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991.
ZHANG Qiang ZHOU Jifu & LI Jiachun Institute of Mechanics Chinese Academy of Sciences Beijing 《中国科学G辑(英文版)》2005,48(4):469-484
As one of the important coherent structures in the near-wall region, turbulent burst is responsible for the production and transport of major turbulent kinetic energy and Rey- nolds stress[1]. Nearly half of turbulent kinetic energy or Reynolds stress is produced in the near-wall region, and 80% flows in outer region only contribute 20% of them. Both ejection and sweeping events contribute 60―70% of the turbulent shear stress respec- tively[2]. Recently, turbulent burst process has been foun… 相似文献
992.
Köhn RD Pan Z Haufe M Kociok-Köhn G 《Dalton transactions (Cambridge, England : 2003)》2005,(16):2793-2797
As the first 1st-row transition metal complexes having six tertiary amine donor groups, bis(triazacyclohexane) sandwich complexes [L2M](BF4)2 (L = benzyl- or p-fluorobenzyl-triazacyclohexane, M = Cu or Zn) have been obtained by the protonolysis of Et2Zn in the presence of L or by reaction of [Cu(MeCN)4](BF4) with L in CH2Cl2 and subsequent air oxidation via an unprecedented Cu(I)(2) sandwich complex containing a short Cu-Cu contact. 相似文献
993.
In situ self-assemblies of new biodegradable triblock PLLA-b-PBS-b-PLLA and PDLA-b-PBS-b-PDLA have been investigated in acetonitrile solution. At first, two series of PLLA-b-PBS-b-PLLA and PDLA-b-PBS-b-PDLA, respectively denoted as the P and Q triblock copolyester series, were prepared with fixed PBS block ((overline) M(n,NMR) = 6.9 kDa) and diverse enantiomeric PLLA/PDLA blocks. Further, their chemical structures and thermal properties were characterized by means of titration, nuclear magnetic resonance spectroscopy (NMR), gel permeation chromatography (GPC), polarimeter, wide-angle X-ray diffraction (WAXD) and thermal analytical instruments. When mixing the synthesized enantiomeric copolyester pairs denoted as P(1)/Q(1) - P(8)/Q(8) in acetonitrile solution at 60 degrees C, in situ self-assemblies were found to happen for the P(4)/Q(4) to P(8)/Q(8) pairs, bearing longer enantiomeric PLA block lengths. DSC and WAXD analysis of the self-assembled microparticles demonstrated that PLLA/PDLA racemic crystals were formed for the P(5)/Q(5) - P(8)/Q(8) systems, as evidenced by their melting points over 200 degrees C, and a new X-ray diffraction peak detected at 2theta = 11.8 degrees . Moreover, morphological studies by scanning electron microscopy (SEM) indicated the formation of disk- or platelet-like microparticles. It was noted that the diameters of the microparticles self-assembled in situ decreased from 1.28-1.50 mum down to 480-660 nm, through tailoring the enantiomeric PLA block length. Other factors, such as a central PBS block, the enantiomeric block length and the preparation conditions were suggested to play important roles in the in situ self-assembly of these enantiomeric triblock copolyesters. These results provide a facile way to self-assemble hydrophobic, biodegradable microparticles, through tuning the important van der Waals stereocomplexation interactions between two enantiomeric blocks in solution. 相似文献
994.
Gan Q Song G Xu Y Gao J Cao Q Pan X Zhong Y Yang G Zhu X Chen L 《Optics letters》2005,30(12):1470-1472
The fabrication of very-small-aperture lasers is demonstrated, and their performance is analyzed. Because of strong optical feedback caused by a gold film on the front facet of the laser, its behavior changes: The threshold current decreases, the density of light inside the laser diode and the redshift effect of the spectra are enhanced, and the laser diode's lifetime is shorter than that of common laser diodes with large driving current. 相似文献
995.
Yang HB Pan ZH Sekharan AK Sato T Souma S Takahashi T Jin R Sales BC Mandrus D Fedorov AV Wang Z Ding H 《Physical review letters》2005,95(14):146401
We report a systematic angle-resolved photoemission study on Na(x)CoO2 for a wide range of Na concentrations (0.3 < or = x < or = 0.72). In all the metallic samples at different x, we observed (i) only a single holelike Fermi surface centered around gamma and (ii) its area changes with x according to the Luttinger theorem. We also observed a surface state that exhibits a larger Fermi surface area. The e'(g) band and the associated small Fermi surface pockets near the K points predicted by band calculations are found to sink below the Fermi energy in a manner almost independent of the doping and temperature. 相似文献
996.
997.
[reaction: see text] A total synthesis of the complex, biologically active, dimeric natural product (+/-)-torreyanic acid, which is composed of seven rings and laced with dense, variegated oxy-functionalization, has been accomplished from readily available allyl-substituted p-benzoquinone 8. Our synthetic stratagem involves crafting an epoxyquinone monomer for use in a biomimetic cascade process involving tandem a 6pi electrocyclization and a Diels-Alder dimerization. 相似文献
998.
Xun?Gu Selcuk?Akturk Aparna?Shreenath Qiang?Cao Rick?TrebinoEmail author 《Optical Review》2004,11(3):141-152
We review the state of the art of ultrashort-light-pulse measurement using frequency-resolved-optical-gating (FROG). Recent developments have extended the state of the art considerably. FROG devices for measuring the intensity and phase of ultrashort laser pulses have become so simple that almost no alignment is required. In addition, such devices not only operate single shot, but they also yield the two most important spatio-temporal distortions, spatial chirp and pulse-front tilt. With other FROG variations, it is now possible to measure more general ultrashort light pulses (i.e., pulses much more complex than common laser pulses), with time-bandwidth products as large as several thousand and as weak as a few hundred photons, and despite other difficulties such as random absolute phase and poor spatial coherence. 相似文献
999.
LI Qiang ZHU Yuying HE Yunha WANG Xu LI Gong YU Jinku & SU Zhibin .Key Laboratory of Metastable Materials Science &Technology Yanshan University QinhuangdaO China .Department of Mechanical Engineering Yanshan University Qinhuangdao China .Department of Environmental & Chemical Engineering Yanshan University QinhuangdaO . China 《中国科学G辑(英文版)》2004,47(5):581-587
~~Undercooling and solidification of germanium melts studied by differential scanning calorimeter~~ 相似文献
1000.
Lü Baida & PAN Liuzhan . Institute of Laser Physics Chemistry Sichuan University Chengdu China . Department of Physics Luoyang Normal College Luoyang China . State Key Laboratory of Laser Technology Huazhong University of Science Technology Wuhan China Correspondence should be addressed to L Baida 《中国科学G辑(英文版)》2004,47(1):24-35
Inrecentyearsanewbranchofmodernphysicalopticscalledsingularoptics[1]hasbeendeveloped.In2002theworkinsingularopticswasextendedfrommonochromaticlighttospatiallyfullycoherentandpolychromaticlightbyGburetal.[2—4].Itwasfoundthat,whenaconverging,spatiallyfullycoherentandpolychromaticsphericalwaveisdiffractedatanaperture,anomalousspectralchangestakeplaceclosetozerosoftheintensityinthefarfield;i.e.thespectrumisredshiftedatsomepoints,blueshiftedatothers,andsplitintotwolineselsewhere.Thepredictionsofsp… 相似文献