一种高效的优化量子Monte Carlo波函数的新方法

提出了一个优化量子MonteCarlo波函数的新方法，与前人的方法相比，它不使用变分原理而是极小化Schrodinger方程的剩余量；不按Ψ2取样而是按Ψ2（EL－E）2取样；不用差分而是用分析导数；不使用传统的速降法而是使用一个步长自动调节的下降法，它具有拟牛顿性质，因而是超线性收敛的．由于这四项新技术的使用，使得波函数的优化快速、准确，收敛速度比前人提出的方法快3～5倍．     

波分复用全光通信网中的放大自发辐射噪声积累效应研究

给出了一种全光通信网波长域计算机模拟方法，模拟了波分复用信号经过３个光分插复用节点后的信号及放大自发辐射积累的光谱图，并与实验结果进行了对比。计算了波分复用信号经过５０个光分插复用节点极限情况下的信噪比，结果表明放大自发辐射噪声积累造成的信噪比下降仍然可以保证接收机在１０Ｇｂ／ｓ时的误码率小于１０＾－９。这些结果可以被应用到未来国家或地区级全光通信网中。     

熔锥平面型三光纤耦合特性分析

以线性耦合波方程为基础，分析了具有不同耦合强度的平面型三光纤耦合系统的模场特性和功率耦合特性，并与常规的平面型三光纤耦合系统的耦合特性作了比较，给出的耦合器谱响应实验结果与理论结果较为一致。     

Electrochemical determination of heparin using methylene blue probe and study on competition of Ba with methylene blue for binding heparin

Cyclic voltammetric investigation of the interaction of methylene blue (MB) with heparin (hep) at a gold electrode is presented. The combination of MB with heparin formed a nonelectroactive complex MB-hep, which resulted in the peak current decrease of MB. The anodic peak current difference of MB was found to be proportional to the concentration of heparin in the range of 0.666-64.5 μg mL⁻¹ with a detection limit of 270 ng mL⁻¹ and a satisfactory result was obtained for the determination of heparin in injection samples. The equilibrium constant for MB-hep complex was calculated to be 7.32 × 10⁵. The dynamic process of competition of Ba²⁺ with methylene blue for binding heparin was monitored using quartz crystal microbalance (QCM) technique. The reaction rate constant between Ba²⁺ and MB-hep was estimated to be 0.0022 s⁻¹.     

Performance Degradation due to Cascaded Erbium Doped Fiber Amplifier Power Transients in Wavelength Routed Optical Networking

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Kinetic study of l-isoleucine transport through a liquid membrane containing di(2-ethylhexyl) phosphoric acid in kerosene

A kinetic study of l-isoleucine transport through a liquid membrane containing di(2-ethylhexyl) phosphoric acid (D2EHPA) in kerosene is presented. The influences of pH in the aqueous feed solution, D2EHPA concentration in the organic phase, the stripping solution composition and H₂SO₄ concentration in the stripping solution were investigated, and the effects of stirring speed and temperature on the transport of l-isoleucine through a bulk liquid membrane (BLM) were studied. The kinetics of l-isoleucine transport could be analyzed in the formalism of a reversible pseudo-first-order reaction followed by an irreversible pseudo-first-order reaction. The pseudo-first-order apparent rate constants of the interfacial transport of l-isoleucine species are determined for the liquid membrane, at various temperatures. The apparent activation energy values are 21.3±1.9, 57.6±5.1 and 31.8±2.7 kJ mol⁻¹ for the extraction reaction, extraction back reaction and stripping reaction, respectively.     

WDM多纤环网的优化设计

本文讨论了WDM多纤环网(MFR)的优化设计问题,为解决该问题提出了新的整数线性规划公式.所采用的优化目标是最小化平均结点端口数目,以此为优化目标可以保证所设计的多纤环网具有最大的经济有效性.利用所提出的算法,我们定量分析了采用不同路由方案(波长通道和虚波长通道)的几种MFR结构(单向和双向)的网络性能.本文所获得的结论可作为选择合适MFR结构的参考.     

Epoxidation of cyclohexene with molecular oxygen by electrolysis combined with chemical catalysis

This paper describes an electrochemical coupling epoxidation of cyclohexene by molecular oxygen (O₂) under mild reaction conditions. Herein, the electroreduction of O₂ to hydrogen peroxide (H₂O₂) efficiently proceeds in a relatively environmentally friendly acetone/water medium containing electrolytes at 25–30 °C on a self-assembled H type of electrolysis cell with tree electrodes system, providing ca. 44.3 mM concentration of H₂O₂ under the optimal electrolysis conditions. The epoxidation of cyclohexene with in situ generated H₂O₂ simultaneously occurs upon catalysis by metal complexes, giving ca. 19.8 % of cyclohexene conversion with 78 % of epoxidative selectivity over the best catalyst 5-Cl-7-I-8-quinolinolato manganese(III) complex (Q₃Mn^III (e)). The present electrochemical coupling epoxidation result is nearly equivalent to the epoxidation of cyclohexene with adscititious H₂O₂ catalyzed by the Q₃Mn^III (e).     

光伏应用系统远程监测平台设计

随着太阳能发电技术的不断发展,光伏应用系统越多的被工业单位和个人使用。通过对光伏应用系统的分布形式进行归类,阐述了光伏应用系统远程监测平台的设计方案。在研究分析无线自组网技术和无线数据传输技术的基础上针对光伏应用系统的分布特点,将嵌入式技术,ZigBee技术,GPRS-DTU技术以及互联网Web监测技术之相结合,设计了一种光伏应用系统远程监测平台。该平台能够有效完成数据采集、组网、远程监测等预期要求,最后通过实验验证了该平台的可行性。