二氧化钛光催化杀灭肿瘤细胞的研究

应用二氧化钛光催化的方法在体外对宫颈癌细胞进行了杀灭试验,结果显示,二氧化钛在光照下对宫颈癌细胞有明显的杀灭作用。当二氧化钛浓度为２００μｇ／ｍｌ,紫外光照时间为５０ｍｉｎ时,其杀灭肿瘤细胞的效果最好。     

超临界干燥法制备TiO2气凝胶

以钛酸四丁酯为原料,采用溶胶-凝胶过程及及超临界干燥法制备了TiO2气凝胶,并通过XRD,BET和TEM等方法对所得样品进行了表征.结果表明,该法制备的TiO2气凝胶具有很高的比表面积(488 m2/g),平均粒径为4.6nm,具有锐钛矿型晶体结构.经400℃煅烧2 h所得的纳米粉体,其锐钛矿型晶体结构更为明显,平均粒径6.7 nm,比表面积158 m2/g.     

激光二极管泵浦的Cr:LiSAF二次谐波产生获得可调谐蓝色激光连续输出

以６７９ｎｍ的激光二极管泵浦１ｍｍ厚掺杂摩尔分数为０．０２２Ｃｒ：ＬｉＳＡＦ,用α－切割的１类非临界位相匹配的ＫＮ晶体进行内腔倍频,在吸收功率在２５６ｍＷ时,得到了峰值３．１５ｍＷ,波长为４３１．７ｎｍ的ＴＥＭ００模蓝色激光输出,激光阈值为９６ｍＷ,斜效率为１．９７％,通过改变ＫＮ晶体的温度,实现了波长范围为４２３．４～４４５．５ｎｍ之间的连续可调谐蓝色激光输出。     

龋病易感儿童头发微量元素含量的分析

为进一步了解龋病发病机理,探求儿童龋病发生,发展与预防与微量元素含量的关系,收集３￣５周岁儿童患龋组４０名和正常对照组４０名的头枕部近头皮处发样２ｇ／人,用原子吸收光谱法测定头发中锌,铜,铁,锰,铅的含量,结果表明未见五种微量元素与龋病有显著相关,微量元素含量与患龋易感关系有待于进一步研究。     

浓悬浮体的屈服应力和最大填充率

对剪切稀化的浓悬浮体,假设在剪切状态下结构参数变化的速率服从一级动力学关系,在此基础上导出浓悬浮体最大填充率与剪应力、屈服应力与填充率之间关系的数学模型．用硅粉－甘油水溶液及可可粉－可可脂两种悬浮体的实验确认了模型对工业微米级颗粒悬浮体的适用性     

相移数字云纹测量系统

介绍了一种相位移数字云纹变形测量系统．测试系统采用ＣＣＤ摄像系统记录光栅图像,控制采样的空间频率大约为光栅线密度的整数倍,对试件栅进行采样后用数字信号处理的方法,实现空间相位移及进行实时数字云纹条纹显示,并对相移误差及光栅信号的高阶谐波的影响进行了校正     

射弹倾斜撞击带盖板炸药引发爆轰的条件

用二级轻气炮发射圆柱形、球形钢射弹以不同的角度撞击带不同厚度钢盖板的 ＴＮＴ／ＲＤＸ（４０／６０）炸药,得到了不同条件下引发炸药爆轰的阈值射弹速度。可以用ｖｄ~　（１／２）＝（１ ＋ｋ）［Ａ＋Ｂｈ／（ｄｃｏｓ）］描述临界引爆条件。对于带钢盖板的ＴＮＴ／ＲＤＸ（４０／６０）炸药,Ａ＝ ３．３３．Ｂ＝５．３４;圆柱形平头射弹撞击,ｋ／７５,球形射弹撞击,ｋ０．５＋０．２（１／ｃｏｓ－１）。由 此,本研究将Ｊａｃｏｂｓ 引爆判据推广到了斜碰撞条件。     

The Neutral Part of the Bark of Pinus Luchuensis Mayer

The neutral part of the acetone extract from the bark of Pinus luchuensis Mayer has been investigated and found to consist of alkanes (C₂₂–C₃₄) and triterpenes of serratene type. The triterpenes are 3β–methoxyserrat–14–en–21–one, serrat–14–en–3, 21–dione, 3β–hydroxyserrat–14–en–21–one, 3β–21α–dimethoxyserrat–l4–ene and 3β–methoxyserrat–14–en–21α–ol.     

Quantum chemical definition and calculation of oxidation number

A new quantum chemical definition of oxidation number is proposed, in the present paper, as a direct generalization of the corresponding classical definition. According to the proposed general definition, the oxidation number can be calculated by use of molecular orbital data and a population analysis method or by use of other quantum chemical methods. For the practical calculation, we present a corresponding concrete calculation procedure within the framework of the maximum overlap population principle, which is very simple and very easy to use. The calculated numerical results are, on the whole, in good agreement with chemists' intuitive concepts of chemical bonding.     

A Comparison of Two Isoreticular Metal–Organic Frameworks with Cationic and Neutral Skeletons: Stability,Mechanism, and Catalytic Activity

Although many ionic metal–organic frameworks (MOFs) have been reported, little is known about how the charge of the skeleton affects the properties of the MOF materials. Herein we report how the chemical stability of MOFs can be substantially improved through embedding electrostatic interactions in structure. A MOF with a cationic skeleton is impervious to extremely acidic, oxidative, reductive, and high ionic strength conditions, such as 12 m HCl (301 days), aqua regia (86 days), H₂O₂ (30 days), and seawater (30 days), which is unprecedented for MOFs. DFT calculations suggested that steric hinderance and the repulsive interaction of the cationic framework toward positively charged species in microenvironments protects the vulnerable bonds in the structure. Diverse functionalities can be bestowed by substituting the counterions of the charged framework with identically charged functional species, which broadens the horizon in the design of MOFs adaptable to a demanding environment with specific functionalities.