阳离子表面活性剂三甲基溴化铵与硝酸铵相互作用的表面和热力学研究

本文系统研究了阳离子表面活性剂三甲基溴化铵和硝酸铵盐的表面现象和自聚集行为. 采用电导法和表面张力法研究在不同温度下阳离子表面活性剂三甲基溴化铵的表面性质和热力学性质. 通过表面张力测定得到临界胶束浓度、吸附自由能、胶束化的自由能、最小分子面积和表面过量浓度. 该研究表明,胶束化过程是自发放热反应. 电导测定结果确定了临界胶束浓度、电离程度和反离子结合度. 加入硝酸铵盐至表面活性剂溶液后,临界胶束浓度降低,电离程度和反离子结合度增加,更加有利于胶束化过程的自发. 该研究对进一步理解电解质和表面活性剂之间相互作用具有重要意义.     

Extended finite element modeling of production from a reservoir embedded with an arbitrary fracture network

A numerical scheme based on the eXtended Finite Element Method (XFEM) is proposed to simulate complex fluid flow in a fractured porous reservoir. By enriching the elements fully cut by the fracture and the near‐tip region, the flow mechanism including the tip flux singularity can be exactly represented in the XFEM formulation. Fluid transfer between the matrix and the fractures can be easily coupled, and XFEM also overcomes the sensitivity to the mesh used in the traditional unstructured discretizations, regardless of the complexity of the fracture network. The method is validated for a simple case by the exact analytical solution. Results are compared between XFEM and FEM. Case studies are presented to illustrate the power, efficiency, accuracy, and flexibility of the proposed method for simulating transient productive flow in reservoirs with complex fracture networks.     

基于能量耗散的岩石脆性评价方法

脆性评价是页岩气钻井以及压裂工艺设计的重要环节.然而,现今对于脆性的定义十分模糊,且脆性评价的方法没有成熟的理论作为支撑.本文以岩石应力应变关系为基础,采用能量法来进行储层岩石脆性评价.根据断裂力学裂纹尖端的非线性场理论,以前端区作为尖端特殊的屏蔽构型,来描述储层岩石在断裂过程中能量的耗散. 通过计算本征内聚力与前端区稳态阻力比值来表征储层岩石的脆性指数. 研究表明,能量耗散相对越大,岩石的脆性指数越低,其塑性特征表现得越明显. 基于能量耗散的储层岩石脆性评价是分析岩石力学特性的重要内容,也为压裂选层提供了重要依据.      

利用正交实验法探究铁与水蒸气反应的最佳实验条件

通过设计装置简单、操作简便、安全性高的铁与水蒸气反应的实验,以反应物的放置方式、铁粉的质量以及Ca(OH)2的质量为探究因素,利用正交实验法探究出最佳实验条件,提高实验成功率,并缩短实验时间。     

Structural phase transition behaviour of ZnaSb3 and its substitutional compounds （Zn0.98M0.02）4Sb3 （M = Al,Ga and In） at low temperatures

Structural phase transitions of Zn4Sb3 and its substitutional compounds (Zn0.98M0.02)4Sb3 (M = Al, Ga and In) are investigated by electrical transport measurement and differential scanning calorimetry below room temperature. The results indicate that both β→α and α→α′ phase transitions of Zn4Sb3 are reversible and exothermic processes, which may be explained as that both the transitions originate from the ordering of the disordered interstitial Zn and vacancies in regular sizes. The derived activation energies of β→α and α→α′ phase transition processes for Zn4Sb3 are E1 = 3.9 eV and E2 = 4.1 eV, respectively. Although no remarkable influence on activation energy E2 is observed after Al doping, Al substitution for Zn causes E1 to increase to 4.6 eV, implying its suppression of βα transition to a great extent. Moreover, it is found that both βα and αα′ transitions are completely prohibited by substitution of either In or Ga for Zn in Zn4Sb3. The underlying mechanisms for these phenomena are discussed.     

一类带干扰的多险种风险模型

本文考虑一类带干扰的两独立险种的风险模型,其中两索赔次数过程分别为Poisson过程和Elang(2)过程.主要得出该模型的生存概率所满足的积分-微分方程和破产概率的渐近性.     

Parameter Determination Using 3D FIB-SEM Images for Development of Effective Model of Shale Gas Flow in Nanoscale Pore Clusters

A large amount of nano-pores exists in pore clusters in shale gas reservoirs. In addition to the multiple transport regimes that occur on the nanoscale, the pore space is another major factor that significantly affects the shale gas recoverability. An investigation of the pore-scale shale gas flow is therefore important, and the results can be used to develop an effective cluster-scale pore network model for the convenient examination of the process efficiency. Focused ion beam scanning electron microscope imaging, which enables the acquisition of nanometre-resolution images that facilitate nano-pore identification, was used in conjunction with a high-precision pore network extraction algorithm to generate the equivalent pore network for the simulation of Darcy and shale gas flows through the pores. The characteristic parameters of the pores and the gas transport features were determined and analysed to obtain a deeper understanding of shale gas flow through nanoscale pore clusters, such as the importance of the throat flux–radius distribution and the variation of the tortuosity with pressure. The best parameter scheme for the proposed effective model of shale gas flow was selected out of three derived schemes based on the pore-scale prediction results. The model is applicable to pore-scale to cluster-scale shale gas flows and can be used to avoid the multiple-solution problems in the study of gas flows. It affords a foundation for further study to develop models for shale gas flows on larger scales.     

Experimental determination of one-and two-neutron separation energies for neutron-rich copper isotopes

A method is proposed to determine the one-neutron S_n or two-neutron S_(2n) separation energy of neutronrich isotopes.Relationships between S_n(S_(2n)) and isotopic cross sections have been deduced from an empirical formula,i.e.,the cross section of an isotope exponentially depends on the average binding energy per nucleon B/A.The proposed relationships have been verified using the neutron-rich copper isotopes measured in the 64 A Me V ~(86)Kr+~9Be reaction.S_n,S_(2n),and B/A for the very neutron-rich ~(77,78,79)Cu isotopes are determined from the proposed correlations.It is also proposed that the correlations between S_n,S_(2n) and isotopic cross sections can be used to find the location of neutron drip line isotopes.     

A fault-tolerant small world topology control model in ad hoc networks for search and rescue

Due to their self-organized, multi-hop and distributed characteristics, ad hoc networks are useful in search and rescue. Topology control models need to be designed for energy-efficient, robust and fast communication in ad hoc networks. This paper proposes a topology control model which specializes for search and rescue—Compensation Small World-Repeated Game (CSWRG)—which integrates mobility models, constructing small world networks and a game-theoretic approach to the allocation of resources. Simulation results show that our mobility models can enhance the communication performance of the constructed small-world networks. Our strategy, based on repeated game, can suppress selfish behavior and compensate agents that encounter selfish or faulty neighbors. This model could be useful for the design of ad hoc communication networks.