Microcalorimetric Adsorption of Alumina Oxide Catalysts for Combination of Ethylbenzene dehydrogenation and carbon Dioxide Shift-reaction

Styrene (STY) is now produced industrially in fairly large quantities by the dehydrogenation of ethylbenzene (EB) using promoted iron oxide catalyst with superheated steam.In this case, small amount of carbon dioxide formed as a by-product was known to inhibit the catalytic activity of commercial catalyst. Recently, there have been some reports which carbon dioxide showed positive effects to promote catalytic activities on the reaction over several catalysts.In this study, we attempted to combine the dehydrogenation of EB to STY with the carbon dioxide shift-reaction. The combine reaction (EB + CO2 → STY + H2O + CO) can be considered as one of the ways of using CO2 resources and can yield simultaneously STY and Carbon oxide.Alumina oxide catalysts such as Al2O3, Na2O/Al2O3 and K2O/Al2O3 were prepared by the usual impregnation method with an aqueous solution of NaNO3 and KNO3, and then calcined at 650℃ for 5 h in a stream of air. The reaction condition is 600℃, flow of CO2 38ml/mon and space velocity (EB) 1.28h-1.     

A Novel Cardiac Glycoside from Parepigynum funingesis

From the dried aerial part ofParepigynumfuningesis Tsiang et P. T. Li (Apocynaceae),a new cardiac glucoside, named parefuningoside (1) had been isolated. Its structure was determined by means of hydrolysis and spectral analysis.     

花丝内插物强化竖直管内凝结换热的实验研究

1前言大空隙率多孔体管内插物-绕花丝内插物，被认为是强化管内凝结换热的最有效途径之一[1]．但以往的研究，由于实验雷诺数范围较小，蒸汽速度较低，要正确全面评价其性能尚显不够。本文在原有工作的基础上，进一步完善了实验系统，改进了测试手段，扩大了实验雷诺数范围，并测试了其阻力性能，对花丝内插物强化管内凝结换热进行了较深入全面的实验研究，以全面评价花丝内插物对管内凝结换热的强化效果。2实验系统本文实验系统如图1所示。实验段是一个竖直套管冷凝器，如图2所示．本试验研究蒸汽完全凝结时的传热。凝结水流量采用容积法计…     

Analysis of far-infrared laser magnetic resonance spectra of CH2Br at 447.3 and 671.1μm

A simple model has been developed to describe the Zeeman patterns of far-infrared laser magnetic resonance spectra of the monobromomethyl radical CH₂Br observed at 447.3 and 671.1μm. A satisfactory agreement between the experimental spectra of the radical and their simulation with this simple model has been achieved. This approach can be used to gain further information about the structure and the spectrum of this interesting radical.     

Study of Strange Quark Mass in CFL Phase

[1]M.Alford,K.Rajagopal,and F.Wilczek,Phys.Lett.B 422 (1998) 247; Nucl.Phys.B 537 (1999) 443. [2]M.Gyulassy and L.McLerran,arXiv:nucl-th/0405013;E.V.Shuryak,arXiv:hep-ph/0405066. [3]K.Rajagopal and F.Wilczek,hep-ph/0011333. [4]M.Alford,Chris Kouvaris,and K.Rajagopal,hepph/0406137. [5]Y.Nambu and G.Jona-Lasinio,Phys.Rev.122 (1961)345. [6]R.T.Cahill and C.D.Roberts,Phys.Rev.D 32 (1985)2419. [7]R.T.Cahill and Susan M.Ganner,hep-ph/9812491. [8]A.W.Steiner,S.Reddy,and M.Prakash,Phys.Rev.D 66 (2002) 094007. [9]P.Amore,M.C.Birse,J.A.McGovern,and N.R.Walet,Phys.Rev.D 65 (2002) 074005. [10]M.Alford and K.Rajagopal,JHEP 0206 (2002) 031. [11]Xiao-Fu Li,Yu-Xin Liu,Hong-Shi Zong,and En-GuangZhao,Phys.Rev.C 58 (1998) 1195. [12]H.Reinhardt,Phys.Lett.B 244 (1990) 2. [13]Steven Weinberg,The Quantum Theory of Fields,Vol.2,Cambridge University Press,Cambridge (1996) p.348.     

Effective-Field Theory on High Spin Systems with Biaxial Crystal Field

Based on the effective-field theory with self-spin correlations and the differential operator technique,physical properties of the spin-2 system with biaxial crystal field on the simple cubic, body-centered cubic, as well as faced-centered lattice have been studied. The influences of the external longitudinal magnetic field on the magnetization,internal energy, specific heat, and susceptibility have been discussed in detail. The phenomenon that the magnetization in the ground state shows quantum effects produced by the biaxial transverse crystal field has been found.     

裂解气相色谱质谱法研究增塑剂邻苯二甲酸二甲酯的热降解机理

用裂解气相色谱-质谱联用方法研究了橡胶产品中使用的增塑剂邻苯二甲酸二甲酯(DMP)在不同温度条件下的热裂解行为.对不同温度条件下裂解产物的分析表明,在初始阶段DMP的裂解产物主要为二氧化碳、苯、甲苯和苯甲酸甲酯.随着温度的升高苯甲酸甲酯进一步裂解成为分子质量更小的自由基,并发生稠环化反应形成更稳定的菲、蒽、间-联三苯、三亚苯等芳香族多环化合物.根据分析实验提供的裂解产物信息和有机物热裂解化学反应的原理对DMP的热裂解反应机理作了探讨,表明在废旧合成橡胶热裂解回收过程中,增塑剂DMP的高温裂解会产生多环芳烃污染物.应选择合适裂解工艺和裂解温度,以减少对环境的污染.     

SUN5500小型机MPI编程与蕴式并行计算的实现方法

基于SUN5500小型计算机并行开发环境，给出了消息传递模型和蕴式行模型的实现方法，通过实例分析了SUNMPI实际编程，并对选取不同模型有不同参数的运算时间进行了比较，结果表明，在SUN5500计算机上MPI模型和蕴式并行模型均能较大地提高运算速度，而且MPI在灵活性和并行程度方面更优。