全文获取类型
收费全文 | 4345篇 |
免费 | 772篇 |
国内免费 | 704篇 |
专业分类
化学 | 3006篇 |
晶体学 | 104篇 |
力学 | 218篇 |
综合类 | 65篇 |
数学 | 690篇 |
物理学 | 1738篇 |
出版年
2024年 | 13篇 |
2023年 | 77篇 |
2022年 | 111篇 |
2021年 | 146篇 |
2020年 | 200篇 |
2019年 | 175篇 |
2018年 | 174篇 |
2017年 | 178篇 |
2016年 | 215篇 |
2015年 | 200篇 |
2014年 | 220篇 |
2013年 | 322篇 |
2012年 | 416篇 |
2011年 | 408篇 |
2010年 | 323篇 |
2009年 | 324篇 |
2008年 | 337篇 |
2007年 | 288篇 |
2006年 | 252篇 |
2005年 | 209篇 |
2004年 | 140篇 |
2003年 | 144篇 |
2002年 | 186篇 |
2001年 | 152篇 |
2000年 | 103篇 |
1999年 | 85篇 |
1998年 | 50篇 |
1997年 | 37篇 |
1996年 | 47篇 |
1995年 | 30篇 |
1994年 | 37篇 |
1993年 | 30篇 |
1992年 | 27篇 |
1991年 | 27篇 |
1990年 | 27篇 |
1989年 | 9篇 |
1988年 | 12篇 |
1987年 | 9篇 |
1986年 | 13篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 9篇 |
1982年 | 9篇 |
1980年 | 2篇 |
1977年 | 5篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 5篇 |
1972年 | 4篇 |
1971年 | 4篇 |
排序方式: 共有5821条查询结果,搜索用时 250 毫秒
151.
Jing Wang Ke Feng Nan Xie Zhi-Jun Li Qing-Yuan Meng Bin Chen Chen-Ho Tung Li-Zhu Wu 《中国科学:化学(英文版)》2016,59(8):1018-1024
We develop here a simple wet chemistry to prepare covalent functionalized graphenes(FGs) through epoxide aminolysis especially under alkaline aqueous condition. Remarkably, a series of typical monoamines, such as industrial Huntsman Jeffamine~ M-2070 and M-2005 polymer with hydrophilic or hydrophobic polyetheramine chains, positively-charged 2-amino-N,N,Ntrimethylpropanaminium,negatively-charged sulfanilic acid, even oligopeptide sequence, can be effectively grafted on the platelets of graphene oxide precursor with covalent functionalization and partially reduced features. This strategy provides the researchers a facile and convenient approach to design and synthesize solution processable, biocompatible and functionalized graphenes for the potent applications in electronic inks, drug carriers and biomedicines. Expansion of the current study is actively ongoing in our laboratory. 相似文献
152.
153.
154.
155.
156.
157.
Ke Xu Evan T. Vickers Longshi Rao Dr. Sarah A. Lindley A'Lester C. Allen Prof. Binbin Luo Prof. Xueming Li Prof. Jin Zhong Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(19):5014-5021
CH3NH3PbBr3 perovskite quantum dots (PQDs) are synthesized by using four different linear alkyl phosphonic acids (PAs) in conjunction with (3-aminopropyl)triethoxysilane (APTES) as capping ligands. The resultant PQDs are characterized by means of XRD, TEM, Raman spectroscopy, FTIR spectroscopy, UV/Vis, photoluminescence (PL), time-resolved PL, and X-ray photoelectron spectroscopy (XPS). PA chain length is shown to control the PQD size (ca. 2.9–4.2 nm) and excitonic absorption band positions (λ=488–525 nm), with shorter chain lengths corresponding to smaller sizes and bluer absorptions. All samples show a high PL quantum yield (ca. 46–83 %) and high PL stability; this is indicative of a low density of band gap trap states and effective surface passivation. Stability is higher for smaller PQDs; this is attributed to better passivation due to better solubility and less steric hindrance of the shorter PA ligands. Based on the FTIR, Raman, and XPS results, it is proposed that Pb2+ and CH3NH3+ surface defects are passivated by R−PO32− or R−PO2(OH)−, whereas Br− surface defects are passivated by R−NH3+ moieties. This study establishes the combination of PA and APTES ligands as a highly effective dual passivation system for the synergistic passivation of multiple surface defects of PQDs through primarily ionic bonding. 相似文献
158.
Dr. Longyu Li Qianming Lin Miao Tang Dr. Andrew J. E. Duncan Prof. Dr. Chenfeng Ke 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(46):10768-10781
The rapid development of additive manufacturing techniques, also known as three-dimensional (3D) printing, is driving innovations in polymer chemistry, materials science, and engineering. Among current 3D printing techniques, direct ink writing (DIW) employs viscoelastic materials as inks, which are capable of constructing sophisticated 3D architectures at ambient conditions. In this perspective, polymer designs that meet the rheological requirements for direct ink writing are outlined and successful examples are summarized, which include the development of polymer micelles, co-assembled hydrogels, supramolecularly cross-linked systems, polymer liquids with microcrystalline domains, and hydrogels with dynamic covalent cross-links. Furthermore, advanced polymer designs that reinforce the mechanical properties of these 3D printing materials, as well as the integration of functional moieties to these materials are discussed to inspire new polymer designs for direct ink writing and broadly 3D printing. 相似文献
159.
Wang Fei Cressault Yann Teulet Philippe Li Huan Yang Ke 《Plasma Chemistry and Plasma Processing》2019,39(4):1049-1069
Plasma Chemistry and Plasma Processing - Gas tungsten arc welding (GTAW), a widely used industrial process, is one of the most intense artificial sources of optical radiation. This paper presents a... 相似文献
160.
Hui‐Min Lin Jian‐Rong Li Chao Mu Ao Li Xu‐Feng Liu Pei‐Hua Zhao Yu‐Long Li Zhong‐Qing Jiang Hong‐Ke Wu 《应用有机金属化学》2019,33(11)
Five monophosphine‐substituted diiron propane‐1,2‐dithiolate complexes as the active site models of [FeFe]‐hydrogenases have been synthesized and characterized. Reactions of complex [Fe2(CO)6{μ‐SCH2CH(CH3)S}] ( 1 ) with a monophosphine ligand tris(4‐methylphenyl)phosphine, diphenyl‐2‐pyridylphosphine, tris(4‐chlorophenyl)phosphine, triphenylphosphine, or tris(4‐fluorophenyl)phosphine in the presence of the oxidative agent Me3NO·2H2O gave the monophosphine‐substituted diiron complexes [Fe2(CO)5(L){μ‐SCH2CH(CH3)S}] [L = P(4‐C6H4CH3)3, 2 ; Ph2P(2‐C5H4N), 3 ; P(4‐C6H4Cl)3, 4 ; PPh3, 5 ; P(4‐C6H4F)3, 6 ] in 81%–94% yields. Complexes 2 – 6 have been characterized by elemental analysis, spectroscopy, and X‐ray crystallography. In addition, electrochemical studies revealed that these complexes can catalyze the reduction of protons to H2 in the presence of HOAc. 相似文献