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121.
122.
Hong Mao-Chun Huang Zhi-Ying Cao Rong Jiang Fei-Long Liu Han-Qin State Kev Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou Fujian 《结构化学》1993,(5)
<正> [Au13Ag12(μ-Br)1(μ3-Br)2 (Ph3P)10Br2] Br, monoclinic. space group C2/m, a = 36. 496(17). b=16. 878(7), c-=19. 772(9) A , β=99. 87(5)°, V=11998. 9 A3.Z=2. The final R(Rw) is 0. 097(0. 109) for 3779 reflections with I>3σ(I). The structure can he considered as two icosahedral cluster units (AurAg6) sharing one vertex and linked hy six bromine atoms. The Au - Au, Au - Ag. and Ag-Ag distances fall in the ranges of 2. 69-2. 96. 2. 84-3. 02. and 2. 92-3. 26 A, respectively. 相似文献
123.
X. S. Wu Xuehai Wu Yunping Li Zhangde Lu Liangen Gong Ping Zhou Qing Zhang 《Fiber and Integrated Optics》1993,12(1):97-103
Miniature, etching ridge InGaAsP/InP Phase Modulator with highly efficient phase shifting efficiency of 60°/V.mm and 43°/V.mm for TE and TM modes, respectively, and 3 dB bandwidth of 650 MHz at 1.52 μm are reported. It is well suited for integrated opto-electronics. Some functions depending on bandwidth of the devices are discussed. 相似文献
124.
本文对Brauer第24问题[1]作了推广.利用Dade关于循环块的理论得到如下结果:设G是有限群,P是G的循环Sylowp子群.设|P|=pa,a为正整数.令Pi为P中唯一的pi阶子群,1ia.则|Cl(G)|=|Cl(NG(Pi))|的充分必要条件为PiG. 相似文献
125.
Cao Xuan Chuan 《International Journal of Theoretical Physics》1998,37(9):2439-2448
It is shown that in the case of shapeinvariance, with the use of the mixing functionformalism, exact solvability of the Schrodinger equationcan be obtained without recourse to the technique ofsupersymmetrization. Some consequences of the method are outlinedand illustrated by specific examples. 相似文献
126.
Y.Y. Sun I. Rusakova R.L. Meng Y. Cao P. Gautier-Picard C.W. Chu 《Physica C: Superconductivity and its Applications》1994,230(3-4):435-442
We have carried out a systematic structural, electric, and magnetic study on Y---Pd---B---C samples with different compositions with emphasis on the as-cast and annealed YPd5B3C0.3 which was first reported to superconduct at 23 K by Cava et al. We found that the tetragonal body-centered YPd2B2C with lattice parameters a=3.71 Å and c=10.81 Å is the phase responsible for the 23 K superconductivity and that YPd2B2C is metastable, which is consistent with the suggestion made by Cava et al. [1]: it is not stable at high temperatures nor stabilizable by Ni doping, although its isostructural compound, YNi2B2C, exists. Two new phases with Y:Pd ratios of 1:7 and 2:3, respectively, have also bee detected. 相似文献
127.
本文推导了两种非标准色传感器在测色时引入的误差公式,并对其进行分析。最后通过计算8个样品的颜色对分析结果给于验证。 相似文献
128.
Fa‐Yan Meng Xu‐Qing Liu Seik Weng Ng 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(7):m341-m342
The terephthalate dianion and the bis(imidazolyl)benzene ligand of the title compound, {[Zn(C8H4O4)(C20H14N4)]·C2H6O}n, each bridges two adjacent zinc centers, resulting in a layer‐type coordination polymer; the zinc center shows tetrahedral coordination. The disordered ethanol solvent molecules occupy the spaces between the layers and are hydrogen bonded to the layers. The two symmetry‐independent dianions lie on different inversion sites. 相似文献
129.
A room temperature method for the encapsulation of pyrene in SiO2 nanoparticles is described. The relation between alkoxysilane surfactant chain length, reactant molar ratios and the uptake of dye, sample morphology, photophysical properties, and the ability of the silicate matrix to protect the encapsulated dye was examined. The synthesis can easily be adapted for the encapsulation of other hydrophobic and thermolabile substances, and used in the development of nanostructured optically active coatings, films and monoliths. 相似文献
130.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献