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21.
This paper presents a new conversion technique of the standard linear programming problem into a homogenous form desired for the Karmarkar’s algorithm, where we employed the primal–dual method. The new converted linear programming problem provides initial basic feasible solution, simplex structure, and homogenous matrix. Apart from the transformation, Hooker’s method of projected direction is employed in the Karmarkar’s algorithm and the modified algorithm is presented. The modified algorithm has a faster convergence with a suitable choice of step size. 相似文献
22.
23.
Hsuan-Chih Chu Tzung-Chi Liang Harihara Padhy Shou-Jen Hsu Hong-Cheu Lin 《European Polymer Journal》2011,47(12):2266-2276
In this study, we used photoluminescence (PL) quenching and transmission electron microscopy (TEM) to study the morphological behavior of hydrogen-bonded (H-bonded) supramolecular assemblies of luminescent H-acceptor polymers and H-donor gold nanoparticles (Au NPs). In fluorescence titration experiments, the lateral Me and MeO substituents on the fluorescent H-acceptor side-chain polymers PBOT1–PBOT3 and PBT1–PBT3 exhibited different electron-donating capabilities, thereby inducing different degrees of H-bonding and dipole–dipole interactions, as evidenced by effective fluorescence quenching upon the addition of surface-modified Au NPs bearing acid and acid-free surfactants (AuSCOOH and AuSC10, respectively). Among all of our tested nanocomposites, the highest Stern–Volmer quenching constant (KSV) was that obtained from the assembly of AuSCOOH with the homopolymer PBOT1. In addition, we developed fittable exponential equations to predict the values of KSV of other fluorescent polymers (containing various molar ratios of pyridyl conjugated units) when titrated with these NP quenchers. The morphologies observed in the TEM images confirmed that fluorescence quenching resulted from the self-assembly of the supramolecular nanocomposites, mediated by H-bonds between the fluorescent H-acceptors of the polymers and the H-donors of the Au NPs presenting acid-modified surfactants. 相似文献
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25.
Calculation of cross-sections for the two-electron excitation in helium-like ions by electron impact employing Coulomb-Born-Oppenheimer
(CBO) approximation is presented. Analytical expressions for the differential and total scattering cross-sections without
using partial wave expansion of the wavefunction reported earlier have been used. The total and differential scattering cross-sections
for each of the excitations 1s
2
1
S* → 2s
2
1
S
e
, 2s2p
1.3
P
0, 2p
2
1
S
e
,3
P
e,1
D
e in Be2+ and B3+ are computed. Results for Li+ reported earlier are also included for comparison. 相似文献
26.
Diazocoupling of dihydroquinolin-4-ones with aryldiazonium nitrates gave the corresponding diazo derivatives, which undergo facile (4+2) cycloaddition reactions with phenylpropiolic acid to afford 2-aryl-4a-methyl-10-oxo-4-phenyl-2,4a,5,10-tetrahydropyridazino[4,3-b]quinoline-3-carboxylic acid derivatives 3. However, with β-nitrostyrene a mixture of three isomeric products 4a-c was obtained. 相似文献
27.
Support vector regression (SVR) has been successfully applied in various domains, including predicting the prices of different financial instruments like stocks, futures, options, and indices. Because of the wide variation in financial time-series data, instead of using only a single standard prediction technique like SVR, we propose a hybrid model called USELM-SVR. It is a combination of unsupervised extreme learning machine (US-ELM)-based clustering and SVR forecasting. We assessed the feasibility and effectiveness of this hybrid model using a case study, predicting the one-, two-, and three-day ahead closing values of the energy commodity futures index traded on the Multi Commodity Exchange in India. Our experimental results show that the USELM-SVR is viable and effective, and produces better forecasts than our benchmark models (standard SVR, a hybrid of SVR with self-organizing map (SOM) clustering, and a hybrid of SVR with k-means clustering). Moreover, the proposed USELM-SVR architecture is useful as an alternative model for prediction tasks when we require more accurate predictions. 相似文献
28.
Duryodhan Sahu Harihara Padhy Dhananjaya Patra Jen‐hsien Huang Chih‐wei Chu Hong‐Cheu Lin 《Journal of polymer science. Part A, Polymer chemistry》2010,48(24):5812-5823
A series of novel low‐bandgap triphenylamine‐based conjugated polymers ( PCAZCN , PPTZCN , and PDTPCN ) consisting of different electron‐rich donor main chains (N‐alkyl‐2,7‐carbazole, phenothiazine, and cyclopentadithinopyrol, respectively) as well as cyano‐ and dicyano‐vinyl electron‐acceptor pendants were synthesized and developed for polymer solar cell applications. The polymers covered broad absorption spectra of 400–800 nm with narrow optical bandgaps ranging 1.66–1.72 eV. The highest occupied molecular orbital and lowest unoccupied molecular orbital levels of the polymers measured by cyclic voltammetry were found in the range of ?5.12 to ?5.32 V and ?3.45 to ?3.55 eV, respectively. Under 100 mW/cm2 of AM 1.5 white‐light illumination, bulk heterojunction photovoltaic devices composing of an active layer of electron‐donor polymers ( PCAZCN , PPTZCN , and PDTPCN ) blended with electron‐acceptor [6,6]‐phenyl‐C61‐butyric acid methyl ester or [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC71BM) in different weight ratios were investigated. The photovoltaic device containing donor PCAZCN and acceptor PC71BM in 1:2 weight ratio showed the highest power conversion efficiency of 1.28%, with Voc = 0.81 V, Jsc = 4.93 mA/cm2, and fill factor = 32.1%. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010 相似文献
29.
Vijaya Madhyanapu Golla Mallika Kalyan Upasana Gholap Hara Prasad Padhy Roshitha K. Ramachandran Gananadhamu Samanthula 《Journal of mass spectrometry : JMS》2024,59(3):e5007
The present study aimed to separate, identify, and characterise the degradation products formed when mavacamten is exposed to stress degradation as well as the stability of the drug in various environments and also to understand its degradation chemistry. Prediction of in silico toxicity and mutagenicity was aimed at the observed degradation products. Stress degradation along with stability studies and degradation kinetics were performed on mavacamten, and separation of degradation products was carried out by high-performance liquid chromatography. Tandem mass spectrometry studies were executed to characterise the structures of degradation products using product ion fragments. Orthogonally, nuclear magnetic resonance experiments were conducted to elucidate the structures having ambiguity in characterising them. Deductive Estimation of Risk from Existing Knowledge and Structure Activity Relationship Analysis using Hypotheses software were used to establish in silico toxicity and mutagenic profiles of mavacamten and its degradation products. Two degradation products of mavacamten found in acidic hydrolytic stress conditions were separated, identified, characterised, and proposed as 1-isopropylpyrimidine-2,4,6(1H,3H,5H)-trione and 1-phenylethanamine. Mavacamten was found to be stable under different pH and gastrointestinal conditions. The degradation kinetics of mavacamten under 1 N acidic condition followed zero-order kinetics, and it was degraded completely within 6 h. In silico toxicity and mutagenicity studies revealed that 1-phenylethanamine can be a skin sensitiser. A high-performance liquid chromatography method was developed for the separation of degradation products of mavacamten and characterised by liquid chromatography–tandem mass spectrometry and nuclear magnetic resonance. During the manufacturing and storage of drug product, precautions need to be taken when dealing with acidic solutions as the drug is prone to hydrolysis in acidic conditions. The formation of 1-phenylethanamine under these conditions is to be monitored as it is a skin sensitiser. 相似文献
30.
Punnag Padhy Mohammad Asif Zaman Michael Anthony Jensen Lambertus Hesselink 《Electrophoresis》2021,42(9-10):1079-1092
Electrically polarizable micro- and nanoparticles and droplets can be trapped using the gradient electric field of electrodes. But the spatial profile of the resultant dielectrophoretic force is fixed once the electrode structure is defined. To change the force profile, entire complex lab-on-a-chip systems must be re-fabricated with modified electrode structures. To overcome this problem, we propose an approach for the dynamic control of the spatial profile of the dielectrophoretic force by interfacing the trap electrodes with a resistor and an inductor to form a resonant resistor–inductor–capacitor (RLC) circuit. Using a dielectrophoretically trapped water droplet suspended in silicone oil, we show that the resonator amplitude, detuning, and linewidth can be continuously varied by changing the supply voltage, supply frequency, and the circuit resistance to obtain the desired trap depth, range, and stiffness. We show that by proper tuning of the resonator, the trap range can be extended without increasing the supply voltage, thus preventing sensitive samples from exposure to high electric fields at the stable trapping position. Such unprecedented dynamic control of dielectrophoretic forces opens avenues for the tunable active manipulation of sensitive biological and biochemical specimen in droplet microfluidic devices used for single-cell and biochemical reaction analysis. 相似文献