全文获取类型
收费全文 | 2008篇 |
免费 | 407篇 |
国内免费 | 204篇 |
专业分类
化学 | 1374篇 |
晶体学 | 6篇 |
力学 | 108篇 |
综合类 | 18篇 |
数学 | 241篇 |
物理学 | 872篇 |
出版年
2024年 | 5篇 |
2023年 | 45篇 |
2022年 | 72篇 |
2021年 | 90篇 |
2020年 | 85篇 |
2019年 | 88篇 |
2018年 | 70篇 |
2017年 | 63篇 |
2016年 | 79篇 |
2015年 | 90篇 |
2014年 | 118篇 |
2013年 | 133篇 |
2012年 | 191篇 |
2011年 | 202篇 |
2010年 | 151篇 |
2009年 | 107篇 |
2008年 | 136篇 |
2007年 | 115篇 |
2006年 | 123篇 |
2005年 | 103篇 |
2004年 | 69篇 |
2003年 | 55篇 |
2002年 | 68篇 |
2001年 | 49篇 |
2000年 | 38篇 |
1999年 | 31篇 |
1998年 | 33篇 |
1997年 | 24篇 |
1996年 | 20篇 |
1995年 | 15篇 |
1994年 | 20篇 |
1993年 | 9篇 |
1992年 | 24篇 |
1991年 | 12篇 |
1990年 | 14篇 |
1989年 | 8篇 |
1988年 | 4篇 |
1987年 | 12篇 |
1986年 | 7篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1969年 | 2篇 |
1957年 | 2篇 |
1906年 | 1篇 |
排序方式: 共有2619条查询结果,搜索用时 15 毫秒
41.
We demonstrate the coherent beam combination of eight Watt-level polarization-maintained fiber amplifiers. The phase control signal of each amplifier is generated by running a stochastic parallel gradient descent algorithm on a digital signal processor (DSP). The experimental result shows that the whole system in close-loop performs well for long-time observation. Energy encircled in the target pinhole is 6.68 times more than that in open-loop. The combination efficiency is as high as 84.5%. 相似文献
42.
Gary Shambat Albert Deberardinis Petra Reinke Lin Pu John Bean 《Applied Surface Science》2009,255(20):8533-8538
Studies were performed to determine the chemical addition of a metal complex molecule, chlorotris(triphenylphosphine)iridium(I), on hydrogen passivated Si(1 1 1) surfaces to form a self-assembled monolayer (SAM). The iridium complex was synthesized prior to chemical addition, for which modified reaction conditions were chosen. Following addition, the silicon surfaces were characterized with X-ray photoelectron spectroscopy (XPS) and cyclic voltammetry (CV). The XPS results revealed that the surfaces consisted of the expected elemental percentages and that the iridium has a slightly higher success rate at attaching to oxide-free surfaces. XPS data also strongly indicate that the iridium complex remained intact upon chemisorption and did not decompose during the addition reaction. CV data show a difference between iridium treated surfaces and control samples. Hydrogen passivated wafers with iridium complex were much more conductive than those which were terminated with just an oxide or with an oxide and iridium complex. Furthermore, no free iridium reagent was detected as an additional feature in the current profile, indicating there was no physisorbed layer. 相似文献
43.
Guang-Feng Hong Zhen-Hua Dong Yong-Mei Xiao Pu Mao Ling-Bo Qu 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):771-779
AbstractA practical metal-free procedure for the synthesis of (E)-vinyl sulfones has been developed through the coupling of β-nitrostyrenes with sodium sulfinates under microwave irradiation. This methodology provides a convenient and efficient approach to various (E)-vinyl sulfones from readily available starting materials with excellent regioselectivity. The present oxidative reaction involves an efficient denitrative radical cross-coupling of β-nitrostyrenes with sodium sulfinates via using AcOH as an additive. 相似文献
44.
Yuqiao Wang Huijun Zhang Dan Yao Junjie Pu Yuan Zhang Xiaorui Gao Yueming Sun 《Journal of Solid State Electrochemistry》2013,17(3):881-887
Graphene/Fe3O4 nanocomposite was prepared for the immobilization of hemoglobin (Hb) to improve the electron transfer between Hb and glass carbon electrode (GCE). The characterization of nanocomposites was described by transmission electron microscopy, Fourier transform infrared, Raman spectroscopy, and X-ray photoelectron spectroscopy, respectively. The electrochemistry of Hb on the graphene/Fe3O4-based GCE was investigated by cyclic voltammetry and amperometric measurement. The modified electrode showed a wide linear range from 0.25 μmol/L to 1.7 mmol/L with a correlation coefficient of 0.9967. The detection limit of the H2O2 biosensor was estimated at 6.0?×?10?6?mol/L at a signal-to-noise ratio of 3. 相似文献
45.
P. Pu H. Cachet E. Ngaboyamahina E. M. M. Sutter 《Journal of Solid State Electrochemistry》2013,17(3):817-828
Two types of TiO2 nanotubular arrays were obtained by anodisation of a titanium foil, in two different solutions containing fluoride ions. For the first type which has rough tube walls, impedance measurements in the dark showed the presence of a localised surface state which was related to adsorbed molecular water. Under UV illumination, this adsorbed molecular water was photo-dissociated. Moreover, an increase of 2 orders of magnitude for the limiting capacitance of the space charge layer was observed, simultaneously with the disappearance of the localised state and with a 100-time increase of the carrier density associated with hydrogen insertion. The second type of layer was characterised by smoother tube walls, a high doping level (1020?cm?3) in the dark, a lack of localised states and no long-lasting photo-induced effect. In this case, the width of the space charge layer became rapidly higher than the half-thickness of the tube walls, when the applied potential increased. Therefore, the walls were progressively depleted under anodic polarisation, passing from a situation where the tubes were totally active in the cathodic range towards a situation where the contribution of the tube walls could be neglected. 相似文献
46.
Xinjian Yang Zhen Liu Zhenhua Li Fang Pu Prof. Dr. Jinsong Ren Prof. Dr. Xiaogang Qu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(31):10388-10394
Hydrophobicity has been an obstacle that hinders the use of many anticancer drugs. A critical challenge for cancer therapy concerns the limited availability of effective biocompatible delivery systems for most hydrophobic therapeutic anticancer drugs. In this study, we have developed a targeted near‐infrared (NIR)‐regulated hydrophobic drug‐delivery platform based on gold nanorods incorporated within a mesoporous silica framework (AuMPs). Upon application of NIR light, the photothermal effect of the gold nanorods leads to a rapid rise in the local temperature, thus resulting in the release of the entrapped drug molecules. By integrating chemotherapy and photothermotherapy into one system, we have studied the therapeutic effects of camptothecin‐loaded AuMP‐polyethylene glycol‐folic acid nanocarrier. Results revealed a synergistic effect in vitro and in vivo, which would make it possible to enhance the therapeutic effect of hydrophobic drugs and decrease drug side effects. Studies have shown the feasibility of using this nanocarrier as a targeted and noninvasive remote‐controlled hydrophobic drug‐delivery system with high spatial/temperal resolution. Owing to these advantages, we envision that this NIR‐controlled, targeted drug‐delivery method would promote the development of high‐performance hydrophobic anticancer drug‐delivery system in future clinical applications. 相似文献
47.
通过熔融共混法制备了一系列等比例聚左旋乳酸(PLLA)/聚右旋乳酸(PDLA)共混试样,采用差示扫描量热法(DSC)、核磁共振(13C-NMR)及广角X射线衍射(WAXD)等方法对共混产物进行了表征和研究分析.结果表明,等比例PLLA和PDLA熔融共混生成了立构复合物(stereocomplex,sc),同时部分均聚物发生酯交换反应,生成了立体嵌段物(stereoblock,sb),从而在DSC升温曲线上sc晶体处出现特殊的熔融双峰现象;随着熔融共混温度升高,sc晶体的生成率和结晶度逐渐下降;聚乳酸立构复合物的加工稳定性较好,二次加工后,sc晶体熔点基本不变,生成率和结晶度提高;由于sc晶体的存在,PLLA/PDLA共混物的耐热性能提高,退火热处理后耐热性能得到进一步提高.这对于开发高耐热聚乳酸及其加工应用具有重要的应用价值. 相似文献
48.
In this paper, we derive the asymptotic expansions of the moments of normalized partial maxima for general error distribution. A byproduct is to deduce the convergence rates of the moments of normalized maxima to the moments of the corresponding extreme value distribution. 相似文献
49.
50.
Dongliang Tang Changtao Wang Zeyu Zhao Yanqin Wang Mingbo Pu Xiong Li Ping Gao Xiangang Luo 《Laser \u0026amp; Photonics Reviews》2015,9(6):713-719
Conventional optics is diffraction limited due to the cutoff of spatial frequency components, and evanescent waves allow subdiffraction optics at the cost of complex near‐field manipulation. Recently, optical superoscillatory phenomena were employed to realize superresolution lenses in the far field, but suffering from very narrow working wavelength band due to the fragility of the superoscillatory light field. Here, an ultrabroadband superoscillatory lens (UBSOL) is proposed and realized by utilizing the metasurface‐assisted law of refraction and reflection in arrayed nanorectangular apertures with variant orientations. The ultrabroadband feature mainly arises from the nearly dispersionless phase profile of transmitted light through the UBSOL for opposite circulation polarization with respect to the incident light. It is demonstrated in experiments that subdiffraction light focusing behavior holds well with nearly unchanged focal patterns for wavelengths spanning across visible and near‐infrared light. This method is believed to find promising applications in superresolution microscopes or telescopes, high‐density optical data storage, etc.