首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9715篇
  免费   1498篇
  国内免费   1335篇
化学   7547篇
晶体学   157篇
力学   492篇
综合类   80篇
数学   1030篇
物理学   3242篇
  2024年   32篇
  2023年   212篇
  2022年   336篇
  2021年   388篇
  2020年   476篇
  2019年   490篇
  2018年   358篇
  2017年   383篇
  2016年   464篇
  2015年   487篇
  2014年   551篇
  2013年   740篇
  2012年   827篇
  2011年   889篇
  2010年   632篇
  2009年   545篇
  2008年   654篇
  2007年   519篇
  2006年   475篇
  2005年   410篇
  2004年   316篇
  2003年   272篇
  2002年   330篇
  2001年   244篇
  2000年   208篇
  1999年   167篇
  1998年   117篇
  1997年   123篇
  1996年   129篇
  1995年   121篇
  1994年   110篇
  1993年   87篇
  1992年   68篇
  1991年   60篇
  1990年   54篇
  1989年   56篇
  1988年   39篇
  1987年   26篇
  1986年   32篇
  1985年   41篇
  1984年   21篇
  1983年   19篇
  1982年   11篇
  1981年   11篇
  1980年   6篇
  1979年   2篇
  1977年   2篇
  1966年   1篇
  1959年   2篇
  1957年   3篇
排序方式: 共有10000条查询结果,搜索用时 625 毫秒
71.
Stopband phenomena are reported in the passband of left-handed metamaterials. The samples with linear defect are designed by removing one layer of split ring resonators (SRRs). It is shown that the left-handed transmission peaks have a distinct transform with the relative deviation of the SRRs centre from the wire centre 8, from a single left-handed peak, double left-handed peaks with different magnitude to no transmission peak, i.e. left-handed properties of metamaterials disappear. Numerical simulation shows that the change of 8 makes the effective permeability shift at a frequency range, where stopband occurs. It is thought that the stopband in left-handed passband is due to the symmetry breaking between SRRs and wires in the metamaterials.  相似文献   
72.
Using the Laplace transformation, the kinetic theory of the high-relativistic electron cyclotron maser having a novel open-resonator-the axisymmetrical quasioptical cavity of oblique rotation at arbitrary angle, is carried out within the framework of the linearized Vlasov-Maxwell equations. The beam-wave interaction power, starting current and frequency shift have been derived and numerically calculated. The influence of rotation angle on the beam-wave interaction is also studied. A series of important conclusions obtained reveal the characteristics of this novel quasioptical electron cyclotron maser  相似文献   
73.
王正荣  张伯珩 《光子学报》1996,25(11):1048-1053
本文介绍了我们研制的“运动粒子瞬态激光全息测试仪”电子线路.该电路经严格的逻辑设计及计算,采用了10MHz时钟电路,并将1MHz的时钟信号巧妙地引入门控电路中,同时在技术上采用了行之有效的措施,消除了可能产生0.1μs的随机误差,时间间隔达到了(1~9)±0.1μs的精度,所输出的激光双脉冲能量接近,整机抗干抗能力强,一次性试验成功率高,可精确地测量雾化粒子场中的微粒的速度、形状、大小及其分布,收到了良好的使用效果.  相似文献   
74.
75.
In this paper we prove that (1<p<+∞), give the characteristics of xo and the optimal subspace for n-width dn in space X=l n N . Where dn in the n-width, in the sense of Kolmogorov, ofD in X, dn is the n-width ofD with respect to X, in the sense of Gel'fand, δ is the linear n-width ofD with respect to X.  相似文献   
76.
77.
78.
A novel method for the surface modification of a microporous polypropylene membrane by tethering phospholipid analogous polymers (PAPs) is given, which includes the photoinduced graft polymerization of N,N-dimethylaminoethyl methacrylate (DMAEMA) and the ring-opening reaction of grafted poly-(DMAEMA) with 2-alkyloxy-2-oxo-1,3,2-dioxaphospholanes. Five 2-alkyloxy-2-oxo-1,3,2-dioxaphospholanes, containing octyloxy, dodecyloxy, tetradecyloxy, hexadecyloxy, and octadecyloxy groups in the molecular structure, were used to fabricate the PAP-modified polypropylene membranes. The attenuated total reflectance FT-IR spectra of the original, poly(DMAEMA)-grafted, and PAP-modified membranes confirmed the chemical changes on the membrane surface. Scanning electron microscope pictures showed that, compared with the original membrane, the surface porosities ofpoly(DMAEMA)-grafted and PAP-modified membranes were somewhat reduced. Water contact angles measured by the sessile drop method on PAP-modified membranes were slightly lower than that on the original polypropylene membrane, but higher than those on poly(DMAEMA)-grafted membranes with the exception of octyloxy-containing PAP-modified membranes. However, BSA adsorption experiments indicated that the five PAP-modified membranes had a much better protein-resistant property than the original polypropylene membrane and the poly(DMAEMA)-grafted membranes. For hexadecyloxy- and octadecyloxy-containing PAP-modified membranes, almost no protein adsorption was observed when the grafting degree was above 6 wt %. It was also found that the platelet adhesion was remarkably suppressed on the PAP-modified membranes. All these results demonstrate that the described approach is an effective way to improve the surface biocompatibility for polymeric membranes.  相似文献   
79.
Seven transition metal molybdovanadoarsenic heteropoly compounds have been synthesized and characterized using IR, UV, TG-DTA, pH potential titration techniques. The molecular formulae of these compounds are pro-posed to be HxMyAsMO10V2O40·zH2O(x=1~3, y=1,2, M=Cr, Mn, Fe, Co, Ni, Cu, Zn).They are all keggin structure. Surface nature of these compounds have been investigated by temperature programmed desorption and temperature programmed reduction techniques. NH3-TPD results show that in TPD profiles of the compounds there are two desorption peaks corresponding to weak acid sites of desorption, respectively. Desorbing activativon energy and preexponential factor of weak acid site of desorption for compounds have been calculated. H2-TPR re-sults show that introducting transtion metal to molybdovanarsenic acid, the reduction peak temperatures of H2-TPR shift regularly with increasing d electron numbers of transition metals. In addition, Zn and Cu heteropoly com-pounds have yet apparent effect of hydrogen spill over.  相似文献   
80.
我们曾报道CO_2/H_2在CuO-ZnO及CuO-ZnO-ZrO_2催化剂上低压合成甲醇的反应,指出CuO-ZnO-ZrO_2对CO_2/H_2制甲醇具有较高的活性和选择性。本文通过TPD-MS测试研究了第3组分ZrO_2的加入对CO_2/H_2在CuO-ZnO-ZrO_2催化剂上低压合成甲醇的促进作用。 1 实验部分 催化剂的评价在恒压流动反应系统内进行。用色谱仪分析产物(Porapak Q柱,4 mm×3m,柱温120℃,CO、CO_2、CH_3OH、H_2O的保留时间分别为0.55、0.84、4.72、6.6 min),热  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号