Water Status and Predictive Models of Moisture Content during Drying of Soybean Dregs Based on LF-NMR

To explore the drying characteristics of soybean dregs and a nondestructive moisture content test method, in this study, soybean dregs were dried with hot air (80 °C), the moisture content was measured using the drying method, water status was analyzed using low-field nuclear magnetic resonance (LF-NMR) and the moisture content prediction models were built and validated. The results revealed that the moisture contents of the soybean dregs were 0.57 and 0.01 g/g(w.b.), respectively, after drying for 5 and 7 h. The effective moisture diffusivity increased with the decrease in moisture content; it ranged from 5.27 × 10⁻⁹ to 6.96 × 10⁻⁸ m²·s⁻¹. Soybean dregs contained bound water (T₂₁), immobilized water (T₂₂) and free water (T₂₃ and T₂₃’). With the proceeding of drying, all of the relaxation peaks shifted left until a new peak (T₂₃’) appeared; then, the structure of soybean dregs changed, and the relaxation peaks reformed, and the peak shifted left again. The peak area may predict the moisture content of soybean dregs, and the gray values of images predict the moisture contents mainly composed of free water or immobilized water. The results may provide a reference for drying of soybean dregs and a new moisture detection method.     

非稳态油膜力作用下偏角不对中碰摩转子系统振动特性分析

建立了非稳态油膜力、碰摩力作用下,偏角不对中轴系的横向振动模型,将Jeffcott转子模型推广至约束条件下的轴系振动模型,通过引入转子间的位移约束,由Lagrange方程导出了不对中轴系系统的振动方程.仿真研究表明:由于不对中的存在,轴系横向振动是强非线性、非定常、同时含有自激励、参数激励和外激励的三自由度振动系统;由于从动轴与主动轴的不对中,导致了转轴间的运动约束,使轴系横向振动系统比Jeffcott转子动力学模型所描述的振动系统少了一个自由度.随着偏角不对中量、转轴质量比的变化,系统出现周期、概周期、混沌运动特征.不对中轴系处于概周期运动时,呈现出自激振动特征.其结果可为旋转机械故障诊断、轴系对中及设备的安全运行提供更为准确的理论参考.     

Polyoxometalate/Cellulose Nanofibrils Aerogels for Highly Efficient Oxidative Desulfurization

Polyoxometalate (POM) presents great potential in oxidative desulfurization (ODS) reaction. However, the high dissolubility of POM in common solvents makes it difficult to recycle. Besides, the small specific surface area of POM also limits the interaction between them and the substrate. Depositing polyoxometalates onto three-dimensional (3D) network structured materials could largely expand the application of POM. Here, the surfaces of cellulose nanofibrils (CNFs) were modified with very few (3-Aminopropyl) trimethoxysilane (APTS) to endow positive charges on the surfaces of CNFs, and then phosphotungstic acid (PTA) was loaded to obtain the aerogel A-CNF/PTA as the ODS catalyst. FT-IR indicated the successful deposition of PTA onto aminosilane modified CNF surfaces. UV-VIS further suggested the stability of PTA in the aerogels. BET and SEM results suggested the increased specific surface area and the relatively uniform 3D network structure of the prepared aerogels. TGA analysis indicated that the thermal stability of the aerogel A-CNF/PTA50% was a little higher than that of the pure CNF aerogel. Most importantly, the aerogel A-CNF/PTA50% showed good catalytic performance for ODS. Catalysis results showed that the substrate conversion rate of the aerogel A-CNF/PTA50% reached 100% within 120 min at room temperature. Even after five cycles, the substrate conversion rate of the aerogel A-CNF/PTA50% still reached 91.2% during the dynamic catalytic process. This work provides a scalable and facile way to stably deposit POM onto 3D structured materials.     

A Docosahexaenoic Acid Derivative (N-Benzyl Docosahexaenamide) as a Potential Therapeutic Candidate for Treatment of Ovarian Injury in the Mouse Model

Commonly used clinical chemotherapy drugs, such as cyclophosphamide (CTX), may cause injury to the ovaries. Hormone therapies can reduce the ovarian injury risk; however, they do not achieve the desired effect and have obvious side effects. Therefore, it is necessary to find a potential therapeutic candidate for ovarian injury after chemotherapy. N-Benzyl docosahexaenamide (NB-DHA) is a docosahexaenoic acid derivative. It was recently identified as the specific macamide with a high degree of unsaturation in maca (Lepidium meyenii). In this study, the purified NB-DHA was administered intragastrically to the mice with CTX-induced ovarian injury at three dose levels. Blood and tissue samples were collected to assess the regulation of NB-DHA on ovarian function. The results indicated that NB-DHA was effective in improving the disorder of estrous cycle, and the CTX+NB-H group can be recovered to normal levels. NB-DHA also significantly increased the number of primordial follicles, especially in the CTX+NB-M and CTX+NB-H groups. Follicle-stimulating hormone and luteinizing hormone levels in all treatment groups and estradiol levels in the CTX+NB-H group returned to normal. mRNA expression of ovarian development-related genes was positive regulated. The proportion of granulosa cell apoptosis decreased significantly, especially in the CTX+NB-H group. The expression of anti-Müllerian hormone and follicle-stimulating hormone receptor significantly increased in ovarian tissues after NB-DHA treatment. NB-DHA may be a promising agent for treating ovarian injury.     

Improvement of Biological Effects of Root-Filling Materials for Primary Teeth by Incorporating Sodium Iodide

Therapeutic iodoform (CHI₃) is commonly used as a root-filling material for primary teeth; however, the side effects of iodoform-containing materials, including early root resorption, have been reported. To overcome this problem, a water-soluble iodide (NaI)-incorporated root-filling material was developed. Calcium hydroxide, silicone oil, and NaI were incorporated in different weight proportions (30:30:X), and the resulting material was denoted DX (D5~D30), indicating the NaI content. As a control, iodoform instead of NaI was incorporated at a ratio of 30:30:30, and the material was denoted I30. The physicochemical (flow, film thickness, radiopacity, viscosity, water absorption, solubility, and ion releases) and biological (cytotoxicity, TRAP, ARS, and analysis of osteoclastic markers) properties were determined. The amount of iodine, sodium, and calcium ion releases and the pH were higher in D30 than I30, and the highest level of unknown extracted molecules was detected in I30. In the cell viability test, all groups except 100% D30 showed no cytotoxicity. In the 50% nontoxic extract, D30 showed decreased osteoclast formation compared with I30. In summary, NaI-incorporated materials showed adequate physicochemical properties and low osteoclast formation compared to their iodoform-counterpart. Thus, NaI-incorporated materials may be used as a substitute for iodoform-counterparts in root-filling materials after further (pre)clinical investigation.     

磁致伸缩材料弱磁场响应特性的实验研究

针对磁致伸缩材料在弱磁场传感器领域的应用需要,采用迈克耳逊干涉原理实验测量了零应力条件下Tb-Dy-Fe材料和Fe-Ga合金的磁场响应灵敏度,以及不同应力下Fe-Ga合金的磁场响应特性和温度响应特性.实验结果表明：在零应力,外加磁场16 mT条件下,Fe-Ga合金的磁场响应灵敏度远高于Tb-Dy-Fe材料,更合适作为弱磁场传感器敏感材料;同时,在1.2 MPa预应力和26 mT偏置磁场下,Fe-Ga合金材料具有较好的磁场响应灵敏度和较大的饱和磁致伸缩系数,因而处在最佳工作状态.所得到的材料的磁场和温度响应曲线可作为弱磁场传感器参量设计的参考依据.     

声光栅正弦结构光投射器的光学系统设计

针对一种新型的声光波干涉测量技术,对声光栅正弦结构光投射器的三维测量工作原理进行了系统的分析,讨论了影响投射器光学系统结构的因素和影响接收屏上的光照度的因素,并进行了光学系统设计。在优化设计过程中,采用了限制光线最大入射角的方法,达到控制投射系统的球差和保证接收屏上照明均匀的要求。所设计的声光栅正弦光投射器具有很好的成像质量。应用该系统对在500mm处的石膏像上投射干涉条纹,可以得到能量比较均匀、变形量很小的干涉条纹图,利用该条纹图和相关的算法可以对具有复杂几何形状的物体进行有效的三维测量。     

大模场面积光子晶体光纤激光器展宽脉冲锁模域的束缚态运转

实验研究了大模面积光子晶体光纤飞秒激光器在近零色散点展宽脉冲锁模的束缚态运转.获得了双脉冲束缚态锁模,以及脉冲间隔不相等的多脉冲束缚态锁模,实验发现束缚态的子脉冲间距具有随机性.通过建立光纤锁模激光器的数值模型,分析了激光器束缚态锁模建立的动力学过程,在一定抽运强度下,激光器存在多个稳态,或者单脉冲运转,或者子脉冲间隔不相等的束缚态运转,这取决于锁模建立阶段半导体可饱和吸收镜(SESAM)对噪声信号的随机提取.并提出了抑制束缚态的方法,模拟得出此项技术可直接获得的最大单脉冲能量为19.6 nJ,考虑到40%左右的压缩损耗,可得到压缩至76 fs的最短脉冲,单脉冲能量为11.8 nJ.数值模拟结果能很好的与实验相符合.     

增生性疤痕组织与正常上皮组织FTIR光谱研究

通过对40例疤痕组织和正常皮肤组织的ETIR光谱比较分析发现,由于个体差异,其光谱均可分为三种不同类型。此外,疤痕组织中的胶原、蛋白质、核酸和脂类等生物大分子的吸收峰强度均在不同程度上高于正常皮肤组织,但两者的A_(1083)/A_(1548)并无明显差异。提示疤痕组织中的细胞仍属正常生长,治疗中不应损伤。     

从革命到改良：整顿《解放与改造》与“梁启超系”的渐进取向

《解放与改造》由张东荪在1919年创办,在五四时期风行一时,影响极大。刊名中“解放”的涵义本有整体性、对抗性的破坏倾向,故杂志对西方现代文明、中国传统文明、现有政权均取革命立场,倡导在“解放”一切现状基础上进行改造。同时,以讨论、宣传社会主义为职责,高谈主义而不重具体问题之研究、解决。然而,1920年梁启超、蒋百里等欧游归国,接收并整顿《解放与改造》,更名《改造》,扭转了此前由张东荪主导的革命倾向：舍弃“解放”中所带有的破坏性的战斗精神,对中国传统文明与西方现代文明均取渐进改造方式;同时,不再以社会主义为倡导,从原先的高谈主义,转为研究具体的问题。在思想界整体逐渐走向革命的潮流中,“梁启超系”却通过整顿《改造》,从革命回归改良,成为激进时代的渐进者。