全文获取类型
收费全文 | 17769篇 |
免费 | 2917篇 |
国内免费 | 2349篇 |
专业分类
化学 | 13022篇 |
晶体学 | 256篇 |
力学 | 1031篇 |
综合类 | 171篇 |
数学 | 1808篇 |
物理学 | 6747篇 |
出版年
2024年 | 63篇 |
2023年 | 331篇 |
2022年 | 604篇 |
2021年 | 617篇 |
2020年 | 682篇 |
2019年 | 693篇 |
2018年 | 634篇 |
2017年 | 579篇 |
2016年 | 798篇 |
2015年 | 881篇 |
2014年 | 1079篇 |
2013年 | 1348篇 |
2012年 | 1514篇 |
2011年 | 1638篇 |
2010年 | 1181篇 |
2009年 | 1066篇 |
2008年 | 1206篇 |
2007年 | 1123篇 |
2006年 | 989篇 |
2005年 | 846篇 |
2004年 | 668篇 |
2003年 | 626篇 |
2002年 | 644篇 |
2001年 | 551篇 |
2000年 | 429篇 |
1999年 | 340篇 |
1998年 | 245篇 |
1997年 | 225篇 |
1996年 | 198篇 |
1995年 | 153篇 |
1994年 | 202篇 |
1993年 | 137篇 |
1992年 | 136篇 |
1991年 | 102篇 |
1990年 | 101篇 |
1989年 | 90篇 |
1988年 | 56篇 |
1987年 | 34篇 |
1986年 | 37篇 |
1985年 | 31篇 |
1984年 | 25篇 |
1983年 | 16篇 |
1982年 | 19篇 |
1981年 | 8篇 |
1980年 | 17篇 |
1979年 | 9篇 |
1976年 | 10篇 |
1975年 | 7篇 |
1974年 | 8篇 |
1973年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
Nickel complexes 1–4 ligated with 2,9-disubstituted-1,10-phenanthroline were synthesized and characterized by FT-IR spectra and elemental analysis.
The molecular structure of complex 2 was confirmed by X-ray crystal diffraction analysis. Activated with methylaluminoxane (MAO), those complexes showed moderate
activities for ethylene oligomerization.
Published in Kinetika i Kataliz, 2007, Vol. 48, No. 5, pp. 710–714.
This article was submitted by the authors in English. 相似文献
32.
J. Song H. Jiang Z.J. Liu D.Y. Khang Y. Huang J.A. Rogers C. Lu C.G. Koh 《International Journal of Solids and Structures》2008,45(10):3107-3121
A finite-deformation theory is developed to study the mechanics of thin buckled films on compliant substrates. Perturbation analysis is performed for this highly nonlinear system to obtain the analytical solution. The results agree well with experiments and finite element analysis in wavelength and amplitude. In particular, it is found that the wavelength depends on the strain. Based on the accurate wavelength and amplitude, the membrane and peak strains in thin films, and stretchability and compressibility of the system are also obtained analytically. 相似文献
33.
双金属催化剂是一类重要的多相催化剂。其中d电子在催化活性方面起着重要的作用.本文在Co_3[Fe(CN)_6]_2的工作基础上,进一步研究了该配合物在硅胶、氧化铝、以及氧化镁上的热性质,同时考察了CN~-在Co-Fe体系双端基配位的活化加氢,探讨了载体的影响. 相似文献
34.
Zhaoqiang Lu Lin Cheng Jun Li Kai Zhang Song Yi Jingui Qin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):925-932
The synthesis and structural characterization of a series of novel, fluorinated poly(phthalazinone ether)s containing perfluorophenylene moieties are described. The monomers, 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a – 2d ), were conveniently and efficiently synthesized from phenols and phthalic anhydride in two steps via 2‐(4′‐hydroxybenzoyl)benzoic acids, which were first obtained by the Friedel–Crafts reaction in good yields and with high stereoselectivity and were then converted into 2a – 2d by fusion with hydrazine. All the polymers were prepared by nucleophilic aromatic substitution (SNAr) polycondensation between the compounds perfluorobiphenyl and 4‐(4′‐hydroxyaryl)phthalazin‐1(2H)‐ones ( 2a ‐ 2d ). The resulting fluorinated polymers were readily soluble in common organic solvents (e.g., CHCl3, tetrahydrofuran, dimethylformamide, dimethyl sulfoxide, N‐methylpyrrolidone, etc.) at room temperature. Their weight‐average molecular weights and the polydispersities ranged from (7.96–18.25) × 103 to 1.31–2.71, respectively. Their glass‐transition temperatures varied from 213 to 263 °C. They were all stable up to 390 °C both in air and in argon. The 5% weight‐loss temperatures of these polymers in air and argon ranged from 393–487 to 437–509 °C, respectively. Wide‐angle X‐ray diffraction studies indicated they were all amorphous and could be attributed to the presence of kink nonplanar moiety, phenyl phthalazinone along the polymer backbone. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 925–932, 2004 相似文献
35.
The reversible nonlinear conduction (RNC) in of high‐density polyethylene/acetylene carbon black composites with different degrees of crosslinking was studied above room temperature and below the melting point of high‐density polyethylene (HDPE). The experimental current density‐electric field strength curves can be overlapped onto a master curve, suggesting that the microscopic mechanisms for the appearance of RNC exist regardless of the ambient temperature and the crosslinking degree of the HDPE matrix. The relationship between the crossover current density and the linear conductivity can be explained in the framework of the dynamic random‐resistor‐network model. According to these results, two electron‐tunneling models are suggested to interpret the microscopic conduction behavior. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1212–1217, 2004 相似文献
36.
37.
Harnack inequality for some classes of Markov processes 总被引:3,自引:0,他引:3
In this paper we establish a Harnack inequality for nonnegative harmonic functions of some classes of Markov processes with jumps.
Mathematics Subject Classification (2000): Primary 60J45, 60J75, Secondary 60J25.This work was completed while the authors were in the Research in Pairs program at the Mathematisches Forschungsinstitut Oberwolfach. We thank the Institute for the hospitality.The research of this author is supported in part by NSF Grant DMS-9803240.The research of this author is supported in part by MZT grant 0037107 of the Republic of Croatia. 相似文献
38.
S. P. Savin L. M. Zelenyi E. Amata J. Buechner J. Blecki S. I. Klimov B. Nikutowski J. L. Rauch S. A. Romanov A. A. Skalsky V. N. Smirnov P. Song K. Stasiewicz 《JETP Letters》2004,79(8):368-371
The study of the interaction between collisionless plasma flow and stagnant plasma revealed the presence of an outer boundary layer at the border of a geomagnetic trap, where the super-Alfvén subsonic laminar flow changes over to the dynamic regime characterized by the formation of accelerated magnetosonic jets and decelerated Alfvén flows with characteristic relaxation times of 10–20 min. The nonlinear interaction of fluctuations in the initial flow with the waves reflected from an obstacle explains the observed flow chaotization. The Cherenkov resonance of the magnetosonic jet with the fluctuation beats between the boundary layer and the incoming flow is the possible mechanism of its formation. In the flow reference system, the incoming particles are accelerated by the electric fields at the border of boundary layer that arise self-consistently as a result of the preceding wave-particle interactions; the inertial drift of the incoming ions in a transverse electric field increasing toward the border explains quantitatively the observed ion acceleration. The magnetosonic jets may carry away downstream up to a half of the unperturbed flow momentum, and their dynamic pressure is an order of magnitude higher than the magnetic pressure at the obstacle border. The appearance of nonequilibrium jets and the boundary-layer fluctuations are synchronized by the magnetosonic oscillations of the incoming flow at frequencies of 1–2 mHz. 相似文献
39.
40.
Song Jiang 《Mathematische Nachrichten》1998,190(1):169-183
We consider initial boundary value problems for the equations of the one-dimensional motion of a viscous, heat-conducting gas with density-dependent viscosity that decreases (to zero) with decreasing density. We prove that if the viscosity does not decrease to zero too rapidly, then smooth solutions exist globally in time. 相似文献