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61.
Tarushi A Totta X Raptopoulou CP Psycharis V Psomas G Kessissoglou DP 《Dalton transactions (Cambridge, England : 2003)》2012,41(23):7082-7091
The interaction of Zn(II) with the non-steroidal anti-inflammatory drug tolfenamic acid leads to the formation of the structurally characterized trinuclear [Zn(3)(tolfenamato)(6)(CH(3)OH)(2)] complex. In the presence of the N,N'-donor heterocyclic ligands 1,10-phenanthroline and 2,2'-bipyridine at a range of ratios, the mononuclear Zn complexes of the general formulae [Zn(tolfenamato)(N,N'-donor)Cl] and [Zn(tolfenamato)(2)(N,N'-donor)] have been isolated and structurally characterized by X-ray crystallography. The deprotonated tolfenamato ligands are coordinated to the Zn(II) ion through carboxylato oxygen atoms. Tolfenamic acid and its complexes exhibit good binding propensity to human or bovine serum albumin protein having relatively high binding constant values. 相似文献
62.
Vassilis G. Papanicolaou Effie G. Papageorgiou Dimitris C. Lepipas 《Methodology and Computing in Applied Probability》2012,14(2):285-297
Consider a stochastic process that lives on n-semiaxes joined at the origin. On each ray it behaves as one dimensional Brownian Motion and at the origin it chooses a ray
uniformly at random (Kirchhoff condition). The principal results are the computation of the exit probabilities and certain
other probabilistic quantities regarding exit and occupation times. 相似文献
63.
64.
65.
Ati Sharma Vassilis Theofilis Tim Colonius 《Theoretical and Computational Fluid Dynamics》2017,31(5-6):471-474
This special issue is the second on the topic of “Global Flow Instability and Control,” following the first in 2011. As with the previous special issue, the participants of the last two symposia on Global Flow Instability and Control, held in Crete, Greece, were invited to submit publications. These papers were peer reviewed according to the standards of the journal, and this issue represents a snapshot of the progress since 2011. In this preface, a sampling of important developments in the field since the first issue is discussed. A synopsis of the papers in this issue is given in that context. 相似文献
66.
This paper describes a combined fracture–plastic model for concrete. Tension is handled by a fracture model, based on the classical orthotropic smeared crack formulation and the crack band approach. It employs the Rankine failure criterion, exponential softening, and it can be used as a rotated or a fixed crack model. The plasticity model for concrete in compression is based on the Menétrey–Willam failure surface, the plastic volumetric strain as a hardening/softening parameter and a non-associated flow rule based on a nonlinear plastic potential function. Both models use a return-mapping algorithm for the integration of constitutive equations. Special attention is given to the development of an algorithm for the combination of the two models. The suggested combination algorithm is based on a recursive substitution, and it allows for the two models to be developed and formulated separately. The algorithm can handle cases when failure surfaces of both models are active, but also when physical changes such as crack closure occur. The model can be used to simulate concrete cracking, crushing under high confinement and crack closure due to crushing in other material directions. The model is integrated in a general finite element package ATENA and its performance is evaluated by comparisons with various experimental results from the literature. 相似文献
67.
Panagiotis Loginos Anastasios Patsidis Katerina Vrettos George Sotiriadis Georgios C. Psarras Vassilis Kostopoulos Vasilios Georgakilas 《Molecules (Basel, Switzerland)》2022,27(20)
In this work, UV-curable resin poly (ethylene glycol) diacrylate (PEGDA) was reinforced with three different types of nanofillers: pristine graphene (G), multiwalled carbon nanotubes (MWNTs), and a hybrid of MWNTs and graphene 70/30 in mass ratio (Hyb). PEGDA was mixed homogenously with the nanofiller oligomer by shear mixing and then photopolymerized, affording thin, stable films. The thermomechanical properties of the afforded nanocomposites indicated the superior reinforcing ability of pristine graphene compared with MWNTs and an intermediate behavior of the hybrid. 相似文献
68.
E. Devlin V. Psycharis A. Kostikas A. Simopoulos D. Niarchos A/ Jankowski T. Tsakalakos Hong Wan G. Hadjipanayis 《Journal of magnetism and magnetic materials》1993,120(1-3):236-238
A series of Fe/Pt multilayers prepared by magnetron sputtering have been studied by XRD, conversion electron Mössbauer spectroscopy (CEMS) and SQUID magnetometry. The samples with individual Fe thickness of 3 Å show orientation of the magnetic moment close to perpendicular to the film plane and Curie temperatures near 350 K. Interdiffusion at the interface is manifested in a distribution of hyperfine fields. 相似文献
69.
Vassilis G. Keramidas Bernardo A. Deangelis William B. White 《Journal of solid state chemistry》1975,15(3):233-245
Infrared and Raman spectra are reported for compounds with 1 : 1, 1 : 3, and 1 : 2 mixed ordering on the octahedral sites of the spinel structure. The spectra of the superstructures are complex with many more bands observed than occur in the parent spinel structure, although less than were predicted by group theoretical analysis. A qualitative interpretation of the spectra can be made through the large Brillouin zone concept. 相似文献
70.
Liang ZX Tsigos I Bouriotis V Klinman JP 《Journal of the American Chemical Society》2004,126(31):9500-9501
The hydride transfer catalyzed by thermophilic alcohol dehydrogenase (htADH) exhibits sharply different kinetic and activation parameters from that catalyzed by the more flexible psychrophilic alcohol dehydrogenase (psADH). In addition, the hydride transfer in htADH is affected by mutating two distal residues that are suggested to be responsible for the decreased local protein flexibility in htADH. These observations provide support for the view that protein dynamics is tightly coupled to the hydrogen-transfer processes in these enzymes. 相似文献