全文获取类型
收费全文 | 252篇 |
免费 | 2篇 |
专业分类
化学 | 116篇 |
晶体学 | 2篇 |
力学 | 14篇 |
数学 | 55篇 |
物理学 | 67篇 |
出版年
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2016年 | 3篇 |
2014年 | 4篇 |
2013年 | 19篇 |
2012年 | 4篇 |
2011年 | 11篇 |
2010年 | 6篇 |
2009年 | 9篇 |
2008年 | 16篇 |
2007年 | 7篇 |
2006年 | 11篇 |
2005年 | 7篇 |
2004年 | 9篇 |
2003年 | 15篇 |
2002年 | 3篇 |
2001年 | 7篇 |
2000年 | 6篇 |
1999年 | 11篇 |
1998年 | 6篇 |
1997年 | 2篇 |
1996年 | 6篇 |
1995年 | 6篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1989年 | 2篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1977年 | 4篇 |
1975年 | 2篇 |
1972年 | 1篇 |
1966年 | 2篇 |
1965年 | 1篇 |
1964年 | 1篇 |
1961年 | 1篇 |
1959年 | 1篇 |
1958年 | 2篇 |
1955年 | 1篇 |
1954年 | 1篇 |
1922年 | 1篇 |
排序方式: 共有254条查询结果,搜索用时 15 毫秒
41.
RD Harris WS Baker Van Stipdonk MJ RM Crooks EA Schweikert 《Rapid communications in mass spectrometry : RCM》1999,13(14):1374-1380
A suite of keV polyatomic or 'cluster' projectiles was used to bombard unoxidized and oxidized self-assembled monolayer surfaces. Negative secondary ion yields, collected at the limit of single ion impacts, were measured and compared for both molecular and fragment ions. In contrast to targets that are orders of magnitude thicker than the penetration range of the primary ions, secondary ion yields from polyatomic projectile impacts on self-assembled monolayers show little to no enhancement when compared with monatomic projectiles at the same velocity. This unusual trend is most likely due to the structural arrangement and bonding characteristics of the monolayer molecules with the Au(111). Copyright 1999 John Wiley & Sons, Ltd. 相似文献
42.
43.
MJ Singh DO Kataria N Madhavan P Sugathan JJ Das DK Awasthi AK Sinha R Shanker 《Pramana》1999,53(4):743-764
A projectile ion-recoil ion coincidence technique has been employed to study the multiple ionization and the charge transfer
processes in collisions of 60–120 MeV Si
q+ (q = 4−14) ions with neutral argon atoms. The relative contribution of different ionization channels, namely; direct ionization,
electron capture and electron loss leading to the production of slow moving multiply charged argon recoil ions have been investigated.
The data reported on the present collision system result from a direct measurement in the considered impact energy for the
first time. The total ionization cross-sections for the recoil ions are shown to scale as q
1.7/E
p
0.5
, where E
p is the energy in MeV of the projectile and q its charge state. The recoil fractions for the cases of total- and direct ionizations are found to decrease with increasing
recoil charge state j. The total ionization fractions of the recoils are seen to depend on q and to show the presence of a ‘shell-effect’ of the target. Further, the fractions are found to vary as 1/j
2 upto j = 8+. The average recoil charge state 〈j〉 increases slowly with q and with the number of lost or captured electrons from or into the projectile respectively. The projectile charge changing
cross-sections σ
qq′ are found to decrease with increasing q for loss ionization and to increase with q for direct-and capture ionization processes respectively. The physics behind various scaling rules that are found to follow
our data for different ionization processes is reviewed and discussed. 相似文献
44.
Miriam C. Strumia Alejandra Halabi Paola A. Pucci George R. Newkome Charles N. Moorefield Jon D. Epperson 《Journal of polymer science. Part A, Polymer chemistry》2000,38(15):2779-2786
Aware of the growing interest in materials that exhibit specific physiochemical properties and potential applications, we focused our work on modifying commercial agarose with polyfunctional dendrons capable of molecular recognition through hydrogen bonding. 2,6‐Di(acylamino)pyridine moieties within the internal superstructure of dendritic macromolecules have been reported to be capable of forming H‐bonded complexes with imide groups, such as barbituric acid and its derivatives. We report the synthesis of new dendrons possessing multiple 2,6‐di(acylamino)pyridinyl sites, each capable of molecular recognition, and the development of new polymeric supports of an activated agarose matrix by surface modification. From comparative studies of the beads modified by different dendrons, we found improved results in those dendritic supports possessing 2,6‐di(acylamino)pyridinyl moieties, except when their juxtaposition between the groups promoted inner H bonds. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 2779–2786, 2000 相似文献
45.
Tristan A. Geervliet Ionela Gavrila Giuseppe Iasilli Francesco Picchioni Andrea Pucci 《化学:亚洲杂志》2019,14(6):877-883
This study reports for the first time the use of bio‐based alternatives for PMMA as host matrix for luminescent solar concentrators (LSCs). Notably, two types of renewable polyesters were synthesized in varying molar ratios via a two‐step melt‐polycondensation reaction with dibutyl tin oxide as catalyst. The first is a homopolymer of diethyl 2,3:4,5‐di‐O‐methylene galactarate (GxMe) and isosorbide (IGPn), and the second is a random copolymer of GxMe with 1,3‐propanediol and dimethyl terephthalate (GTPn). The two polyesters were found to be optically transparent, totally amorphous with a Tg higher than 45 °C and temperature resistance comparable to PMMA. Lumogen Red (LR) and an aggregation‐induced emission (AIE) fluorophore, TPETPAFN, were utilized as fluorophores and the derived thin polymer films (25 μm) were found highly homogeneous, especially for those prepared from GTPn, possibly due to the presence of compatibilizing terephthalate units in the matrix composition and the higher molecular weight. The spectroscopic characterization and the optical efficiency determination (ηopt) evidenced LSCs performances similar or superior to those collected from LR/PMMA thin films. Noteworthy, ηopt of 7.7 % and 7.1 % were recorded for the GTPn‐based matrix containing LR and TPETPAFN, respectively, thus definitely supporting the bio‐based polyesters as renewable and highly fluorophore‐compatible matrices for high‐performance LSCs. 相似文献
46.
Gabriella Leo Laura Cartechini Piero Pucci Antonio Sgamellotti Gennaro Marino Leila Birolo 《Analytical and bioanalytical chemistry》2009,395(7):2269-2280
The identification of proteinaceous components in paintings remains a challenging task for several reasons. In addition to
the minute amount of sample available, complex and variable chemical composition of the paints themselves, possible simultaneous
presence of several binders and contaminants, and degradation of the original materials due to aging and pollution are complicating
factors. We proposed proteomic strategies for the identification of proteins in binders of paintings that can be adapted to
overcome the requirements and difficulties presented by specific samples. In particular, we worked on (1) the development
of a minimally invasive method based on the direct tryptic cleavage of the sample without protein extraction; (2) the use
of microwave to enhance the enzymatic digestion yield, followed by the analysis of the peptide mixtures by nanoLC-MS/MS with
electrospray ionization (ESI). Moreover, as an additional tool to tackle the problem of contaminating proteins, we exploited
the possibility of generating an exclusion list of the mass signals that in a first run had been fragmented and that the mass
spectrometer had to ignore for fragmentation in a subsequent run. The methods, tested on model samples, allowed the identification
of milk proteins in a sample from paintings attributed to Cimabue and Giotto, thirteenth-century Italian masters, decorating
the vaults of the upper church in the Basilica of St. Francis in Assisi, Italy. 相似文献
47.
Roberta Filippucci Patrizia Pucci Frédéric Robert 《Journal de Mathématiques Pures et Appliquées》2009,91(2):156-177
Using the Mountain-Pass Theorem of Ambrosetti and Rabinowitz we prove that admits a positive weak solution in of class , whenever , and . The technique is based on the existence of extremals of some Hardy–Sobolev type embeddings of independent interest. We also show that if is a weak solution in of , then when either , or and u is also of class . 相似文献
48.
49.
Pucci V Bonelli F Monteagudo E Laufer R 《Rapid communications in mass spectrometry : RCM》2006,20(8):1240-1246
A very highly sensitive and highly selective liquid chromatographic/tandem mass spectrometric (LC/MS/MS) method was developed to evaluate and quantify a new drug candidate in different biological matrices. Following a simple plasma protein precipitation using acetonitrile, the post-treatment samples were analyzed on a C18 column interfaced with a new generation of triple-quadrupole mass spectrometer. The recently introduced triple-quadrupole mass spectrometer, the TSQ Quantum Ultra, with enhanced mass-resolution capability, demonstrated improved sensitivity (0.05 ng/mL), coupled with suitable accuracy and precision, over a broad linear dynamic range (0.05-1000 ng/mL). A comparison of the assay performance data (dynamic range, calibration curve equation, precision and accuracy) of the enhanced resolution method against a unit resolution method under optimized conditions showed the performance improvement of the enhanced mass resolution method for bioanalytical high-throughput applications. The enhanced mass resolution method herein described was successfully applied to the evaluation of the pharmacokinetic profile of a new drug candidate in rat, rabbit and dog plasma samples. 相似文献
50.
A material is of coaxial type if the Cauchy stress tensor T and the strain tensor B are coaxial for all deformations. Clearly a hyperelastic material is of coaxial type if and only if it is isotropic. Here we present a weaker definition of materials of coaxial type. Anisotropic materials may be of a coaxial type in a weak sense if for a given specific B we have that TB=BT. We denote these materials B-coaxial. We show that for transverse isotropic materials weak coaxial constitutive equations may be characterized using universal relations. We discuss the impact of B-coaxial materials in the modeling of soft tissues. We conclude that B-coaxial materials are a strong evidence that in real world materials two anisotropic invariants are always necessary to model in a meaningful and correct way single fiber reinforced materials. 相似文献