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991.
从理论上研究了共轭高聚物链中在电场作用下极化子运动的热效应.基于SSH模型以及通过绝热动力学演化的方法,模拟了共轭高聚物链中极化子在电场作用下从链左端向右端运动的过程.晶格受到的热扰动作用假设为通过局域的晶格范围内原子位移的随机涨落来实现.结果发现,晶格中的局域热涨落对于运动中的极化子而言等效于一个势垒.势垒高度由高分子中受到热扰动的区域的范围大小以及该区域与其周围环境的温差来决定.当分子中存在热吸收不均匀的现象时,链内极化子迁移率在低电场范围内随电场的变化遵循对数曲线变化规律. 相似文献
992.
993.
Xiaogang Sun Jun Xing Jingping Qiu 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2016,90(6):1151-1156
A series of boron and sulfur co-doped titanium dioxide (TiO2) photocatalysts were prepared by a sol-gel method using boric acid, thiourea and tetrabutyl titanate [Ti(OC4H9)4] as precursors. The photoabsorbance of as-prepared photocatalysts was measured by UV–Vis diffuse reflectance spectroscopy (DRS), and its microstructure was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and N2 adsorption-desorption measurements. The prepared photocatalysts consisted of the anatase phase mainly in the form of spherical particles. The photocatalytic performance was studied by photodegradation of methyl blue (MB) in water under UV and visible light irradiation. The calcination temperature and the codoping content influenced the photoactivity. The synergistic effect of boron and sulfur co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of codoped TiO2 was also confirmed, the photocatalytic activity of TiO2 remained above 91% of that of the fresh sample after being used four times. It was shown that the co-doped TiO2 could be activated by visible light and could thus be potentially applied for the treatment of water contaminated by organic pollutants. 相似文献
994.
A Facile Synthesis of Novel Allenylphosphinates Containing Multi Potential Asymmetric Centers
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Lan Yao Si‐Yu Ji Zhong‐Yuan Xu Yong‐Ming Sun Chang‐Qiu Zhao 《Journal of heterocyclic chemistry》2016,53(4):1155-1158
The novel allenylphosphinates containing up to three axial and phosphorus asymmetric centers were prepared in excellent yields via the reactions of 6‐chloro‐6H‐dibenzo[c,e][1,2]oxaphosphinine to propargyl alcohols. During the process, the configuration of phosphorus determined the biphenyl axial chirality, stereospecifically forming (l)‐stereomers but did not influence the chirality of allenyl axis. 相似文献
995.
996.
Electrospun polystyrene nanofibers as a novel adsorbent to transfer an organic phase from an aqueous phase
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![点击此处可从《Journal of separation science》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The aim of this work is to develop a simple phase‐transfer method for dispersive liquid–liquid microextraction. For this purpose, a polystyrene nanofiber was prepared by a facile electrospinning strategy and used for the first time as an adsorbent to transfer the organic phase in dispersive liquid–liquid microextraction procedure. The fiber was characterized and its chemical stability and excellent hydrophobicity enable it to selectively adsorb the organic solvent in an aqueous sample. High porosity and specific surface area provide a large adsorption capacity. Under the optimal conditions, the developed dispersive liquid–liquid microextraction with high‐performance liquid chromatography method was successfully applied to the analysis of aldehydes in environmental water samples. The merits of this approach are that it is easy‐to‐operate, low‐cost, time‐saving, and has satisfactory sensitivity. It provides an alternative way for fast and convenient phase transfer of the hydrophobic organic solvent from the aqueous phase. 相似文献
997.
A Copper‐Catalyzed Decarboxylative Amination/Hydroamination Sequence: Switchable Synthesis of Functionalized Indoles
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Tian‐Ren Li Bei‐Yi Cheng Ya‐Ni Wang Mao‐Mao Zhang Prof. Dr. Liang‐Qiu Lu Prof. Dr. Wen‐Jing Xiao 《Angewandte Chemie (International ed. in English)》2016,55(40):12422-12426
A copper‐catalyzed decarboxylative amination/hydroamination sequence of propargylic carbamates with various nucleophiles is described for the first time. It features an earth‐abundant metal catalyst, mild reaction conditions, and high efficiency. Further treatments of the resultant key intermediates using an acid or a base in one pot enable the controllable and divergent synthesis of two types of functionalized indoles. Moreover, experiments to demonstrate the synthetic potential of this methodology are performed. 相似文献
998.
Zongyang Qiu Prof. Li Song Prof. Jin Zhao Prof. Zhenyu Li Prof. Jinlong Yang 《Angewandte Chemie (International ed. in English)》2016,55(34):9918-9921
Metal‐nanoparticle‐catalyzed cutting is a promising way to produce graphene nanostructures with smooth and well‐aligned edges. Using a multiscale simulation approach, we unambiguously identified a “Pac‐Man” cutting mechanism, characterized by the metal nanoparticle “biting off” edge carbon atoms through a synergetic effect of multiple metal atoms. By comparing the reaction rates at different types of edge sites, we found that etching of an entire edge carbon row could be triggered by a single zigzag‐site etching event, which explains the puzzling linear dependence of the overall carbon‐atom etching rate on the nanoparticle surface area observed experimentally. With incorporation of the nanoparticle size effect, the mechanisms revealed herein open a new avenue to improve controllability in graphene cutting. 相似文献
999.
Hepatitis B virus (HBV) and its vaccination strategy may affect human immunodeficiency virus (HIV) transmission dynamics because both viruses have synergistic effects. To quantitatively assess the potential impact of HBV and its vaccination strategy on HIV transmission dynamics at the population level, in this paper, we formulate a deterministic compartmental model that describes the joint dynamics of HBV and HIV. We first derive the explicit expressions for the basic reproduction numbers of HIV and HBV and analyze the dynamics of HIV and HBV subsystems, respectively. Then a systematic qualitative analysis of the full system is also provided, which includes the local and global behavior. By using a set of reasonable parameter values, the full system is numerically investigated to assess the potential impact of HBV and its vaccination strategy on HIV transmission. The direct and indirect population level impact of HBV on HIV is demonstrated by calculating the fraction of HIV infections attributable to HBV and the difference between HIV prevalence in the presence and absence of HBV, respectively. The findings imply that the increase of HBV vaccination rate may unusually accelerate HIV epidemics indirectly, although the direct effect of HBV on HIV transmission decreases as HBV vaccination rate increases. Finally, the potential impact of HIV on HBV transmission dynamics is investigated by way of parenthesis. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
1000.
Determination of arsenic species in Solanum Lyratum Thunb using capillary electrophoresis with inductively coupled plasma mass spectrometry
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Pei‐Yu Shuai Xiao‐Jun Yang Zong‐Qing Qiu Xiao‐Hui Wu Xi Zhu Ganga Raj Pokhrel Yu‐Ying Fu Hui‐Min Ye Wen‐Xiong Lin Gui‐Di Yang 《Journal of separation science》2016,39(16):3239-3245
A simple and highly efficient interface to couple capillary electrophoresis with inductively coupled plasma mass spectrometry by a microflow polyfluoroalkoxy nebulizer and a quadruple ion deflector was developed in this study. By using this interface, six arsenic species, including arsenite, arsenate, monomethylarsonic acid, dimethylarsinic acid, arsenobetaine, and arsenocholine, were baseline‐separated and determined in a single run within 11 min under the optimized separation conditions. The instrumental detection limit was in the range of 0.02–0.06 ng/mL for the six arsenic compounds. Repeatability expressed as the relative standard deviation (n = 5) of both migration time and peak area were better than 2.5 and 4.3% for six arsenic compounds. The proposed method, combined with a closed‐vessel microwave‐assisted extraction procedure, was successfully applied for the determination of arsenic species in the Solanum Lyratum Thunb samples from Anhui province in China with the relative standard deviations (n = 5) ≤4%, method detection limits of 0.2–0.6 ng As/g and a recovery of 98–104%. The experimental results showed that arsenobetaine was the main speciation of arsenic in the Solanum Lyratum Thunb samples from different provinces in China, with a concentration of 0.42–1.30 μg/g. 相似文献