微电喷雾与纳电喷雾装置的制作

研制了实验室可自制的多种微／纳电喷雾喷头。喷头制作简单且易于操作,并利用利血平标准样品测试了各种微／纳电喷雾喷头的性能,显示了其高灵敏、低消耗的显著特点。     

Low-Temperature Thermal Conductance in Superlattice Nanowire with Structural Defect

Using the scattering-matrix cascading method, we investigate the effect of structural defect on the acoustic phonon transmission and thermal conductance in the superlattice nanowire at low temperatures. In the present system, the phonon transmissions exhibit quite complex oscillatory behaviour. It is found that a lateral defect in an otherwise periodic structure significantly decrease the thermal conductance and completely washes away the transmission quantization. However, the appreciable transmission quantization survives in the presence of a longitudinal defect whereas a good quantization plateau of thermal conductance emerges below the universal level in a wide temperature range with the lateral defect.     

水声材料低频声性能的行波管测量

发展了一种测量水声材料声学性能的行波管测量技术,能够在实验室充水管中模拟海洋水温水压环境,对样品的声学参数实施低频范围的测量。被测样品置于声管中央,声管两端配置一对发射器。应用主动消声技术使样品的透射声波在声管次发射器表面的反射可忽略,在管中建立起行波声场。然后,通过分别计算样品两边声场中每一对水听器的传递函数,得到样品的反射系数和透射系数。测量系统声管的内径为Φ208 mm,工作频率范围为100～4000 Hz,最高静水压为5 MPa。对水层和层状不锈钢样品的反射系数和透射系数进行了实际测量和理论计算,结果表明,测量值和计算值有较好的吻合,测量不确定度不大于1．5 dB。     

Molecular Recognition Regulates Coordination Structure of Single-Atom Sites

Coordination engineering for single-atom sites has drawn increasing attention, yet its chemical synthesis remains a tough issue, especially for tailorable coordination structures. Herein, a molecular recognition strategy is proposed to fabricate single-atom sites with regulable local coordination structures. Specifically, a heteroatom-containing ligand serves as the guest molecule to induce coordination interaction with the metal-containing host, precisely settling the heteroatoms into the local structure of single-atom sites. As a proof of concept, thiophene is selected as the guest molecule, and sulfur atoms are successfully introduced into the local coordination structure of iron single-atom sites. Ultrahigh oxygen reduction electrocatalytic activity is achieved with a half-wave potential of 0.93 V versus reversible hydrogen electrode. Furthermore, the strategy possesses excellent universality towards diversified types of single-atom sites. This work makes breakthroughs in the fabrication of single-atom sites and affords new opportunities in structural regulation at the atomic level.     

Overall metabolic network analysis of urine in hyperlipidemic rats treated with Bidens bipinnata L.

Hyperlipidemia has been highlighted as one of the most prominent and global chronic conditions nowadays. Bidens bipinnata L. (BBL), a folk medicine in contemporary China, has efficacy in the treatment of hyperlipidemia (HLP) in China. Although some physiological and pathological function parameters of hyperlipidemia have been investigated, little information about the changes in small metabolites in biofluids has been reported. In the present study, global metabolic profiling with high-performance liquid chromatography–linear ion trap/Orbitrap high-resolution mass spectrometry (HPLC–LTQ/Orbitrap MS) combined with a pattern recognition method was performed to discover the underlying lipid-regulating mechanisms of BBL on hyperlipidemic rats induced by high-fat diet (HFD). The total of four metabolites, up- or down-regulated (p < 0.05 or 0.01), were identified and contributed to the progression of hyperlipidemia. These promising identified biomarkers underpin the metabolic pathway, including glyoxylate and dicarboxylate metabolism, the TCA cycle, sphingolipid metabolism and purine metabolism. They are disturbed in hyperlipidemic rats, and are identified using pathway analysis with MetPA. The altered metabolite indices could be regulated closer to normal levels after BBL intervention. The results demonstrated that urinary metabolomics is a powerful tool in the clinical diagnosis and treatment of hyperlipidemia to provide information on changes in metabolite pathways.     

Fabrication of high-performance silicon anode materials for lithium-ion batteries by the impurity compensation doping method

Journal of Solid State Electrochemistry - Due to its high theoretical specific capacity and lower working potential, silicon is regarded as the most promising anode material for the new generation...