气相色谱法测定缩水甘油丁酸酯

采用气相色谱快速分析方法测定环氧氯丙烷反应体系中的缩水甘油丁酸酯.采用SE-30( φ3mm×1.5mm)填充柱,载气流量:48.86mL/min;柱温:100℃;气化室温度:185℃;热导检测器温度185℃;缩水甘油丁酸酯的量(x)与峰面积(y)有良好的线性关系; y=1594.1x+1370.1,R2=0.9993...     

Enhancement of light-emitting efficiency using combined plasmonic Ag grating and dielectric grating

Based on the analysis of the near-field evanescent wave in total internal reflection, the flip-chip light-emitting diode (LED) structure was proposed by placing a plasmonic Ag grating and a perforated sapphire grating in the substrate. The finite difference time domain (FDTD) method has been applied to study the spectral properties of the hybrid structure and the enhancement factor of light extraction efficiency of the LED model. From the computation examples, the effects of structure parameters on the extraction enhancement have been investigated. The results indicate that the plasmonic grating can enhance the near-field evanescent wave and couple it to propagation wave in the specific wavelength bands, which leads to the photons emitting out of the LED chip with high extraction efficiency. Due to the combined gratings used, the enhancement factor of the light extraction efficiency can reach approximately 4 times at a relatively longer wavelength.     

Numerical study of an ion-exchanged glass waveguide using both two-dimensional and three-dimensional models

A numerical study is carried out to compare the two-dimensional (2-D) case and three-dimensional (3-D) case for the modelling of an ion-exchanged glass waveguide. It is shown that different waveguide widths on the photomask correspond to different ion concentration distributions after an annealing process. A numerical example is presented of two waveguide sections with different widths indicates that due to the abrupt change of the waveguide width, a 3-D theoretical model is required for an accurate prediction of the parameters of ion-exchanged glass waveguides. The good agreement between the modelled and measured results proves that the developed 3-D numerical model can be beneficially utilized in the generalized design of optical devices based on ion-exchange waveguides.     

Polarization beam splitter based on photonic crystal self-collimation Mach-Zehnder interferometer

A polarization beam splitter based on a self-collimation Mach-Zehnder interferometer (SMZI) in a hole-type silicon photonic crystal was proposed and numerically demonstrated. Utilizing polarization dependence of the transmission spectra of the SMZI and polarization peak matching (PPM) method, the SMZI can work as a polarization beam splitter (PBS) by selecting appropriate path length difference in the structure. Because of its intrinsic operating principle, the PBS possesses high polarization extinction ratios (PERs). As its dimensions are only several operating wavelengths, the PBS may have practical applications in photonic integrated circuits.     

Injection-seeded Tm:YAG laser at room temperature

The solid-state, tunable, narrowband, high pulse energy and high reliability lasers are attractive source for LIDAR system. In this paper, we demonstrated a diode pumped injection-seeded 2 μm Tm:YAG laser. By inserting two F-P etalons into the laser cavity, linear-polarized single-frequency seed-laser was achieved at a wavelength of 2013 nm, with a maximum output power of 60 mW. Long-term and short-term frequency stability for the seed-laser were 1.27 × 10^− 7 and 97 Hz/μs, respectively. High power Q-switched laser was operated using a bowtie cavity, the bidirectional output of which was favorable for the injection-seeded. After injecting the seed-laser to the power-laser, single-frequency, nearly transform-limited pulsed 2 μm laser was obtained. As much as 2.0 mJ output energy was achieved at an operating repetition rate of 15 Hz, with a pulse width of 356.2 ns.     

Exact solutions for a type of electron pairing model with spin-orbit interactions and Zeeman coupling

A type of electron pairing model with spin-orbit interactions or Zeeman coupling is solved exactly in the framework of the Richardson ansatz. Based on the exact solutions for the case with spin-orbit interactions, it is shown rigorously that the pairing symmetry is of the p + ip wave and the ground state possesses time-reversal symmetry, regardless of the strength of the pairing interaction. Intriguingly, how Majorana fermions can emerge in the system is also elaborated. Exact results are illustrated for two systems, respectively, with spin-orbit interactions and Zeeman coupling.     

Confinement-deconfinement interplay in quantum phases of doped Mott insulators

In the t-J model, the electron fractionalization is dictated by the phase string effect. We find that in the underdoped regime, the antiferromagnetic and superconducting phases are dual: in the former, holons are confined while spinons are deconfined, and vice?versa in the latter. These two phases are separated by a novel phase, the so-called Bose-insulating phase, where both holons and spinons are deconfined. A pair of Wilson loops was found to constitute a complete set of order parameters determining this zero-temperature phase diagram. The quantum phase transitions between these phases are suggested to be of non-Landau-Ginzburg-Wilson type.     

Ce3+离子激活的(氟)磷酸盐基质发光材料的光谱特性

利用高温固相反应方法合成了Ce3+离子激活的氟磷酸盐基质发光材料NNa2Gd0.99Ce0.001PO4F2和多磷酸盐基质发光材料MGd0.99Ce0.01(P03)4(M=Na,K,Cs).通过光谱研究发现,在Na:Gd0 99ce-tP0.F:的真空紫外-紫外(VUV-UV)激发光谱上,可以看到Ce3+离子中心波长...     

无氧铜环颈缩区孔洞长大与局域化温升效应研究

 利用金相显微镜,对电磁加载下无氧铜（M态TU1）环碎片的颈缩部位进行了金相分析,观察到了颈缩区孔洞长大、汇通及孔洞壁熔化现象。利用球形孔洞模型,分析了颈缩区孔洞长大条件,发现周向偏应力更适合于描述膨胀环颈缩区的孔洞长大。据此,讨论了颈缩区的局域化温升效应。研究结果为延性金属环膨胀颈缩失稳的细观机理研究提供参考。