A threefold interpenetrated two‐dimensional zinc(II) supramolecular architecture based on 3‐nitrobenzoic acid and 4,4′‐bipyridine

With regard to crystal engineering, building block or modular assembly methodologies have shown great success in the design and construction of metal–organic coordination polymers. The critical factor for the construction of coordination polymers is the rational choice of the organic building blocks and the metal centre. The reaction of Zn(OAc)₂·2H₂O (OAc is acetate) with 3‐nitrobenzoic acid (HNBA) and 4,4′‐bipyridine (4,4′‐bipy) under hydrothermal conditions produced a two‐dimensional zinc(II) supramolecular architecture, catena‐poly[[bis(3‐nitrobenzoato‐κ²O,O′)zinc(II)]‐μ‐4,4′‐bipyridine‐κ²N:N′], [Zn(C₇H₄NO₄)₂(C₁₀H₈N₂)]_n or [Zn(NBA)₂(4,4′‐bipy)]_n, which was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and single‐crystal X‐ray diffraction analysis. The Zn^II ions are connected by the 4,4′‐bipy ligands to form a one‐dimensional zigzag chain and the chains are decorated with anionic NBA ligands which interact further through aromatic π–π stacking interactions, expanding the structure into a threefold interpenetrated two‐dimensional supramolecular architecture. The solid‐state fluorescence analysis indicates a slight blue shift compared with pure 4,4′‐bipyridine and HNBA.     

二氧化钛微晶结构和光催化性能关联性研究

研究了不同煅烧温度、煅烧时间的系列二氧化钛样品悬浮体系光催化降解X-3B活性艳红的催化活性。分析了晶粒尺寸、晶相、晶格畸变应力和光催化体系等诸多因素对二氧化钛光催化活性的影响。发现晶格畸变应力对空穴电子对复合速率的影响在诸因素中占主导地位,并在一定程度上决定了二氧化钛悬浮体系的光催化效能。     

1,3,4—噻二唑的α—氨基膦酸酯衍生物的合成及其生物活性

利用２－氨基－５－烷基－１,３,４－噻二唑、芳笛醛和亚磷酸三苯酯泊类Ｍａｎｎｉｃｈ反应,合成了一系列１,３,４－噻二唑的α－氨基膦酸酯生物。它们的结构级元素分析、ＩＲ,ＨＮＭＲ和ＭＳ这。初步生物活性测试结果表明,目标化合物对５种病人有一定的抑制作用。     

The Initial Reactions of H3PO4 and NaH2PO4Supported on Silica: A Joint Experimental and Theoretical Study

利用XRD、TG、DRIFTS、31P MAS NMR和密度泛函理论研究了浸渍法制备的硅胶负载型磷酸和磷酸二氢钠催化剂,阐明了催化剂制备过程中生成的初始缩合产物和其反应机理. 光谱试验结果显示,在二氧化硅负载的磷酸上,除了聚磷酸外,还有硅磷酸盐的存在;在二氧化硅负载的磷酸二氢钠上,仅发现聚磷酸钠存在. 密度泛函模拟结果也证明,磷酸与二氧化硅表面硅羟基之间的反应在缩合反应的初始阶段比其自身的二聚反应更为有利. 但是在硅胶负载的磷酸二氢钠上,磷酸二氢钠的二聚和三聚是缩合反应初始阶段的主要反应.     

微型滴定法测定硫酸亚铁的含量

将微型滴定用于硫酸亚铁含量的测定 ,设计并使用与微型滴定管精度一致的移液管 ,比较了微型滴定与常量滴定的测定结果。方法可行 ,有使用价值。     

Poisson–Dirichlet distribution with small mutation rate

A large deviation principle is established for the Poisson–Dirichlet distribution when the mutation rate θ$\theta$ converges to zero. The rate function is identified explicitly, and takes on finite values only on states that have finite number of alleles. This result is then applied to the study of the asymptotic behavior of the homozygosity, and the Poisson–Dirichlet distribution with selection. The latter shows that several alleles can coexist when selection intensity goes to infinity in a particular way as θ$\theta$ approaches zero.     

The facile in situ preparation and characterization of C/FeOF/FeF<Subscript>3</Subscript> nanocomposites as LIB cathode materials

C/FeOF/FeF₃ nanocomposite was synthesized by a facile in situ partial oxidation method. High-resolution transmission electron microscopy (HR-TEM) showed a special texture comprised of interpenetrating nanodomains of FeOF and FeF₃. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements revealed that the introduction of nanodomain FeOF enhanced both the electronic and ionic conductivity of the composite material. Therefore, the improvement of electron and lithium-ion dynamics resulted in the significant enhancement of the electrochemical performances of the material at ambient temperature. At a current density of 20 mA g^?1 within potential range 1.5–4.5 V, the specific capacities of the first ten circles were maintained at about 400 mAh g^?1 _. This material also exhibited excellent cycling capacity retention capability especially for high C rates. When the current density further increased to 100 and 200 mA g^?1, a steady capacity of 80 and 60 mAh g^?1 was observed, respectively. Furthermore, nearly no capacity loss was observed for the followed cycles. The discharge platforms based on intercalation and conversion reaction were also heightened by about 0.4 V, which increased the contribution of high voltage capacities. Compared to C/FeF₃, C/FeOF/FeF₃ is showing more of capacitive behavior, which also contributes to the high specific capacity delivered and is believed to be closely related to the enlarged nanodomain interfaces between two electrochemical active materials. An expansion-cracking-oxidation mechanism was proposed to explain the formation of this interpenetrating nanodomains of FeOF and FeF₃.     

Large refractive index with vanishing absorption in optical fibers

We propose and demonstrate a novel scheme for realizing large refractive index with vanishing absorption in a three-level quantum system consisting of the energy levels of Er³⁺-doped ZrF₄–BaF₂–LaF₃–AlF₃–NaF (ZBLAN) optical fiber. It is found that the refractive index of the probe field can be controlled via the coherent coupling field and incoherent pumping field. The switching from negative refractive index to positive refractive index and manipulation of the value of the index of refraction while maintaining vanishing absorption of the probe field can be achieved via tuning the detuning of the coherent coupling field. Our scheme may provide some new possibility for technological applications in fiber communication.     

一种抑制合成孔径雷达图像相干斑的各向异性扩散滤波方法

本文提出了一种抑制合成孔径雷达图像乘性相干斑噪声的各向异性扩散滤波新方法.该方法将受自适应耦合函数控制的平均曲率运动嵌入到传统相干斑抑制的各向异性扩散方程中,形成了一种可有效抑制边缘区域相干斑与同质区块效应现象的各向异性扩散新方程,同时在新建的扩散方程中,引入了由改进Frost滤波与局部方向比率联合构建的一种带方向约束的新扩散函数,进一步削弱了块效应现象且明显改善了抑斑图像的边缘抖动扭曲问题.实验结果表明该方法在有效保护图像边缘的同时,能充分平滑同质区与边缘区域的相干斑,明显削弱块效应现象,有效改善抑斑图像边缘抖动扭曲问题,而抑斑图像无论视觉效果还是参数指标均比多种传统抑斑方法更具优势.