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121.
122.
Shuidong Zhang Fang Liu Huaqiao Peang 《Journal of Macromolecular Science: Physics》2015,54(7):836-850
Dialdehyde sweet potato starch (DASS) with various aldehyde contents was prepared and the properties analyzed in terms of solubility, intrinsic viscosity, scanning electron microscopy (SEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). The results demonstrated that when the aldehyede content of DASS was increased from 20% to 95%, the solubility, molecular weight, crystallizability, and thermal stability decreased. Thermoplastic DASS (TPDASS) was prepared by adding glycerol as a plasticizer; the thermal, rheological, hydrophobic, and tensile properties of TPDASS were investigated. The results indicated that, for the same glycerol content, with the increase of aldehyde content, the moisture adsorption decreased, while the shear viscosity, glass transition temperature, and tensile properties of TPDASS increased significantly. The effects were attributed to the introduction of aldehyde groups reducing the hydrogen bonds and decreasing the hydrophility of the starch. Moreover, the aldehyde and hydroxyl groups of DASS favored a semi-acetal formation with higher aldehyde content and cross-linking of DASS occurred with the increase of aldehyde content. In summary, compared to starch, the thermoplastic properties and hydrophobicity of DASS was improved. In the presence of water (10 wt%), the tensile strength of TPDASS with 95% aldehyde content (TPDASS95) moderately decreased, from 16.7 MPa to 14.0 MPa, when the glycerol content increased from 10% to 30%. The TPDASS with improved properties will find their applications in preparing biodegradable plastics. 相似文献
123.
本文通过变分方法,证明包含Hardy位势的奇异椭圆问题-Δu(x)-μ/|x|2u(x)=K(x)f(u),x ∈RN,x在u∈D1,2(RN)中至少有一个非平凡解,其中N≥3,0≤μ≤∶=((N-2)/2)2,f(t)是在R上的连续函数并且在无穷远处渐近线性. 相似文献
124.
Conjugated polymers (CPs) have long been recognized as an important class of materials. The highly conjugated backbone of the CPs will facilitate the rapid exciton migration and result in amplification of fluorescence signals. However, CPs are likely to aggregate and form excimers in solid states, directly leading to the fluorescence quenching, namely aggregation-caused quenching (ACQ), hence inhibiting their prospective utilizations in a large degree. Since the effect of aggregation-induced emission (AIE) is opposite to that of notorious ACQ, the AIE has raised great attention from scientists. CPs with AIE or aggregation-enhanced emission (AEE) features may help to solve the ACQ problem and meanwhile impart polymers with new properties and practical applications. In this review, we summarize the recent progress on the preparation of CPs with AIE or AEE characteristics, where AIE-active luminogens are located at polymer backbones or pendants. Their potential applications including fluorescent sensors, biological probes, and active layers for the fabrication of light-emitting diodes are also described. 相似文献
125.
Ying Zhang Wei Shen Zhongping Ou Weihua Zhu Yuangyuan Fang Karl M. Kadish 《Electroanalysis》2013,25(6):1513-1518
Two iron(I) porphyrins were electrogenerated and then utilized as catalysts for the reductive dechlorination of 1,1‐bis(4‐chlorophenyl)‐2,2,2‐trichloroethane (DDT) in N,N′‐dimethylformamide. No reaction is observed between DDT and the Fe(III) or Fe(II) forms of the porphyrin, but the electrogenerated Fe(I) porphyrin efficiently catalyzes the electroreduction of DDT to give (1,1‐bis(4‐chlorophenyl)‐2,2‐dichloroethane) DDD, (1,1‐bis(4‐chlorophenyl)‐2,2‐dichloroethylene) DDE and (1,1‐bis(4‐chlorophenyl)‐2‐dichloroethane) DDMU as determined by GC‐MS analysis. The reductive dechlorination was monitored by electrochemistry, controlled potential electrolysis and spectroelectrochemistry and a mechanism for the reaction involving the reduced porphyrins and DDT is proposed. Comparisons are also made between the catalytic properties of metalloporphyrins containing iron, cobalt and manganese central metal ions under the same solution conditions. 相似文献
126.
Wen-Yan Ji Xiao-Li Xia Xiao-Hui Ren Fang Wang Hai-Jun Wang Kai-Sheng Diao 《Structural chemistry》2013,24(1):49-54
Ab initio calculations have been performed on the complexes of CF2Cl2 with NO and SO2, and a set of stable configurations for CF2Cl2–NO and CF2Cl2–SO2 were found with no imaginary frequencies by the MP2 method. In addition, the binding energy and the NBO analysis were used to evaluate the relative stability of the complexes. The calculated results indicate that the weak interactions in the CF2Cl2–NO and CF2Cl2–SO2 systems involved are enhanced with the increase of the number of non-covalent bonds. Further studies predict that the CF2Cl2–SO2 system may play a more important role than the CF2Cl2–NO system in environmental problem because the former offers a stronger interaction than the latter. Furthermore, the non-covalent binding interactions of Cl···N and Cl···O for CF2Cl2–NO system, Cl···O, Cl···S and F···S for CF2Cl2–SO2 system, are the dominant forces, which seem to be very significant as a driving force influencing the arrangement of molecules, especially in CF2Cl2–SO2 system. 相似文献
127.
128.
In this work, the calcium phosphate nanoparticles have been produced by new reverse micro emulsion method containing β‐cyclodextrin, poly(oxyethylene)5 nonyl phenol ether and cyclohexane. Scanning electron microscope, transmission electron microscope, fourier transform infrared spectroscope and X‐ray diffraction were used to characterize the particles. The sizes of the nanoparticles were identified between 70‐80 nm. In conclusion, these results suggested that the developed reverse micro emulsion system based nanoparticles seem to be a promising formulation for calcium phosphate nanoparticles synthesis and it has immense potential in delivery of drugs and vaccines. 相似文献
129.
Chi Fang Ting Xiong Jie Hou Jing Wei Gu Mei Hu Sheng 《Journal of Dispersion Science and Technology》2013,34(4):604-610
Amidoxime (AO)/amine co-functionalized polypropylene fiber adsorbents were prepared. The all-polymeric structures were characterized by using Fourier transform infrared spectroscopy (FTIR), optical microscope, contact angle meter and electron spin resonance (ESR) analysis methods, confirming the grafting, modification, and amidoximation stages gravimetrically, spectroscopically, and visually. The properties for the removal of uranyl(VI) from aqueous solutions were investigated. For amidoxime (AO) fiber, high adsorption rate was observed within the first 30 minutes and the plateau value of 40.6% uranium loading (0.0812 mg/g) was reached at around 30 minutes. The adsorption equilibrium for AO/amine fiber was attained within 20 minutes, resulting in the adsorption of 92.6% uranium loading (0.185 mg/g). The percentage of adsorption increases with increasing pH value (2–6), reaches a maximum at pH 6.0 and then remains almost constant for AO/amine fiber, whereas reduces slightly for AO fiber. 相似文献
130.
A hydrophilic and temperature-induced degradation drug, vinorelbine bitartrate (VB)-loaded phosphatidylethanolamin sterically stabilized liposomes (PSLs) were prepared by the thin film hydration method. Liposomes were made of phosphatidylethanolamine: cholesteryl: oleic acid (PE: CHOL: OA, 6:4:3 mass/mass). The mean particle size of the PSLs ranged from 600 to 650 nm. The transmission electron microscope (TEM) images displayed that the shape of the PSLs was multilamellar vesicles with smooth surface. The highest entrapment efficiency (EE) and drug loading capacity (DL) could reach up to 81.2 and 16.6%, respectively. The studies of drug release showed that the drug release could last for much more than 48 hours. The PSLs was evaluated by comparing the rate of release of encapsulated VB in different phosphate buffer solution (PBS). 相似文献