全文获取类型
收费全文 | 9579篇 |
免费 | 1578篇 |
国内免费 | 1599篇 |
专业分类
化学 | 7305篇 |
晶体学 | 194篇 |
力学 | 557篇 |
综合类 | 106篇 |
数学 | 1039篇 |
物理学 | 3555篇 |
出版年
2024年 | 51篇 |
2023年 | 202篇 |
2022年 | 403篇 |
2021年 | 416篇 |
2020年 | 477篇 |
2019年 | 474篇 |
2018年 | 345篇 |
2017年 | 397篇 |
2016年 | 462篇 |
2015年 | 515篇 |
2014年 | 582篇 |
2013年 | 750篇 |
2012年 | 833篇 |
2011年 | 892篇 |
2010年 | 645篇 |
2009年 | 592篇 |
2008年 | 661篇 |
2007年 | 554篇 |
2006年 | 485篇 |
2005年 | 404篇 |
2004年 | 311篇 |
2003年 | 278篇 |
2002年 | 305篇 |
2001年 | 233篇 |
2000年 | 222篇 |
1999年 | 166篇 |
1998年 | 116篇 |
1997年 | 117篇 |
1996年 | 119篇 |
1995年 | 118篇 |
1994年 | 104篇 |
1993年 | 95篇 |
1992年 | 63篇 |
1991年 | 55篇 |
1990年 | 46篇 |
1989年 | 56篇 |
1988年 | 32篇 |
1987年 | 29篇 |
1986年 | 31篇 |
1985年 | 40篇 |
1984年 | 25篇 |
1983年 | 17篇 |
1982年 | 11篇 |
1981年 | 10篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1971年 | 2篇 |
1959年 | 3篇 |
1957年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
52.
53.
54.
Reaction solutions of selectfluor (1) with triphenylethylene (4a) and tetraphenylethylene (4b) were monitored by ESI-MS and ESI-MS/MS. Detection and characterization of the key radical cationic intermediates 5a.+ and 5b.+) fully supports the SET mechanism in electrophilic fluorination as depicted above. [reaction: see text] 相似文献
55.
56.
In the degassing process of transformer oil with ultrasonic waves ,decompostition of the oil was observed.Light hydrocarbons,including methane,ethane,ethylene ,aceylene,propane etc,were found to be released continuously from the oil into headspace within a closed vial placed in an ultrasonic field ,The gases came from decomposition of hydrocarbon molecules under cavitation effect. 相似文献
57.
(1)测定了醋酸十二烷基铵(DAA)在CAB-O-SIL上的吸附,其等温线属双平台或LS型[1-3,5];(2)NaCl的存在使DAA的吸附增加.但不影响其低浓度下第一平台的吸附量;HCl的存在则在全浓度范围内抑制了DAA的吸附,(3)测定了CAB-O-SIL颗粒在上述各溶液中的悬浮液的稳定性;(4)根据表面形成小胶团的吸附理论(即二步模型产)[2,3,5,],并借助电导跟踪溶液中发生的变化,满意地解释了吸附和聚沉的实验结果. 相似文献
58.
Investigation of Tomato Plant Defence Response to Tobacco Mosaic Virus by Determination of Methyl Salicylate with SPME-Capillary GC-MS 总被引:2,自引:0,他引:2
Headspace SPME was applied to investigation of tomato plant defence response to tobacco mosaic virus (TMV) by determination of compounds emitted from tomato plants at the extraction conditions of 25 °C and 15 min. It was found that TMV-inoculated tomato plant released large amount of methyl salicylate (MeSA) as response to TMV and MeSA concentration changed dramatically with time after inoculation. Gaseous MeSA as a signaling compound could induce in surrounding tomato plants to produce salicylic acid (SA) and synthesize and release MeSA. These results show that MeSA might be an airborne plant-signalling molecule in tomato plant response to TMV. The present method provided low detection limit of 2.0 ng L–1 and needed little sample preparation time (15 min), so the method makes it easy to find the critical times of tomato plant response to TMV by fast determination of MeSA released from tomato plant. 相似文献
59.
标题化合物C24H29NO4?1/2C2H5OH稨2O)由香兰素、5,5-二甲基-1,3-环己二酮、醋酸铵在微波辐射下干反应并经95%乙醇重结晶而得C24H29NO4穀2(C2H5OH稨2O)晶体。结构通过单晶X-射线衍射法确定,其晶体属单斜晶系,空间群P21/n, a = 9.810(2), b = 14.516(3), c = 17.008(3) ? b = 101.03(2), V = 2377.2(8) ?, Z = 4, Mr = 427.52, Dc = 1.195 g/cm3 , m(MoKa) = 0.082 mm-1, F(000) = 920。晶体结构用直接法解出,经全矩阵最小二乘法对原子参数进行修正,最终的偏离因子为R = 0.0406, wR = 0.0892。X-射线衍射分析结果表明,吡啶环和与之稠合的2个六员环均为信封式构象。 相似文献
60.
Qian Yanlong Li Guisheng Chen Weichun Li Bihua Jin Xianglin 《Transition Metal Chemistry》1990,15(6):478-482
Summary A new class of differentially ring-substituted titanocene dichlorides of the type CpCpTiCl2 has been prepared by reacting CpM (M=Li, K; Cp=RC5H4) with CpTiCl3 (Cp=MeOCH2CH2C5H4). The crystal structure of Cp(PhCEt2C5H4)TiCl2, the first example, has been determined by x-ray diffraction and refined to a final R factor of 0.0532 for 2304 reflections. The crystal belongs to the monoclinic space group C
2h
5
–P21/c with unit cell parameters:a 10.205(6),b 13.003(5),c 17.591(9) Å, 101.91(4)°, V=2284 Å3, Z=4 and Dc=1.32 g/cm–3. Replacement of one neomenthyl in bis(neomenthyl-cyclopentadienyl)titanium dichloride by one MeOCH2CH2 — raises the e.e. value from 5.8% to 11.2% in the catalytic asymmetric hydrogenation of 2-phenyl-1-butene. 相似文献