Preparation and characterization of waterborne poly(urethane urea) with well‐defined hard segments

A series of polyester‐based poly(urethane urea) (PUU) aqueous dispersions with well‐defined hard segments were prepared from polyester polyol, 4,4′‐diphenylmethane diisocyanate, dimethylolpropionic acid, 1,4‐butanediol, isophorone diisocyanate, and ethylenediamine. These anionic‐type aqueous dispersions had good dispersity in water and were stable at the ambient temperature for more than 1 year. For these aqueous dispersions, the particle size decreased as the hard‐segment content increased, and the polydispersity index was very narrow (<1.10). Films prepared with the PUU aqueous dispersions exhibited excellent waterproof performance: the amount of water absorption was as low as 5.0 wt %, and the contact angle of water on the surface of this kind of film was as high as 103° (this led to a hydrophobic surface). The water‐resistant property of these waterborne PUU films could be well correlated with some crystallites and ordered structures of the well‐defined hard segments formed by hydrogen bonding between the urethane/urethane groups and urethane/ester groups, as well as the degree of microphase separation between the hard and soft segments in the PUU systems. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 2606–2614, 2005     

PbTe(001)表面原子几何结构和电子结构的第一性原理计算

用第一性原理的密度泛函理论计算了PbTe（001）表面的几何结构和电子结构.计算结果表明：PbTe（001）表面不发生重构，但表面几层原子表现出明显的振荡弛豫现象，其中第一、第二层间距减小4.5%，第二、第三层间距增加2.0%，并且表面层原子出现褶皱.表面带隙在X 点，带隙变宽，在基本带隙中不引入新的表面态，而导带底和价带顶附近等多处出现新的表 面共振态；弛豫后费米面处态密度很低，所以表面结构很稳定. 关键词： 密度泛函理论 表面几何结构 表面电子结构 PbTe     

非线性Schroedinger方程组的精确解组

运用Maple语言程序，在没有假设的条件下，得到了具有耦合特性的非线性Schrfidinger方程组的行波精确解组及其约束条件方程，它们的表达式涵盖了所有的耦合解组与非耦合解组，具有任意性。耦合解组的算例函数及其特性分析，解释了α螺旋蛋白质螺旋链运动模型的行波孤立子解的耦合效应，揭示了增加、稳定和控制蛋白质活性和功能的方向。文章的研究方法，为求解耦合的非线性微分方程组的行波精确解组探索了蹊径。     

具有时滞的不确定离散时间系统时滞相关鲁棒镇定(英文)

基于状态观测器的设计,研究了不确定多时滞离散系统的鲁棒镇定问题,基于比较原理和不等式方法,给出了一个时滞相关鲁棒镇定条件。     

飞秒激光作用下全向高反膜破坏的激发过程

设计和制备了全向高反膜SiO₂/TiO₂，研究了它在不同脉冲宽度、不同脉冲能量的飞秒激光作用下的破坏阈值和烧蚀深度.利用发展的抽运-探针方法，研究了抽运脉冲作用下材料中导带电子的超快激发和能量沉积过程，建立并求解了飞秒激光激发材料和材料的激发对抽运光自身反作用的耦合动力学模型.模型较好地揭示了材料破坏的激发过程. 关键词： 飞秒激光 全向高反膜 激发过程 破坏机制     

Electromechanical coupled nonlinear dynamics for microbeams

In this paper, an electromechanical coupled nonlinear dynamic equation of a microbeam under an electrostatic force is presented. Using the nonlinear dynamic equations and perturbation method, we investigated nonlinear free vibrations, forced responses far from and near to natural frequency, respectively. Nonlinear natural frequencies and vibrating amplitudes of the electromechanical coupled microbeam are dependent on the mechanical and electric parameters. Compared with linear forced responses, the obvious shift of the mean dynamic response occurs. Under certain condition, the jump phenomenon will occur. The studies can be used to design parameters of the microbeam and remove undesirable dynamic behavior such as jump phenomenon, etc.     

参数优化的最优性及在控制问题中的一个应用

在Banach空间中,给出了含参数的单值映射的不变类凸,拟不变类凸和伪不变类凸的概念.在这类较弱凸性条件下,提出了参数优化问题弱有效解的几个最优性充分条件.作为应用,研究了一类状态约束最优控制问题的弱最优控制.     

Improved adaptive-threshold burst assembly in optical burst switching networks

An improved adaptive-threshold burst assembly algorithm is proposed to alleviate the limitation of conventional assembly schemes on data loss and delay. The algorithm will adjust the values of assembly factors according to variant traffic regions. And the simulation results show that, by using the adaptive-factor adaptive assembly scheme, the performance of networks is extensively enhanced in terms of burst loss probability and average queuing delay.     

一种维修性神经网络模型

运用神经网络的ＢＰ算法建立了系统的维修性模型，结合一实例验证了模型，效果较好。     

8字形主被动锁模掺Er3+光纤激光器

在理论上分析了利用非线性光学环形镜作为等效可饱和吸收体压缩脉冲进行锁模的物理机制。利用8字形主被动混合锁模的结构在调制频率2．498749GHz下，在1．543μm处获得了12ps的锁模脉冲输出，对应谱宽0．22nm，时间脉宽积0．33。在抽运功率50mW情况下，输出脉冲平均功率3．715mW。在调制频率2．499344GHz、2．499114GHz和2．498999GHz时分别并获得了2～4阶幅度较为均衡的有理数谐波锁模脉冲序列。