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41.
Xinzhi Chen Shaodong Zhou Yuehan Chen Zehan Dong Yeyu Gao Chao Qian Chaohong He 《Research on Chemical Intermediates》2012,38(9):2255-2269
Alcoholate was utilized in catalytic transfer hydrogenation of unsaturated nitrogen compounds. In the reduction of nitro compounds, oximes and imines, alkoxide was used as the promoter, with alcohol as the hydrogen source, while in the reduction of nitriles, alkoxide was used as the hydrogen source. 相似文献
42.
Bahni Ray P. Dinesh Sankar Reddy Dipankar Bandyopadhyay Sang Woo Joo Ashutosh Sharma Shizhi Qian Gautam Biswas 《Theoretical and Computational Fluid Dynamics》2012,26(1-4):311-318
Instability of a thin electrolyte film undergoing a direct current electroosmotic flow has been investigated. The film with a compliant electrolyte–air interface is flowing over a rigid charged substrate. Unlike previous studies, inclusion of the Maxwell stresses in the formulation shows the presence of a new finite wavenumber shear-flow mode of instability, alongside the more frequently observed long-wave interfacial mode. The shear mode is found to be the dominant mode of instability when the electrolyte–solid and electrolyte–air interfaces are of opposite charge or of same charge but have very large zeta-potential at the electrolyte–air interface. The conditions for mode-switch (interfacial to shear) and the direction of the travelling waves are discussed through stability diagrams. Interestingly, the analysis shows that when the interfaces are of nearly same zeta potential, the ‘free’ electrolyte–air interface behaves more like a ‘stationary’ wall because of the ion transport in the reverse direction of the flow. 相似文献
43.
本文用本征通道量子亏损理论方法(EQDT方法)计算了氖等电子序列2p^5nl(l=s,d)系列的高激发态结构。得到基本结构参量(EQDT参量)随净电荷数Zc增大的变化规律,并从静电相互作用下自旋-轨道相互作用之间的竞争角度给出确切的物理解释。以NeI为实例,给出其高激发态结构的具体数值结果。 相似文献
44.
为了深入了解生物柴油在ZSM-5沸石上的催化反应机理,在常压的流动反应器中进行了生物柴油代用品丁酸甲酯在氢型ZSM-5(HZSM-5)催化剂上的热解和催化热解. 热解产物使用气相色谱-质谱法定性和定量测量. 动力学模型和实验表明,气相中氢提取反应是热解过程中丁酸甲酯分解的主要途径,但在HZSM-5上,丁酸甲酯则主要通过解离生成烯酮和甲醇消耗;与无催化反应相比,丁酸甲酯在HZSM-5上的初始分解温度降低了约300 K. 并且通过Arrhenius方程获得了在催化热解和均相热解条件下丁酸甲酯消耗的表观活化能. 明显降低的表观活化能证实了HZSM-5对丁酸甲酯热解的催化性能. 此外催化剂的活化温度对HZSM-5的某些催化性能具有一定的影响. 该研究对进一步的实际生物柴油燃料的催化燃烧具有一定的指导意义. 相似文献
45.
The generalized Hamiltonian structures for a hierarchy of nonlinear evolution equations are established with the aid of the trace identity. Using the nonlinearization approach, the hierarchy of nonlinear evolution equations is decomposed into a class of new finite-dimensional Hamiltonian systems. The generating function of integrals and their generator are presented, based on which the finite-dimensional Hamiltonian systems are proved to be completely integrable in the Liouville sense. As an application, solutions for the hierarchy of nonlinear evolution equations are reduced to solving the compatible Hamiltonian systems of ordinary differential equations. 相似文献
46.
讨论了结构与饱和土壤相互作用的固结分析问题.对于结构利用多重子结构分析技术实现向饱和土交界面上的凝聚.从而建立了结构与饱和土壤相互作用的固结控制方程.文中给出了问题求解的一次性算法方案,采取压力主从关系的手段处理边界上的不排水条件.文末给出数值算例.本文工作为大型结构与土体相互作用固结分析研究工作的深入创造了条件. 相似文献
47.
要解决的问题是一个矩阵是否可以分解为若干稳定 (连续时间意义下 )矩阵的和 .通过推广Ito,Hattori and Maeda在文献 [2 ]中使用的方法并运用其中的成果 ,我们得到了更为准确的相关结论 . 相似文献
48.
49.
Jinyuan Liu Deming Shu Yujie Wang Suresh Narayanan Ali Mashayekhi Jun Qian Jin Wang 《Journal of synchrotron radiation》2007,14(1):138-143
The development of a sagittally focusing double‐multilayer monochromator is reported, which produces a spatially extended wide‐bandpass X‐ray beam from an intense synchrotron bending‐magnet source at the Advanced Photon Source, for ultrafast X‐ray radiography and tomography applications. This monochromator consists of two W/B4C multilayers with a 25 Å period coated on Si single‐crystal substrates. The second multilayer is mounted on a sagittally focusing bender, which can dynamically change the bending radius of the multilayer in order to condense and focus the beam to various points along the beamline. With this new apparatus, it becomes possible to adjust the X‐ray beam size to best match the area detector size and the object size to facilitate more efficient data collection using ultrafast X‐ray radiography and tomography. 相似文献
50.
Deeply penetrating photoacoustic tomography in biological tissues enhanced with an optical contrast agent 总被引:3,自引:0,他引:3
Photoacoustic tomography (PAT) in a circular scanning configuration was developed to image deeply embedded optical heterogeneity in biological tissues. While the optical penetration was maximized with near-infrared laser pulses of 800-nm wavelength, the optical contrast was enhanced by Indocyanine Green (ICG) dye whose absorption peak matched the laser wavelength. This optimized PAT was able to image objects embedded at depths of as much as 5.2 cm, 6.2 times the 1/e optical penetration depth, in chicken breast muscle at a resolution of <780 microm and a sensitivity of <7 pmol of ICG in blood. The resolution was found to deteriorate slowly with increasing imaging depth. The effects of detection bandwidth on the quality of images acquired simultaneously by four different ultrasonic transducers are described. 相似文献