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41.
42.
Multifunctional TiO2‐Based Particles: The Effect of Fluorination Degree and Liquid Surface Tension on Wetting Behavior 下载免费PDF全文
Yuekun Lai Huanfu Zhou Zheng Zhang Yuxin Tang Jeffrey Weng Chye Ho Jianying Huang Qiuling Tay Keqin Zhang Zhong Chen Bernard P. Binks 《Particle & Particle Systems Characterization》2015,32(3):355-363
A systematic investigation into the influence of the degree of fluorination on the static and dynamic wetting behavior of TiO2‐based nanobelt (TNB) particles with various liquids is described. The effect of the degree of fluorination and the surface tension of the liquid on the occurrence and stability of liquid marbles, foams or dispersions are studied and the wetting behavior and arrangement of particles at the air–liquid surface are observed. Using contact angle (θ) measurements, the relation between the type of particle‐stabilized material and θ is established. For liquids of relatively high tension like water or formamide which do not wet the fluorinated particles, a powder‐like material (marble) is formed. For polar oils of intermediate tension (35–50 mN m?1), which partially wet the fluorinated particles, stable air‐in‐oil foams can be prepared in which particles form a close‐packed layer enveloping air bubbles. Liquids of relatively low tension, e.g., ethanol or polydimethylsiloxane, wet the particles forming a uniform dispersion and partial sedimentation. By contrast, the as‐prepared hydrophilic TNB particles are rapidly wetted by all the liquids as expected due to their high surface energy. The stable cross‐stacked TNB particles with fluoroalkylsilane (FAS) modification could be a versatile platform in a wide range of applications, especially for fluidic devices (e.g., biofluids, gas sensing, and lab‐on‐a‐chip devices). In a proof‐of‐concept study, the oil–water separation performance of fabrics with chemically stable TNB/FAS coating and the liquid isolation by a TNB/FAS shell for highly sensitive gas sensing or reagent assays are investigated. 相似文献
43.
Individual eye model based on wavefront aberration 总被引:2,自引:2,他引:2
Based on the widely used Gullstrand-Le Grand eye model, the individual human eye model has been established here, which has individual corneal data, anterior chamber depth and the eyeball depth. Furthermore, the foremost thing is that the wavefront aberration calculated from the individual eye model is equal to the eye's wavefront aberration measured with the Hartmann-shack wavefront sensor. There are four main steps to build the model. Firstly, the corneal topography instrument was used to measure the corneal surfaces and depth. And in order to input cornea into the optical model, high-order aspheric surface-Zernike Fringe Sag surface was chosen to fit the corneal surfaces. Secondly, the Hartmann-shack wavefront sensor, which can offer the Zernike polynomials to describe the wavefront aberration, was built to measure the wavefront aberration of the eye. Thirdly, the eye's axial lengths among every part were measured with A-ultrasonic technology. Then the data were input into the optical design software–ZEMAX and the crystalline lens's shapes were optimized with the aberration as the merit function. The individual eye model, which has the same wavefront aberrations with the real eye, is established. 相似文献
44.
Cytokinesis: Cytoskeleton and Chromosome Damage Leading to Abnormal Mitosis Were Involved in Multinucleated Cells Induced by Silicon Nanoparticles (Part. Part. Syst. Charact. 6/2015) 下载免费PDF全文
45.
Qiuling Chen Daniel Milanese Qiuping Chen Monica Ferraris Giancarlo C. Righini 《Journal of Non》2008,354(12-13):1230-1234
In this paper the fabrication, characterization, and thermal assisted bonding of two photosensitive silicate glasses is presented, as part of a wider process aiming to obtain a planar waveguide lossless splitter for telecom applications. Two glass compositions are investigated: an Er–Yb doped silicate glass, which amplifies the signals when pumped at 980 μm and a matchable passive glass, which is designed to host the waveguide splitter. The two parts were bonded successfully using direct bonding technique at 605 ± 20 °C for 240 min under a pressure of 28 kPa. Vickers hardness measurements were made on the bulk glasses and at the bonded interface, which showed no cracks propagating along the interface. 相似文献
46.
Excited-state intramolecular proton transfer (ESIPT) reactions of three amino-type 2-(2'-aminophenyl)benzothiazole (PBT-NH2) derivatives, that is, 2-(2'-methylaminophenyl)benzothiazole (PBT-NHMe), 2-(2'-acetylaminophenyl)benzothiazole (PBT-NHAc) and 2-(2'-tosylaminophenyl)benzothiazole (PBT-NHTs), have been explored by the time-dependent density functional theory (TD-DFT) method with the B3LYP density functional. In addition, their absorption and fluorescence spectra were also simulated at the same theoretical level. The present studies reveal that the energy barriers of the first singlet excited state of the three titled compounds along the ESIPT reactions are predicted at 0.39, 0.30 and 0.12 eV, respectively, suggesting that the inclusion of a strong electron-withdrawing tosyl group can remarkably facilitate the occurrence of the ESIPT reaction, while the involvement of an electron-donating methyl group has no effect on the ESIPT process of the amino-type hydrogen-bonding system. Following the ESIPT, both PBT-NHAc and PBT-NHTs molecules can also undergo the cis–trans isomerisation reactions along the C2–C3 bond between benzothiazole and phenyl moieties, in which the energy barriers of the trans-tautomer → cis-tautomer isomerisations in both ground states are calculated at 0.33 and 0.27 eV, respectively. This implies that there may exist a long-lived trans-tautomer species in the ground states for PBT-NHAc and PBT-NHTs, as observed in the spectroscopic experiments of PBT-NHTs. 相似文献
47.
XuehuaChen ChunzhongLi LingZhang ShoufangXu QiulingZhou YihuaZhu XianzhangQu 《中国颗粒学报》2004,2(5):226-229
Zirconium phosphate containing silver was chosen as antibacterial particles in preparing antibacterial particles/PVC composite. The effect of surface property of the antibacterial particles and of their filler content on the properties of antibacterial particles/PVC composite was studied. The effect of the interracial compatibility on mechanical properties of the composite was also discussed. Experimental results showed that the antibacterial PVC composite had good antibacterial property, reaching almost 100% bacteriostatic level at an antibacterial powder filler content of 1.5phr. 相似文献
48.
Metal-Salen (M = Fe, Co, Ni, Cu, Zn) complexes were synthesized to catalyze the oxidation of benzoin to benzil with air as the “green” oxidizing reagent. The effects of temperature, base and solvent on M-Salen catalyzed oxidation of benzoin had been examined and optimized. The catalysis results showed that Co-Salen and Fe-Salen complexes were efficient to catalyze the oxidation reaction with yields over 80% while the catalytic activities of other three M-Salen complexes were poor. Moreover, the Co-Salen catalysis system could be reused three times with satisfied yield. 相似文献
49.
50.
Yifei Xiang Min Ji Liqin Wu Li Lv Qiuling Liang Ruihan Deng Zhaoyou Deng Xia Liu Lingyi Ren Xin Feng Jiakang He 《Molecules (Basel, Switzerland)》2022,27(22)
Drug-induced liver and kidney damage is an emergent clinical issue that should be addressed. Rosmarinic acid (RA) has obvious anti-inflammatory and antioxidant effects, so we evaluated the anti-inflammatory and antioxidant effects of RA pretreatment on serum and liver and kidney tissues of cisplatin (CP)-treated mice and explored the possible mechanisms. The results showed that RA pretreatment effectively downregulated the serum, liver, and kidney levels of ALT, AST, BUN, and CRE and the inflammatory factors IL-1β, IL-6, and TNF-α, and simultaneously enhanced the total antioxidant capacity of the liver and kidney. RA pretreatment significantly reduced the levels of MPO, MDA, and NO in liver and kidney tissue, inhibited the mRNA expression of IL-1β, IL-6, and TNF-α in liver and kidney tissue, activated the Nrf2 signaling pathway, and upregulated the mRNA expression of downstream target genes. Our findings show that RA could effectively prevent and alleviate acute liver and kidney injury caused by CP. 相似文献