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71.
Based on finite time thermodynamics, an irreversible combined thermal Brownian heat engine model is established in this paper. The model consists of two thermal Brownian heat engines which are operating in tandem with thermal contact with three heat reservoirs. The rates of heat transfer are finite between the heat engine and the reservoir. Considering the heat leakage and the losses caused by kinetic energy change of particles, the formulas of steady current, power output and efficiency are derived. The power output and efficiency of combined heat engine are smaller than that of single heat engine operating between reservoirs with same temperatures. When the potential filed is free from external load, the effects of asymmetry of the potential, barrier height and heat leakage on the performance of the combined heat engine are analyzed. When the potential field is free from external load, the effects of basic design parameters on the performance of the combined heat engine are analyzed. The optimal power and efficiency are obtained by optimizing the barrier heights of two heat engines. The optimal working regions are obtained. There is optimal temperature ratio which maximize the overall power output or efficiency. When the potential filed is subjected to external load, effect of external load is analyzed. The steady current decreases versus external load; the power output and efficiency are monotonically increasing versus external load. 相似文献
72.
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74.
Odinokov S. B. Kolyuchkin V. V. Kuz’min D. V. Talalaev V. E. Khanevich P. A. Smirnov A. V. Smirnov L. I. 《Optics and Spectroscopy》2021,129(5):547-553
Optics and Spectroscopy - The scope of problems of embedding personal data when copying holograms on a photopolymer substrate with the maximum preservation of the region of a hologram during its... 相似文献
75.
NO, NO2是大气污染源中的常见气体, 对环境具有严重的危害性. 为检测污染源中这两种气体的浓度, 构建了成本较低的基于红外热辐射光源的光声光谱气体检测系统. 分析计算得到了NO, NO2 在2500–6667 nm波段吸收谱线. 通过建立光声传输线RLC振荡电路模型和仿真得到品质因数、声压大小与谐振腔长、内腔半径以及调制频率的关系, 据此设计了光声池几何结构. 实验表明该系统所测得的光声信号与气体浓度有很好的线性关系, 并且对NO, NO2气体极限检测灵敏度分别达到4.01 和1.07 μL. 通过调节激光发射波长和选取滤波片, 该系统还可用于其他微量气体的浓度检测.
关键词:
大气污染
光声光谱
气体检测 相似文献
76.
为了获得相变温度低且热致变色性能优越的光学材料, 室温下在F:SnO2 (FTO)导电玻璃基板表面沉积钨钒金属膜, 再经空气气氛下的热氧化处理, 制备了W掺杂VO2/FTO复合薄膜, 利用X射线光电子能谱、X射线衍射和扫描电镜对薄膜的结构和表面形貌进行了分析. 结果表明: 高温热氧化处理过程中没有生成W, F, V混合氧化物, W以替换V原子的方式掺杂. 与采用相同工艺和条件制备的纯VO2/FTO复合薄膜相比, W掺杂VO2薄膜没有改变晶面取向, 仍具有(110)晶面择优取向, 相变温度下降到35 ℃左右, 热滞回线收窄到4 ℃, 高低温下的近红外光透过率变化量提高到28%. 薄膜的结晶程度明显提高, 表面变得平滑致密, 具有很好的一致性, 对光电薄膜器件的设计开发和工业化生产具有重要意义.
关键词:
W掺杂
2')" href="#">VO2
FTO导电玻璃
磁控溅射 相似文献
77.
The structural evolution, stabilities, and electronic properties of copper-doped lithium Li n Cuλ (n?=?1–9, λ?=?0, ?1) clusters have been systematically investigated using a density functional method at PW91PW91 level. Extensive searches for ground-state structures were carried out, and the results showed the copper tends to occupy the most highly coordinated position and form the largest probable number of bonds with lithium atoms. By calculating the binding energies per atom, fragmentation energies and the HOMO-LOMO gaps, we found LiCu, Li7Cu, LiCu?, Li2Cu? and Li8Cu? clusters have the stronger relative stability and enhanced chemical stability. The content and pattern of frontier MOs for the most stable doped isomers were analysed to investigate the bond nature of interaction among Li and Cu atoms. The results show some σ-type and π-type bonds are formed among them, and with small admixture of the Cu d characters. To achieve a deep insight into the electron localization and reliable electronic structure information, the natural population analysis and electron localization function were performed and discussed. 相似文献
78.
Chang-Chun Ding Shao-Yi Wu Qing-Sheng Zhu Guo-Liang Li Zhi-Hong Zhang Yong-Qiang Xu 《Molecular physics》2013,111(12):1478-1484
The local lattice distortions and the electron paramagnetic resonance (EPR) parameters (g factors, hyperfine structure constants and zero-field splittings) for Cu2+, Mn2+ and Fe3+ in ZnWO4 are theoretically studied based on the perturbation calculations for rhombically elongated octahedral 3d9 and 3d5 complexes. The impurity centres on Zn2+ sites undergo the local elongations of 0.01, 0.002 and 0.013 Å along the C2 axis and the planar bond angle variations of 8.1°, 8.0° and 8.6° for Cu2+, Mn2+ and Fe3+, respectively, due to the Jahn–Teller effect and size and charge mismatch. In contrast to the host Zn2+ site with obvious axial elongation (~0.31 Å) and perpendicular (angular) rhombic distortion, all the impurity centres demonstrate more regular octahedral due to the above local lattice distortions. The copper centre exhibits significant Jahn–Teller reductions for the spin-orbit coupling and orbital angular momentum interactions, characterised by the Jahn–Teller reduction factor J (≈0.29 ? 1). The calculated EPR parameters agree well with the experimental results. The local structures of the impurity centres are analysed in view of the corresponding lattice distortions. 相似文献
79.
Almost all natural, social and man-made-engineered systems can be represented by a complex network to describe their dynamic behaviors. To make a real-world complex network controllable with its desired topology, the study on network controllability has been one of the most critical and attractive subjects for both network and control communities. In this paper, based on a given directed–weighted network with both state and control nodes, a novel optimization tool with extremal dynamics to generate an optimal network topology with minimum control nodes and complete controllability under Kalman’s rank condition has been developed. The experimental results on a number of popular benchmark networks show the proposed tool is effective to identify the minimum control nodes which are sufficient to guide the whole network’s dynamics and provide the evolution of network topology during the optimization process. We also find the conclusion: “the sparse networks need more control nodes than the dense, and the homogeneous networks need fewer control nodes compared to the heterogeneous” (Liu et al., 2011 [18]), is also applicable to network complete controllability. These findings help us to understand the network dynamics and make a real-world network under the desired control. Moreover, compared with the relevant research results on structural controllability with minimum driver nodes, the proposed solution methodology may also be applied to other constrained network optimization problems beyond complete controllability with minimum control nodes. 相似文献
80.