首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   114383篇
  免费   21055篇
  国内免费   10298篇
化学   93106篇
晶体学   1069篇
力学   5720篇
综合类   460篇
数学   11210篇
物理学   34171篇
  2024年   303篇
  2023年   1796篇
  2022年   3057篇
  2021年   3406篇
  2020年   4430篇
  2019年   5424篇
  2018年   3709篇
  2017年   3269篇
  2016年   6990篇
  2015年   7060篇
  2014年   7647篇
  2013年   9612篇
  2012年   9958篇
  2011年   9298篇
  2010年   7538篇
  2009年   7301篇
  2008年   7261篇
  2007年   6114篇
  2006年   5501篇
  2005年   4981篇
  2004年   4062篇
  2003年   3380篇
  2002年   3938篇
  2001年   2978篇
  2000年   2801篇
  1999年   2066篇
  1998年   1497篇
  1997年   1427篇
  1996年   1440篇
  1995年   1164篇
  1994年   1044篇
  1993年   859篇
  1992年   743篇
  1991年   674篇
  1990年   591篇
  1989年   425篇
  1988年   376篇
  1987年   302篇
  1986年   280篇
  1985年   242篇
  1984年   159篇
  1983年   120篇
  1982年   88篇
  1981年   74篇
  1980年   69篇
  1979年   36篇
  1978年   30篇
  1977年   42篇
  1976年   30篇
  1973年   29篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
91.
一种漂移室定位子性能反常现象的研究   总被引:1,自引:0,他引:1  
研究了一种漂移室定位子性能的反常现象,它关系到定位子的使用寿命.着重测量了暗电流和随机噪声与时间、高压及温度的关系.  相似文献   
92.
Double-diffusive convection due to a cylindrical source submerged in a salt-stratified solution is numerically investigated in this study. For proper simulation of the vortex generated around the cylinder, a computational domain with irregular shape is employed. Flow conditions depend strongly on the thermal Rayleigh number, Ra T , and the buoyancy ratio, R ρ. There are two types of onset of instability existing in the flow field. Both types are due to either the interaction of the upward temperature gradient and downward salinity gradient or the interaction of the lateral temperature gradient and downward salinity gradient. The onset of layer instability due to plume convection is due to the former, whereas, the onset of layer instability of layers around the cylinder is due to the latter. Both types can be found in the flow field. The transport mechanism of layers at the top of the basic plume belongs to former while that due to basic plume and layer around the cylinder are the latter. The increase in Ra T reinforces the plume convection and reduces the layer numbers generated around the cylinder for the same buoyancy ratio. For the same Ra T , the increase of R ρ suppresses the plume convection but reinforces the layers generated around the cylinder. The profiles of local Nusselt number reflects the heat transfer characteristics of plume convection and layered structure. The profiles of averaged Nusselt number are between the pure conduction and natural convection modes and the variation is due to the evolution of layers. Received on 13 September 1996  相似文献   
93.
唐西林  刘仲奎 《数学杂志》1997,17(3):397-403
本文利用逆半群上的同余扩张,讨论了一类逆半群的亚直可约性,并刻划了这类逆半群的幂等元集的特征。  相似文献   
94.
A technique for the characterization of an interior crack perpendicular to the surface of the plates is presented. A time-harmonic line load is applied on the upper surface of the plate. The scattered displacement field is calculated by using the strip element method. It is found that there are additional superimposed oscillations in the curve of the absolute values of the displacement in the region between the load and the crack. The mean value of the peaks of the additional oscillations increases with the crack length, and is less dependent on the distance from the load to the crack. The crack position is determined from the displacement distribution curve and the crack length is determined from the mean value of the peaks of the additional oscillations. Approximate polynomial formula of degree four for predicting the length of interior vertical cracks in isotropic homogeneous plates is also proposed. Numerical examples are given to demonstrate the present technique.  相似文献   
95.
用DEA方法测算产出弹性   总被引:1,自引:1,他引:0  
本文主要讨论并给出了把DEA模型C2GS2用于测算产出的弧弹性的方法。  相似文献   
96.
The micro element content of food is an important quality index due to the action of these elements on human health. In this article, we discuss how to ensure the reliability of analytical data on micro elements in order to truly represent the condition of food. Sampling, treatment of the analytical sample, selection of the analytical method, standard solution, and certified reference material, blank test, calibration of the instrument and equipment, application of the quality control chart, assessment of the final analytical result, and quality assurance system are briefly described. Received: 5 July 2001 Accepted: 19 November 2001  相似文献   
97.
杨宇  黄醒良 《发光学报》1995,16(4):285-292
采用固源Si分子束外延,在较高的生长温度于Si(100)衬底上制备出Si1-xGex/Si量子阱发光材料。发光样品的质量和特性通过卢瑟福背散射、X射线双晶衍射及光致发光评估。背散射实验中观察到应变超晶格的反常沟道效应;X射线分析表明材料的生长是共度的、无应力释放的,结晶完整性好。低温光致发光主要是外延合金量子阱中带边激子的无声发射和横光学声子参与的激子复合。并讨论了生长温度对量于阱发光的影响。  相似文献   
98.
In theory, both polarity and steric hindrance are basic factors which affect molecular interactions. To investigate the optical properties and steric structures of chiral compounds having different chiral moieties which affect the wavelength of light reflection in liquid crystal (LC) cells, a series of novel chiral compounds and azobenzene derivatives were synthesized. The liquid crystalline phases of the compounds were identified using small angle X-ray diffraction, differential scanning calorimetry and polarizing optical microscopy. Cholesteric LC cells with various synthesized chiral dopants which selectively reflect visible light were first prepared, the photochemical switching behaviour of colours was then investigated, with special reference to the change in transmittance in cholesteric LC cells containing an azobenzene derivative as a photoisomerizable guest molecule. Reversible isomerization of azobenzene molecules occurred in the cholesteric systems, resulting in a depression of TChI and a shift of the selectively reflected wavelength. We discuss the photochemically driven change in the helical pitch of the cholesteric LCs with respect to structural effects involving the chiral moieties. Molecular interactions caused by the added dopants, reliability and stability of the photoisomerization, and UV irradiation effects on the cholesteric LC cells were also investigated. A real image was recorded through a mask on a cholesteric LC cell fabricated in this investigation.  相似文献   
99.
To incorporate an acceptor type polythiophene segment onto a supramolecular block copolymer for potential light harvesting applications, effective synthetic routes for the end‐functionalized and acceptor‐substituted polythiophenes are critical. The Ullmann coupling reaction can be utilized to obtain electron‐deficient polythiophenes and to attach terminal thiophene units that carry functional groups. In this article, the reactions involving a 2,5‐dibromothiophene monomer containing an electron‐withdrawing fluorinated ester and 5‐bromo‐2‐thiophenecarboxaldehyde (the end‐capper) were studied in detail. It was found that the Ullmann coupling reaction of the dibromide is very fast (completed in a few minutes) and the terminal bromine group does not survive long under the reaction condition. These findings lead to the development of an effective procedure for aldehyde end‐capping of electron‐deficient polythiophenes. Polymers with molecular weights around 4000 Da are routinely obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 41–47, 2007  相似文献   
100.
New photocrosslinkable maleimide copolymers have been synthesized by the attachment of a tricyanopyrrolidene‐based chromophore. The 2‐(3‐cyano‐4‐(2‐{4‐[hexyl‐(6‐hydroxy‐hexyl)‐amino]‐phenyl}‐vinyl)‐5‐oxo‐1‐{4‐[4‐(3‐oxo‐3‐phenyl‐propenyl)‐ phenoxy]‐butyl}‐1,5‐dihydro‐pyrrol‐2‐ylidene)‐malononitrile chromophore exhibits nonlinear optical activity and contains a chalcone moiety that is sensitive to UV light (λ = 330–360 nm) for crosslink formation. The maleimide monomers have also been functionalized with chalcone moieties. The resultant copolymers exhibit great processability, and one of them shows a maximum electrooptic coefficient of 90 pm/V at 1300 nm. We could control the thermal stability of the electrooptic coefficient with the newly synthesized photoreactive copolymers successfully. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 531–542, 2007  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号