Enhancement of photocurrent generation by honeycomb structures in organic thin films.

A light-emitting poly (distyryldimethylbenzene-co-triethylene glycol) rod-coil block copolymer was used to fabricate films with three-dimensionally ordered honeycomb structures by the breath-figure method. Photocurrent generation and photovoltaic performance are studied, and the dependence of photocurrent on applied electric field is investigated. Introducing the ordered porous structure significantly improves the photoelectric conversion behavior, because porous structures not only enhance the light-harvesting efficiency but also benefit charge separation and charge transfer. This phenomenon may have great prospects for enhancing the photovoltaic behavior of organic thin-film devices.     

Epoxy-based azo molecular glasses with four-arm architecture: Preparation,characterization and holographic recording

A series of epoxy-based azo molecular glasses with four-arm architecture was synthesized, characterized and applied to holographic recording.     

烯烃聚合数学模拟研究与现状

综述了近年来国内外在烯烃聚合微观形态和宏观反应器数学模拟方面取得的研究成果，指出了烯烃聚合过程数学模拟的发展方向。     

汞的形态分析研究 Ⅱ.固相萃取预富集-液相色谱分离测定不同形态的有机汞

本文报道了固相萃取预富集处理样品继以液相色谱分离测定不同形态痕量有机汞的方法.二乙基二硫代氨基甲酸钠(DDTC)作络合剂及甲醇作洗脱液的预富集系统能在线富集甲基汞(MeHg)、乙基汞(EtHg)和苯基汞(PhHg).用于测定加标海水中MeHg、EtHg和PhHg,回收率分别为96.9％、102.4％和98.0％;相对标准偏差分别为3.5％、5.0％和5.0％;检测下限分别为 1.0μg/L、1.2 μg/L和 1.2 μg/L.     

活性碳分离碳－60和碳－70

活性碳用苯胺处理后，可以减少对Ｃ＿（６０）和Ｃ＿（７０）的不可逆吸附，从而增加Ｃ＿（６０）和Ｃ＿（７０）的分离收率，同时提高了Ｃ＿（７０）的纯度。     

反相高效液相色谱法半制备分离[T(4-MOP)PS4]卟啉的研究

本文研究了新水溶性5，10，15，20-四(4-甲氧基-3-磺酸苯基)卟啉[T(4-MOP)PS4]的反相高效液相色谱(HPLC)分离条件。采用Shimpack PREP-ODS半制备色谱柱，用含有10mmol／L四乙基碘化铵的乙腈-水(体积比25：75)为流动相，流速18mL/min，于418nm波长下检测。[T(4-MOP)PS4]与合成中生成的杂质组分完全分离。经此制备的卟啉纯度高，已成功地应用于自来水样中微量钴、锌、铜离子的HPLC测定中。     

CVD法不同条件下制备的多壁碳纳米管的Fenton氧化改性

碳纳米管经焙烧和稀硝酸纯化处理后,在相同的实验条件下,采用Fenton试剂产生的·OH分别对CVD法合成的两种制备条件不同的多壁碳纳米管进行氧化改性处理。红外光谱(FT IR)表明,改性后的两种碳管结构中都引入了羟基、羰基和羧基等含氧官能团。此外,由于制备条件不同,导致它们的石墨化程度、缺陷含量和抗氧化能力等性质也不同,因此CVD法制备条件能够对碳管Fenton氧化改性结果产生重要影响。机理分析表明,这些含氧官能团可以看作是具有强亲电性和强氧化性的·OH对碳管上缺陷位置和不饱和键进行攻击的结果。     

New Type High Efficient Quasi-Solid-State Ionic Liquid Electrolyte for Dye-Sensitized Solar Cells

For the fist time the preparation of a mostly solid-state high efficiem electro-conductive material comprising 1-methyl-3-propylimidazolium iodide （MPII）, benzimidazole （BI）, iodine and lithium iodide was reported. In this electrolyte, BI acts as not only additives but also gelators. With its significant electrochemical properties, an overall efficiency of 3.07% was achieved under AM 1.5 （100 mW/cm^2）.     

A new Co(II) complex with N,O-donor Schiff base: Synthesis, structure and characterization

A new Co(II) complex with tridentate Schiff base ligand with a N,N,O donor set has been synthesized and characterized by single X-ray technique and spectroscopic techniques. The thermochemical properties have been studied. X-ray structure analysis of the title compound Co(II)L₂ [HL = 2-methyl-6-(2′-hydroxybenzylideneamino) pyridine] shows that the polyhedron around Co(II) is a distorted tetrahedron, and the self-assembly via intermolecular π-π interactions leads to a three-dimensional network. Crystal data for the title complex C₂₆H₂₂CoN₄O₂: Monoclinic, space group Ia, a = 11.741(7) Å, b = 8.149(5) Å, c = 22.764(16) Å, β = 98.530(12)°, V = 2154(2) ų, Z = 4.     

Gd_3Al_5O_(12)∶Eu~(3+)柠檬酸盐硝酸盐燃烧法合成及其发光性能研究

采用柠檬酸盐硝酸盐燃烧法,在较低的温度(900℃)下成功地合成单一晶相Gd3Al5O12∶Eu3+发光粉体,紫外激发荧光光谱分析表明,粉体615 nm和593 nm荧光发射源于Eu3+的5D0-7F2和5D0-7F1跃迁.该方法中各工艺条件(如pH值、柠檬酸/金属离子比、煅烧温度)对Gd3Al5O12∶Eu3+发光性能均有影响,通过试验得出了获得最佳发光性能荧光粉体的工艺参数.