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981.
982.
With the B3LYP calculation method of density functional theory(DFT)and the 6-31G* basis set,full optimization calculation was made for phenoxathiin10-oxide(PTO)and 135 polybromine phenoxathiin 10-oxides(PBPTOs)with the Gaussian 03 program and molar heat capacity in constant volume(CVθ)value of each molecule in the standard state was obtained.The relation between CVθ and the substitution position and number of bromine atom(NPBS)was studied,and the results indicated good correlation(R2 = 1.000)between CVθ and NPBS of PBPTO compounds.Based on the output file of Gaussian 03 program,molar heat capacity at constant pressure(Cp,m)of PBPTO compounds from 200 to 1,000 K was calculated with the statistical thermodynamics program,and the correlation equation between Cp,m and temperature(T,T-1 and T-2)was obtained with the least-squares method,and the correlation coefficient of the correlation equation(R2)was 1.000.In addition,based on the partition function of each molecule calculated by vibration analysis,the relative rate constant of formation of each molecule was calculated. 相似文献
983.
984.
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986.
A New Capillary Electrophoresis Apparatus with Piezoelectric Ceramics High Voltage Source and Amperometric Detector 总被引:13,自引:0,他引:13
Zuan Guang CHENI Jin Yuan MO Xiao Yun YANG Li Shi WANG Xue Ting MEIZ Min Sheng ZHANGI 《中国化学快报》1999,(3)
IntroductionHighperformancecapiliar}'electrophoresis(HPCE)isanewanalyticaltechnology'rapidly'developedinrecentyears.Withtheadvantagesofsmallsample.highsensitivity,highresolution.rapidanalysisandverycheaprunning,ithasbeenappliedinchemistry'.lifescienc... 相似文献
987.
首先根据团队生产在产出函数的特点,建立了由二人组成的团队生产模型;接着,在分析了团队生产的博弈过程后,求得团队成员努力投入的N ash均衡;最后,着重研究了两种证实团队生产中存在道德风险的方法. 相似文献
988.
Huang Yun Liu Bo Cao Haijun Lin Yuanhua Tang Shuihua Wang Mingshan Li Xing 《Journal of Solid State Electrochemistry》2017,21(8):2291-2299
Journal of Solid State Electrochemistry - One novel cage kind of polyhedral ligomeric silsesquioxane (POSS), for modification application of gel polymer electrolyte (GPE) in lithium ion batteries... 相似文献
989.
Yun Zhi Fu Ping Yang Jin Ru Li Long Jiang 《Journal of Dispersion Science and Technology》2013,34(4):633-637
In this article, a new method which not only can separate hydrophobic Au nanoparticles (NPs), but also obtain highly monodisperse NPs is discussed. A self‐made device of two same burettes, one of which was inserted into the other, was used for separating the nanoparticles by washing the reversal micelle. The effects of separation were characterized and analyzed by micrograph of transmission electron microscope (TEM), UV‐vis spectra, quartz crystal microbalance (QCM), and energy dispersive x‐ray analysis (EDX). It has been shown that, the smaller nanoparticles are, the easier they are to stay at the reversal micelle and the narrower the sizes are. This method can be applied to synthesize highly monodisperse Au NPs. 相似文献
990.
Xiaomei Luo Nicholas A. Tinker Yun Jiang Pu Xuan Haiqin Zhang Yonghong Zhou 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(2):1129-1134
Seeds from six accessions of three species of Roegneria were radiated with 60Co γ-ray at different doses (50, 100, 150, 200, 250, 300 and 400 Gy). Following these treatments, germination energy, germination rate, seedling height, plant height, plant survival, and seed set were observed. Plant survival was highly correlated with seedling height (R 2 > 0.91, P < 0.01) and seed set (R 2 > 0.82, P < 0.01). The semi-lethal dose of each accession, calculated using a ‘Multi-target single-hit’ model, ranged from 60 to 173 Gy. The most suitable absorbed doses for each accession were deduced from these data. The suitable doses for Roegneria kamoji, Roegneria ciliaris and Roegneria japonensis were 65–100 Gy, 63–150 Gy and 80–170 Gy, respectively. According to the range of suitable doses, R. kamoji (Pr87-88-353) was the most sensitive to radiation, and R. japonensis (88-89-267) was the most resistant to radiation. Suitable doses of R. ciliaris were close to that of R. kamoji (ZY1007). This research provides preliminary guidelines for radiation induced mutagenesis in Roegneria. 相似文献