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21.
A new kind of chiral dienophiles, cyclic vinyl-p-tolylsulfilimines (2a and 2b), were obtained from the corresponding (Z)-sulfinylacrylonitriles with HBF(4) and methanol. The asymmetric Diels-Alder reaction of optically pure 2a with cyclopentadiene under mild thermal or catalyzed conditions afforded only the endo-4a adduct with complete endo and pi-facial selectivities. The ability of the sulfilimine moiety to enhance the dienophilic reactivity of the double bond is similar to that of the sulfinyl group.  相似文献   
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Experimental investigations of lyotropic cholesterics fluids are presented which show that changes in the shape anisotropy and chirality of the micellar population determine the topology of the temperature-concentration phase diagrams. For given amounts of the substances which induce the chirality and modify the shape anisotropy of the micelles, two distinct biaxial cholesteric phases are disclosed in the phase diagrams. This is interpreted in the framework of the catastrophe theory of phase transitions.  相似文献   
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The synthesis of salicylic acid derivatives of 1,4,7,10-tetraazacyclododecane has been described. The complexing properties of these compounds towards metal cations were investigated by absorption and emission spectroscopy, and 1H NMR. The X-ray structure of L-2 nitrate is reported.  相似文献   
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This is the report of Heavy Ion Physics and Quark-Gluon Plasma at WHEPP-09 which was part of Working Group-4. Discussion and work on some aspects of quark-gluon plasma believed to have created in heavy-ion collisions and in early Universe are reported.  相似文献   
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S-factors for direct capture reactions can be found at astrophysical energies from asymptotic normalization coefficients which provide the normalization of the tail of the overlap function. For example the overlap for 8B → 7Be+p defines the S-factor for 7Be (p, γ)8B. Peripheral transfer reactions offer a technique to determine these asymptotic normalization coefficients. As a test of the technique, the 16O(3He, d)17F reaction has been used to determine asymptotic normalization coefficients for transitions to the ground and first excited states of 17F. The S-factors for 16O(p, γ)17F calculated from these 17F → 16O+p asymptotic normalization coefficients are found to be in very good agreement with recent measurements. Following the same technique, the 10B(7Be, 8B)9Be and 14N(7Be, 8B)13C reactions have been used to measure the asymptotic normalization coefficient for 7Be(p, γ)8B. This result provides an indirect determination of S 17(0).  相似文献   
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The collision-induced dissociation (CID) of deprotonated arylalkylamines of general formula R(1)C(6)H(4)CHR(2)CH(2)NR(3)(2) (where R(1) = H, OH, F or NO(2); R(2) = H or OH; R(3) = H or CH(3)) generated by negative chemical ionization with H(2)O and D(2)O as ionizing reagents, is discussed. The negative chemical ionization mass spectra show that, in the absence of a hydroxy group in the aromatic ring, deprotonation takes place at the benzylic position whereas the proton is lost from the OH group when present. The nitro compound forms only M(-.) ions. The CID spectra of the deprotonated molecules show that fragmentations are strongly dependent on the structural features of the molecules, namely the presence or absence of substituents in the aromatic ring or aliphatic chain. Copyright 1999 John Wiley & Sons, Ltd.  相似文献   
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