Synthesis and transformations of 3-allyl-7,10-dimethyl-2-sulfanylidene-2,3,5,6-tetrahydrospiro[benzo[<Emphasis Type="Italic">h</Emphasis>]quinazoline-5,1′-cyclopentan]-4(1<Emphasis Type="Italic">H</Emphasis>)-one

Ethyl 4′-amino-5′,8′-dimethyl-1′H-spiro[cyclopentane-1,2′-naphthalene]-3′-carboxylate reacted with allyl isothiocyanate to give 3-allyl-7,10-dimethyl-2-sulfanylidene-2,3,5,6-tetrahydrospiro[benzo[h]quinazoline- 5,1′-cyclopentan]-4(1H)-one. Reactions of the latter with alkyl halides and hydrazine hydrate and subsequent transformations of the products afforded a series of new benzo[h]quinazoline derivatives containing an allyl group in the 3-position.     

New eco-friendly low-cost binders for Li-ion anodes

In the production of commercial Li-ion batteries, the active materials slurries are generally prepared using polyvinylidene fluoride (PVdF) as binder because of its good adhesion properties and electrochemical stability. Unfortunately, there are some disadvantages related to the use of PVdF: the most important is the use of toxic and environmentally unfriendly solvents, such as N-methyl-pyrrolidone (NMP), and the second is the high costs. In the light of these considerations, it seemed straightforward to investigate the suitability of some water-soluble, inexpensive, and eco-friendly materials to test as alternative binders (sodium alginate, chitosan tragacanth gum, gelatin). The rheological properties of these materials have been investigated in addition to the electrochemical characterization. Furthermore, graphite electrodes with PVdF, carboxymethyl cellulose (CMC), and styrene-butadiene rubber (SBR) binders have been considered for sake of comparison. We found that some of these water-soluble binders, besides good electrochemical performances, showed a high adhesion to the current collector and a good electrochemical stability under the experimental conditions employed, which makes them interesting for the next generation of Li-ion batteries.     

α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript> thin films by liquid phase deposition: low-cost option for supercapacitor

In the present study, iron oxide (α-Fe₂O₃) thin films with good adhesion on stainless steel substrates are deposited by liquid phase deposition (LPD) technique, which is additive and binder-free. Iron oxyhydroxide (FeOOH) thin films are formed by means of a ligand-exchange equilibrium reaction of metal-fluoro complex ions and an F^?ions consuming reaction by using boric acid (H₃BO₃) as a scavenging agent. These films are annealed at 500 °C to get α-Fe₂O₃ thin films. The transformation from hydrophobic to hydrophilic nature of the films is observed due to annealing. The films are characterized by different techniques. The α-Fe₂O₃ film is checked for electrochemical supercapacitive performance in Na₂SO₃ solutions of various concentrations. Specific capacitance is calculated from cyclic voltammetry at numerous scan rates (5–200) mV s^?1. The highest obtained value of specific capacitance is 582 F g^?1 at 5 mV s^?1 for 0.5 M Na₂SO₃ electrolyte. The maximum values of specific power and specific energy are 6.9 and 53.4 Wh kg^?1 from the charge-discharge curve at the current density 2 mA cm^?2 in 0.5 M Na₂SO₃ electrolyte.     

The influence of stabilizers on the properties of silicone rubber

The influence of various stabilizers on the properties of rubber based on silicone rubber SKTV is studied. It is established that the use of the Ca/Zn stabilizer in the resin composition makes it possible to increase thermal resistance and physico-mechanical characteristics of the rubber used to make sealing elements in the automotive industry.     

Evaluation of the biosafety of cyanoacrylate adhesive in vitro

This paper considers the evaluation of the biosafety of cyanoacrylate adhesive in vitro on human multipotent mesenchymal stem cells. This adhesive is intended for medical use, in particular, for X-ray and endovascular interventions. A toxicity study was carried out in a culture of multipotent mesenchymal stem cells isolated from human subcutaneous fat. As a result of the work, the concentration of cyanoacrylate adhesive in lipiodol was chosen, which has the lowest toxicity.     

Determination of the heat resistance of polymer construction materials by the dynamic mechanical method

Russian and foreign standards for the techniques for the determination of the heat resistance of polymer materials are analyzed and the incorrectness of their use for polymer construction materials is shown. The determination of the heat resistance by the low-frequency dynamic mechanical method based on the temperature derivative extrema of the dynamic modulus of elasticity and the dynamic loss modulus under the transition of polymer matrices from the glassy to the highly elastic state is experimentally substantiated for multicomponent polymer compositions with dispersed or fibrous fillers.     

Estimates of Wiman–Valiron type for evolution equations

We establish estimates of Wiman–Valiron type for solutions of evolution equations with a pseudodifferential operator of the Hörmander class in a Hilbert space. Estimates of this type characterize the behavior of the solution of the problem as t→∞ or t → 0 depending on the decay or growth rate of the Fourier coefficients of the initial data.     

Non-accretive Schrödinger operators and exponential decay of their eigenfunctions

We consider non-self-adjoint electromagnetic Schrödinger operators on arbitrary open sets with complex scalar potentials whose real part is not necessarily bounded from below. Under a suitable sufficient condition on the electromagnetic potential, we introduce a Dirichlet realisation as a closed densely defined operator with non-empty resolvent set and show that the eigenfunctions corresponding to discrete eigenvalues satisfy an Agmon-type exponential decay.     

Accelerated reference systems in AdS space

We consider reference systems of uniformly accelerated observers in anti-de Sitter space. We construct coordinate transformations for the transition from an inertial reference system to a uniformly accelerated reference system for all acceleration values, both greater and less than critical. The basis for the construction are the Beltrami coordinates, natural coordinates for describing a uniformly accelerated motion because geodesics in anti-de Sitter space in these coordinates become straight lines, i.e., can be described by linear functions. Because translations of space–time coordinates in anti-de Sitter space are non-Abelian, a nontrivial problem of defining the comoving inertial reference system arises. Constructing the coordinate system of an accelerated observer using this auxiliary comoving inertial reference system requires additional transformations that not only equalize the velocities of the two systems but also equalize the system origins. The presence of a critical acceleration in anti-de Sitter space leads to a difference in explicit expressions in passing to an accelerated coordinate system for accelerations greater and less than critical.     

Sub-Riemannian distance on the Lie group SL(2)

We find the distances between arbitrary elements of the Lie group SL(2) for the left invariant sub-Riemannian metric also invariant with respect to the right shifts by elements of the Lie subgroup SO(2) ? SL(2), in other words, the invariant sub-Riemannian metric on the weakly symmetric space (SL(2) × SO(2))/ SO(2) of Selberg.