(成都理工学院应用化学系成都610059)(四川联合大学分析测试中心成都)关键词偏钛酸锂,离子交换剂,合成,固相反应动力学1997-08-25收稿,1997-12-10修回四川省应用基础研究基金资助项... 相似文献
267.
Star-shaped block copolymers consisting of non-toxic poly(ethylene glycol) and biodegradable polycaprolactone ((PEG5K-PCL)4) were synthesized by ring-opening polymerization of the ε-caprolactone monomer with hydroxyl-terminated 4-armed PEG as initiator. These biodegradable, amphiphilic star block copolymers showed micellization and sol-gel transition behaviors in aqueous solution with varying concentration and temperature. In the dilute aqueous solutions of star block copolymers, micellization behavior occurred over specific concentration. The 1,6-diphenyl-1,3,5-hexatriene (DPH) solubilization method was used to determine the critical micellization concentration (CMC) of star block copolymers. The obtained micelle size increased with increasing hydrophobic PCL block length. In high-concentration solutions, the star block copolymers showed temperature-sensitive sol-gel transition behavior. The morphology of the micelle and gel was investigated by atomic force microscopy (AFM). As a result, the micelles showed a core-corona spherical structure at concentration near CMC, while the gel showed a mountain-chain-like morphology picture. It was proposed that with increasing the micelle concentration the worm-like micelle clusters formed firstly and the gel was constructed by the packing of micelle clusters. 相似文献
268.
FTIR-ATR has been used for understanding the interaction between bacteria and surfaces in the adsorption progress. 相似文献
269.
The hydrothermal reaction of VOSO4, As2O5, piperazine and H2O produces [H2N(CH2)4NH2]4[β‐As8V14O42(SO4)]·2HSO4 ( 1 ), which is the first arsenic‐vanadium cluster containing a spherical β‐As8V14O42 shell. The structure of this compound was characterized by single crystal X‐ray diffraction, elemental analysis, TG, and IR spectrum. Crystal data for 1 : Orthorhombic, Cmcm, a = 15.369(1) Å, b = 16.404(1) Å, c = 25.772(1) Å, V = 6497.4(9) Å3, Z = 4. 相似文献
270.
Guo Jin-xin Sun Si-xiu Zhu Rong-xiu Yin Zhi-lei Yu Hai-yun Li Da-zhi Zhang Wei-min Xu Xian-gang Sun Xuan Shao Hua 《Journal of Radioanalytical and Nuclear Chemistry》2004,261(1):221-224
The 222Rn emanation fraction (EF) released from the technically enhanced naturally occurring radioactive material (TE-NORM) wastes
at certain sites of petroleum and gas production was determined. The samples were analyzed by γ-ray spectrometry to determine
the activity concentration of the 226Ra content, of which the 222Rn emanation fraction was calculated. The results showed that the 222Rn emanation fraction differs in the oil and gas production sites and it is independent of the activity concentration of 226Ra.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献