全文获取类型
收费全文 | 8690篇 |
免费 | 1397篇 |
国内免费 | 1264篇 |
专业分类
化学 | 6748篇 |
晶体学 | 145篇 |
力学 | 463篇 |
综合类 | 84篇 |
数学 | 874篇 |
物理学 | 3037篇 |
出版年
2024年 | 32篇 |
2023年 | 196篇 |
2022年 | 366篇 |
2021年 | 367篇 |
2020年 | 444篇 |
2019年 | 451篇 |
2018年 | 326篇 |
2017年 | 358篇 |
2016年 | 420篇 |
2015年 | 452篇 |
2014年 | 522篇 |
2013年 | 680篇 |
2012年 | 747篇 |
2011年 | 824篇 |
2010年 | 574篇 |
2009年 | 496篇 |
2008年 | 591篇 |
2007年 | 467篇 |
2006年 | 421篇 |
2005年 | 358篇 |
2004年 | 268篇 |
2003年 | 235篇 |
2002年 | 269篇 |
2001年 | 190篇 |
2000年 | 172篇 |
1999年 | 138篇 |
1998年 | 104篇 |
1997年 | 105篇 |
1996年 | 104篇 |
1995年 | 106篇 |
1994年 | 101篇 |
1993年 | 82篇 |
1992年 | 56篇 |
1991年 | 49篇 |
1990年 | 45篇 |
1989年 | 50篇 |
1988年 | 30篇 |
1987年 | 25篇 |
1986年 | 27篇 |
1985年 | 36篇 |
1984年 | 19篇 |
1983年 | 15篇 |
1982年 | 10篇 |
1981年 | 10篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1959年 | 2篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
211.
增塑剂对1,1,1-三[1′-(2′-氧杂-4′-氧代-5′-氮杂-5′-甲基)十二烷基]丙烷PVC膜钠离子电极性能的影响 总被引:2,自引:0,他引:2
以1,1,1-三[1′-(2′-氧杂-4′-氧代-5′-氮杂-5′-甲基)十二烷基]丙烷(即ETH 227,Fluka No.71732)为中性载体的钠离子选择电极由于具有较强的抗钾离子干扰的能力,因而颇受注意。Guggi等首先用邻硝基苯辛醚和癸二酸二丁酯增塑,以合成的ETH227制成了K_((Na)~+,K~+)~(pot),<<10~(-2)的PVC膜钠离子电极.Jenny等以癸二酸二异辛酯为增塑剂, 相似文献
212.
213.
Nanocrystalline Mo2C powders were successfully synthesized at 500 °C by reacting molybdenum chloride (MoCl5) with C (graphite or carbon nanotube) in metallic sodium medium. X-ray powder diffractometer (XRD), transmission electron microscope (TEM), X-ray photoelectron spectroscope (XPS) and surface area analyzer (BET method) were used to characterize the samples. Experiments reveal that the carbon source used for the carbide synthesis has a great effect on the particle size and the surface area of the samples. When micro-sized graphite was used as C source the obtained nanocrystalline Mo2C powder consists of particles of 30∼100 nm, with a surface area of 2.311 m2/g. When carbon nanotubes were used as C source, the as-synthesized Mo2C sample is composed of particles of 20∼50 nm, with a surface area of 23.458 m2/g, which is an order of magnitude larger than that of the carbide prepared from the graphite. 相似文献
214.
Yuchuan Zhang Jiasheng Qian Zhuo KeXiangcheng Zhu Hong BiKangming Nie 《European Polymer Journal》2002,38(2):333-337
The intermolecular interactions between poly(vinyl chloride) (PVC) and poly(vinyl acetate) (PVAc) in tetrahydrofuran (THF), methyl ethyl ketone (MEK) and N,N′-dimethylformamide (DMF) were thoroughly investigated by the viscosity measurement. It has been found that the solvent selected has a great influence upon the polymer-polymer interactions in solution. If using PVAc and THF, or PVAc and DMF to form polymer solvent, the intrinsic viscosity of PVC in polymer solvent of (PVAc+THF) or (PVAc+DMF) is less than in corresponding pure solvent of THF or DMF. On the contrary, if using PVAc and MEK to form polymer solvent, the intrinsic viscosity of PVC in polymer solvent of (PVAc+MEK) is larger than in pure solvent of MEK. The influence of solvent upon the polymer-polymer interactions also comes from the interaction parameter term Δb, developed from modified Krigbaum and Wall theory. If PVC/PVAc blends with the weight ratio of 1/1 was dissolved in THF or DMF, Δb<0. On the contrary, if PVC/PVAc blends with the same weight ratio was dissolved in MEK, Δb>0. These experimental results show that the compatibility of PVC/PVAc blends is greatly associated with the solvent from which polymer mixtures were cast. The agreement of these results with differential scanning calorimetry measurements of PVC/PVAc blends casting from different solvents is good. 相似文献
215.
S.H. LiuX.F. Qian J. YinL. Hong X.L. WangZ.K. Zhu 《Journal of solid state chemistry》2002,168(1):259-262
Ag2S nanoparticles in hyperbranched polyurethane matrix were prepared through the in situ reaction with thioacetamide as the sulfur source at room temperature. Transmission electron microscopic analysis revealed a uniform spherical shape for Ag2S nanoparticles, with an average size of about 4-10 nm and a narrow size distribution. X-ray powder diffraction and UV-vis spectroscopy were also used to characterize the obtained nanoparticles 相似文献
216.
Shen Chao-Hong Bao Bo-Rong Wang Gao-Dong Qian Jun Bao Ya-Zhi Cao Zheng-Bai 《Journal of Radioanalytical and Nuclear Chemistry》1992,162(2):207-216
Extraction of uranium(VI), thorium(IV) from nitric acid has been studied with N-octylcaprolactam and N-(2-ethyl)hexylcaprolactam. Distribution coefficients of U(VI), Th(IV) and HNO3 as a function of aqueous NHO3 concentration, extractant concentration and temperature have been studied. The compositions of extracted species, thermodynamic parameters of extraction have been evaluated. Third phase formation in extraction of U(VI) has been studied. Back extraction behavior of U(VI) and Th(IV) from the organic phase has also been tested. The results obtained are compared with those obtained by using TBP under the same experimental conditions. 相似文献
217.
QianWANG XuXU 《中国化学快报》2003,14(12):1278-1280
The mixtures of two polymers, poly (N,N-dimethylacrylamide) (PDMA) and polyvinylpyrrolidone (PVP) were synthesized and used as the separation medium for double-stranded and single-stranded DNA fragments by capillary electrophoresis with UV detector. On optimal conditions, 2%w/v PDMA 2%w/v PVP can be used to separate the doublet 123/124bp in pBR322/Hae Ⅲ Markers. 相似文献
218.
219.
220.