Surface free energies of electroless Ni–P based composite coatings

Surface free energy of a solid surface gives a direct measure of intermolecular interactions at interfaces and has a strong influence on adsorption and adhesion behaviour. However few data are available for the surface free energies of electroless Ni–P based composition coatings. In this paper, the electroless Ni–P, Ni–P-surfactant, Ni–Cu–P, Ni–P–PTFE and Ni–Cu–P–PTFE composite coatings were prepared under various coating conditions. The chemical compositions, surface morphology and thickness of the coatings were measured using an energy dispersive X-ray microanalysis (EDX), a scanning electron microscope (SEM) and a digital micrometer respectively. The contact angles of water, diiodomethane and ethylene glycol on the coatings were measured automatically using dataphysics OCA-20 contact angle analyser. The surface free energy of the coatings and their components (e.g. dispersion, polar or acid/base portions) were calculated using various methods. The experimental results showed that the incorporation of surfactant or PTFE particles into Ni–P matrixes has a significant influence on the surface free energy of the coatings, while the incorporation of copper into Ni–P matrixes has no significant influence on the surface free energy of the coatings.     

厚高阶光学非线性介质Z扫描的变分法分析

利用变分法对具有五阶光学非线性介质的Z扫描特性进行了研究。通过比较，发现当介质在具有较大的五阶非线性系数或较大光强的情况下，五阶非线性项的作用是不可忽略的。这对光限制器的设计和Z扫描实验都具有一定的指导意义。     

On the even power mean of a sum analogous to Dedekind sums

Summary Our purpose is to extend results due to P. Chandra and L. Leindler concerning the order of approximation by means of Fourier series for functions belonging to generalized Lipschitz-classes.     

蓝光相变光盘的多层膜结构设计

为了使光盘获得优良的记录／读出性能并能够长期稳定地使用，必须优化设计相变光盘的多层膜结构。采用自行设计的模拟分析相变光盘读出过程设计软件，从光学角度出发模拟计算了蓝光(405nm)相变光盘的膜层结构，研究了多层膜系的反射率和反射率对比度等光学参量与各层膜厚度和槽深的关系。研究得出的最佳多层膜结构为：下介电层／记录层／上介电层／反射层的厚度对于台记录为100nm／10nm／25nm，／60nm，而对于槽记录则为140nm／15nm／30nm，／60nm，槽深为50nm。模拟计算结果对于将来高密度蓝光相变光盘的制备具有一定的指导意义。     

Effects of Evanescent Space-Harmonics on the Transmission Characteristics of a Gaussian Beam by Cylindrical Wire Grids

When electromagnetic waves propagate through a wire grid, there will be some evanescent space harmonics generated around the wire grid. In this paper, we mainly investigate their effects on the transmission characteristics of a Gaussian beam by cylindrical wire grids. The results are compared with those without taking account of evanescent space-harmonics.     

Urea method for the synthesis of hydrotalcites

Mg-Al, Zn-Al and Ni-Al hydrotalcite-like compounds with high crystallinity were synthesized by using the decomposing property of urea at high temperature. The crystallinity and the regularly of the samples were much preferable to those synthesized by other methods. This revised version was published online in June 2006 with corrections to the Cover Date.     

Microwave‐improved polymerization of ϵ‐caprolactone initiated by carboxylic acids

The ring‐opening polymerization of ε‐caprolactone (ε‐CL), initiated by carboxylic acids such as benzoic acid and chlorinated acetic acids under microwave irradiation, was investigated; with this method, no metal catalyst was necessary. The product was characterized as poly(ε‐caprolactone) (PCL) by ¹H NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet spectroscopy, and gel permeation chromatography. The polymerization was significantly improved under microwave irradiation. The weight‐average molecular weight (M_w) of PCL reached 44,800 g/mol, with a polydispersity index [weight‐average molecular weight/number‐average molecular weight (M_w/M_n)] of 1.6, when a mixture of ε‐CL and benzoic acid (25/1 molar ratio) was irradiated at 680 W for 240 min, whereas PCL with M_w = 12,100 and M_w/M_n = 4.2 was obtained from the same mixture by a conventional heating method at 210 °C for 240 min. A degradation of the resultant PCL was observed during microwave polymerization with chlorinated acetic acids as initiators, and this induced a decrease in M_w of PCL. However, the degradation was hindered by benzoic acid at low concentrations. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 13–21, 2003     

Diffusion of 99Tc in granite under aerobic and anoxic conditions

Summary  Vezetéknév     

Lower bounds for sums of Barban-Davenport-Halberstam type (supplement)

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