硫化态三组元NiMoP/γ-Al2O3催化剂的TPR表征及噻吩HDS活性的研究

A series of sulfided tertiary NiMoP/γ-Al2O3 catalysts with different contents of MoO3 were prepared by using molybdophosphoric acid of Keggin structure(H3PMo12O40) and nickel nitrate as origins of active phase components of molybdenum, phosphorus and nickel, and characterized by TPR technique, with their HDS activity being investigated with thiophene as a model substrate. For the sulfided Mo-0 catalyst containing no nickel as promoter, the only hydrogen sulfide evolution peak Ⅰ　is observed at 462 K and attributed to the hydrogenation of the so-called edge sulfur atoms chemisorbed on coordinatively unsaturated(cus) Mox+ sites on the MoS2 phase(MoS2 slab). With the introduction of nickel into the active phase of the sulfided Mo-0 catalyst and with the increase of the molybdenum loading, a new hydrogen sulfide evolution peak Ⅱ gradually develops at the low temperature side of the peak Ⅰ, at the same time accompanied by both the increase of the area ratio of the peak Ⅱ to the peak Ⅰ and the shift of the hydrogen sulfide evolution maximum rate to lower temperatures, which may imply the existence of two kinds of active centers related to molybdenum and nickel respectively and the synergic action between the two centers above. It should be noted that for the sulfided NiMoP/γ-Al2O3 catalysts, the thiophene HDS rate and the quantity of hydrogen sulfide evolved during TPR process increase monotonously with the atomic ratio of molybdenum to nickel in the form of ［n(Ni)+n(Mo)］/n(Ni). On the basis of the results here, the conclusion may be reached that the two kinds of vacancies can be formed on the edge of Ni-Mo-S slab due to the loss of S during TPR process and vacancies or sites related to the H2S evolution peak II should be regarded as the mainly active reaction centers of thiophene HDS.     

聚苯乙烯/蒙脱土纳米复合材料的自组装行为

聚合物／层状硅酸盐（PLS）纳米复合材料由于具有常规复合材料所没有的结构、形态以有较常规聚合物基复合材料更优异的物理力学性能等而引起人们的关注^[1],但以往文献^[1-3]主要报道PLS纳米复合材料的制备与性能表征,对于熔融加工过程中粘土粒子吸高分子的取向和结构研究很少。作者等^[4-6]发现了剥离型聚苯乙烯（PS）／蒙脱土纳米复合材料中的剪切诱导有序结构,并采用广角X射线衍射法（WAXD）、透射电镜法（TEM）和红外二向色性法对其形成机理进行了研究。结果表明,该有序结构的主要来源是分散在PS基体中的蒙脱土初级粒子（Primary particles）内部片层的规整排列以及沿平行于样品表面方面的平面取向,PS的苯环平面平行剪切流动方向取向,而烷项链未见明显取向。本文报道该纳米复合材料的剪切诱导有序结构在升温过程中出现的自组装行为,并用原位升温X射线衍射法和红外二向色性法对蒙脱土初级粒子的规整度以及PS的苯环和烷基链在升温过程中的取向行为进行了研究,在此基础上提出了可能的形成机理。     

~(113)Cd MAS NMR谱表征纳米CdO,CdS在NaY的β笼内形成的构型

通过2 9Si,2 7Al和113CdMASNMR谱 ,观察到如下结果 :( 1)在NaYβ笼内形成的CdO和CdS簇 ,它们的113Cd化学位移分别为 115 .0和 10 0 .0这些值接近于体相CdO的化学位移 83 .5 ,而远离体相CdS的化学位移 5 83 .8,因此它们的构型应归属为体相CdO的立方岩盐构型 ,而不属于体相CdS的配位数为 4的闪锌矿构型 .( 2 )CdO -NaY硫化时 ,NaY的骨架脱铝原子 ,脱铝原子使 β笼的窗口扩大 ,这有利于直径大于 β笼窗口的硫原子 (或H2 S)进入 β笼对CdO[或Cd(OH) +]硫化     

制备工艺对P型ZnO薄膜微观结构和电学特性的影响

本文报道溅射工艺、退火工艺和冷却方式对磷扩散法制备的P型ZnO薄膜的微观结构和电学特性的影响的实验研究.研究结果表明,ZnO薄膜的表面形貌、结晶度、内应力以及电学特性均与制备工艺条件有密切的关系.文章对这些关系的机理做了探讨和分析.     

基于Simulink和FlightGear软件的机载惯性测量单元仿真

包含动力学和运动学特性的机载IMU数据对于飞行对准等惯性系统算法研究具有重要意义。基于人在回路仿真的思想,设计了一种可包含完整飞机模型,不需要设计特定的自动驾驶仪,来实现任意机动下机载惯性测量单元仿真的方案。给出了惯性测量单元仿真模型,设计了基于Simulink、AeroSim模块集及FlightGear模拟飞行软件的新方案,实现了一个机载惯性测量单元的仿真模型,该模型采用飞行摇杆,由人实现对飞机的控制和机动飞行。仿真结果表明,采用该仿真方案,避免了复杂的自动驾驶仪设计,可以得到机动飞行条件下的机载惯性测量单元仿真数据和导航参数基准数据,方案切实可行。     

Galois环上本原序列压缩映射的单性

设Ω是 Ｇａｌｏｉｓ环 ＧＲ（２~ｄ,ｒ）的 Ｔｅｉｃｈｍｕｌｌｅｒ代表集,则 ＧＲ（２~ｄ,ｒ）上每条序列ａ有唯一的权位分解,　其中ａ-ｉ是Ω上序列,同时也可自然视为有限域Ｆ-（２~ｒ）,上序列．设ｆ（ｘ）是环 ＧＲ（２~ｄ,ｒ）上强本原多项式,Ｇ（ｆ（ｘ））表示 ＧＲ（２~ｄ,ｒ）上以ｆ（ｘ）为特征多项式的序列的全体,是Ｆ-（２~ｒ）上一类ｄ－１元多项式, 　本文证明了压缩映射是单射,即对 ａ＝ ｂ当且仅当对所有 ａ,ｂ ∈ Ｇ（ｆ（ｘ））．     

稳定表达egfp基因细胞的构建与克隆

将增强的绿色荧光蛋白（enhanced green fluorescent pprotein,EGFP）基因插在HCMV（humancytomegolovirus）启动子下游,构建了表达质粒pCA13-eG,用脂质体Lipofectin介导分别转染HeLa细胞、Vero细胞,仅通过细胞传代,就最能稳定高效表达EGFP的绿色细胞,比较发现,质粒pCS13-eG转染后,产生能高效表达EGFP的HeLa细胞其比率高于Vero细胞;EGFP高效表达对Vero细胞的毒性大于对HeLa细胞的毒性,本研究表明,绿色细胞轮廓清晰,由于其特有的性质,在用于细胞的形态观察、细胞分裂等研究时会有所作为。     

多台机器流水作业中存在调整时间的Lot—streaming问题

多台机器流水作业的Lot-streaming问题（简称LS）,以往的研究都不考虑调整时间,固定分批数,寻找最优分批大小;本文对机器引入调整时间,研究同时决定最优分批数及分批大小,并给出了相应最优算法。     

Pt/γ-Al2O3催化剂活性位的表征及其噻吩加氢脱硫催化活性

A series of Pt/γ Al 2O 3 catalysts with different content of Pt were characterized by using low temperature FT IR spectroscopy of adsorbed CO, while their catalytic activity for HDS was investigated with thiophene as a model substrate. On the basis of the experimental results, it has been obtained that the pseudo zero order rate of the thiophene HDS reaction is well linearly proportional to the total area of the two IR bands at 2?080 and 1?850 cm -1 of CO adsorbed on Pt/γ Al 2O 3, and that the Pt sites for CO adsorption may be the active centers for thiophene HDS reaction.     

N-环Von-Neumann正则性

环R称为N-环,如果R的素根N(R)=｛r∈R｜存在自然数n使rⁿ=0}.本文不仅对N-环进行了刻划,而且还研究了N-环的VonNeumann正则性.特别证明了：对于N-环R,如下条件是等价的：(1)R是强正则环;(2)R是正则环;(3)R是左SP-环;(4)R是右SF-环;(5)R是MELT,左p-V-环;(6)R是MERT,右p-V-环.因此推广了文献[4]中几乎所有的重要结果,同时也改进或推广了其它某些有关正则环的有用结果.