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991.
The properties of the relativistic alpha fragments produced in interactions of 84Kr at around 1 A GeV in nuclear emulsion are investigated. The experimental results are compared with the similar results
obtained from various projectiles with emulsion interactions at different energies. The total, partial nuclear cross-sections
and production rates of alpha fragmentation channels in relativistic nucleus-nucleus collisions and their dependence on the
mass number and initial energy of the incident projectile nucleus are investigated. The yields of multiple alpha fragments
emitted from the interactions of projectile nuclei with the nuclei of light, medium and heavy target groups of emulsion-detector
are discussed and they indicate that the projectile-breakup mechanism seems to be free from the target mass number. It is
found that the multiplicity distributions of alpha fragments are well described by the Koba-Nielsen-Olesen (KNO) scaling presentation.
The mean multiplicities of the freshly produced or newly created charged secondary particles, normally known as shower and
secondary particles associated with target in the events where the emission of alpha fragments were accompanied by heavy projectile
fragments having Z ≥ 3 seem to be constant as the alpha fragments multiplicity increases, and exhibit a behavior independent of the alpha fragments
multiplicity. 相似文献
992.
Synthesis of Pharmacologically Active Bis(indolyl) and Tris(indolyl) Derivatives Using Chlorotrimethylsilane 下载免费PDF全文
Nongthombam G. Singh Chingrishon Kathing Jims W. S. Rani Rishan L. Nongkhlaw 《中国化学会会志》2014,61(4):442-446
Chlorotrimethylsilane is found to be a comparatively fast and efficient catalyst for carrying out electrophilic substitution reactions of indoles with various aldehydes/ketones/triethylorthoformate, yielding excellent amount of bis(indolyl)methanes/tris(indolyl)methanes. The merits of this protocol are avoidance of any external energy source, minimal reaction time, simple and easy procedure and high yield under solvent free room temperature condition. The versatility of this method has been tested with various aldehydes/ketones and received satisfactory results. 相似文献
993.
A very simple, highly-sensitive and selective quenchofluorimetric method for the rapid determination of molybdenum(VI) in aqueous media is described. The method is based on the instantaneous quenching action by the metal-ion upon the native fluorescence of bathophenanthrolinedisulphonate (4,7-diphenyl-1,10-phenanthrolinedisulphonate) solution [lambda(ex) (max) 288 nm; lambda(em) (max) 444.8 nm] in the optimum pH-range of 3.0-3.7 at room temperature (25 +/- 5 degrees ). The fluorescence quenching is co-linear in the range of 0.01-1.0 ppm molybdenum. Large excesses of over 50 cations, anions and some common complexing agents were found to have no interference. Cu, Ni, Co, Fe and V can be tolerated only up to the corresponding amount of molybdenum. Interference from greater amounts can however be removed by a one-step ion-exchange separation process. The developed method was successfully tested over several standard alloys, synthetic mixtures of various compositions, factory effluents and in spiked environmental waters. 相似文献
994.
Singh S Aggarwal A Farley C Hageman BA Batteas JD Drain CM 《Chemical communications (Cambridge, England)》2011,47(25):7134-7136
Porphyrins appended with four rigid hydrogen bonding motifs on the meso positions were synthesized and self-assembled into a cofacial cage with four complementary bis(decyl)melamine units in dry solvents. The hydrocarbon chains on the melamine mediate the formation of nanofilms on surfaces as the solvent slowly evaporates. 相似文献
995.
Dattatray J. Late Mahendra A. More Sucharita Sinha K. Dasgupta Pankaj Misra B. N. Singh Lalit M. Kukreja Sudha V. Bhoraskar Dilip S. Joag 《Applied Physics A: Materials Science & Processing》2011,104(2):677-685
The paper deals with the comparative study of nanocrystalline Lanthanum hexaboride (LaB6) thin films grown on various substrates by Pulsed laser deposition and Arc plasma method. Field emission studies were carried
out on LaB6 films deposited on various substrates show metallic behavior of the emitters. The high value of field enhancement factors,
indicating that the electron emission from LaB6 nanoscale protrusions deposited on emitter surface. The post field emission surface morphology of the emitters showed no
significant erosion of the films during continuous operation. The observed behavior indicates that it is linked with the growth
of LaB6 films on substrate crystal structure. The LaB6 nanocrystallites/nanowires films were synthesized using arc plasma method shows good emission current stability. The LaB6 micro/nanocrystallites were also obtained by picosecond laser irradiation which gives high enhancement β factor, and good emission current stability along with high current density. The results reveal that nanocrystalline LaB6 films, exhibit high resistance to ion bombardment and excellent structural stability and are more promising emitters for
practical applications in field emission based new generation devices. 相似文献
996.
We report a novel method for producing aligned ZnO nanorods (ANR) on self-grown ZnO template in a single step process involving growth of ZnO by vapor transport, followed by quenching of growing ZnO flux in liquid nitrogen. In the present study Zn powder turns into ZnO sheet under oxygen flow at ∼900 °C and bottom surface of the sheet acts as template for the growth of ANR. It is revealed from XRD and EDAX analysis that the bottom of the sheet is Zn rich region and acts as self catalyst for the growth of ANR. The grown nanorods have length up to several tens of micrometers with diameters ranging from ∼100 to 150 nm. Microstructural analysis of ANR indicates the fractal like configuration. The field emission properties have been investigated for ANR with fractal geometry using the ANR on self-grown ZnO template as a cathode directly. The turn-on electric field required to draw current density of ∼1.0 μA/cm2 has been found to be ∼0.98 V/μm. The field enhancement factor based on Fowler-Nordheim (F-N) plot was found to be ∼7815 for ANR. The fractal geometry of ANR has been shown to be advantageous for achieving improved field emission features. The present investigations of synthesis involving formation of ANR over self-grown ZnO template, together with fractal configuration of the as-synthesized ANR, are first of their type. 相似文献
997.
In this paper anisotropic cosmological models with bulk viscosity and quintessence have been studied. Some exact solutions of Einstein field equations with bulk viscosity and quintessence on the background of anisotropic Bianchi Type I space-time are obtained. The new cosmological models approach to isotropy with evolution of the universe. Physical properties of these cosmological models have also been discussed. 相似文献
998.
A new tetradentate dihydrogen perchlorate macrocyclic ligand (2,4,9,11-tetraphenyl-1,5,8,12-tetraazacyclotetradeca-1,4,8,11-tetraene dihydrogen perchlorate) was prepared and characterised. The macrocycle behaves as a selective chelating ion-exchanger for some metal ions. The polystyrene-based membrane electrode is found to exhibit quite promising selectivity for Cr3+ ions. It can be used to estimate chromium concentrations in the range 3.16x 10(-6)-1.00x10(-1) M with a near-Nernstian slope of 17.5 mV per decade of concentration between pH 3.0 to 6.5. The electrode is found to possess a fast response time of 15 s and was used over a period of three months with good reproducibility (s = +/- 0.3 mV). The selectivity coefficient values for mono-, di- and trivalent cations indicate excellent selectivity for Cr3+ ions over a large number of other cations. Anions such as Cl- and SO4(2-) do not interfere and the electrode also works satisfactorily in a mixed organic-water solution. The sensor has been used as an indicator electrode for the potentiometric titration of Cr3+ with EDTA. The practical utility of the membrane sensor has also been demonstrated in solutions contaminated with detergents (CTAB and SDS). Above all, the membrane sensor has been very successfully used to determine Cr3+ in some foods. 相似文献
999.
Shri Singh 《Phase Transitions》2013,86(3):183-209
A comprehensive review of the recent developments regarding the phenomenon of reentrant phase transitions (RPT) in liquid crystals is presented. In addition to liquid crystals this phenomenon has been observed in amazingly diverse systems. A critical assessment of the experimental investigations concerning single and multiple reentrances is given. A brief account of the theoretical efforts is also given. The article ends with the identification of the factors which impede the proper understanding of the phenomenon. 相似文献
1000.
We propose new phase- and polarisation-insensitive receivers for coherent optical fibre communication systems which have the following characteristic features: (a) insensitivity to LO excess noise in addition to phase- and polarization-insensitivity; (b) absence of optical PLL and polarization control devices; (c) a smaller detector bandwidth requirement than for heterodyne systems; (d) the same source linewidth requirement as for heterodyne systems with non-coherent demodulation; (e) the possibility of a complete optoelectronic integrated circuit (OEIC) version in the future. 相似文献