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101.
Organic emitting compounds that are based on π‐conjugated skeletons have emerged as promising next‐generation materials for application in optoelectronic devices. In this Minireview, recent advances in the development of organic emitters that irradiate room‐temperature phosphorescence and/or thermally activated delayed fluorescence with extraordinary luminescence properties, such as aggregation‐induced emission, mechanochromic luminescence, and circularly polarized luminescence, are discussed. 相似文献
102.
Grzegorz Leniec Tomasz Skibiński Slawomir M. Kaczmarek Przemyslaw Iwanowski Marek Berkowski 《Central European Journal of Physics》2012,10(2):500-505
Growth conditions and electron paramagnetic resonance investigations of two well oriented KSm(WO4)2 and KEr(WO4)2 single crystals have been presented and discussed. Hyperfine structure of Sm3+ ion was detected and analyzed for angular and temperature dependences. EPR spectra of KEr(WO4)2 and its angular dependence showed the presence of 5 magnetically nonequivalent Er centers in the crystal. A change in the
type of magnetic interactions was analyzed using mixed (Gaussian and Lorentzian) fits of the EPR spectra. 相似文献
103.
Paola Zimmermann Crocomo Dr. Masato Okazaki Takumi Hosono Prof. Dr. Satoshi Minakata Prof. Dr. Youhei Takeda Prof. Dr. Przemyslaw Data 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(43):e202200826
Previous work has reported the synthesis of donor–acceptor–donor molecules based on dibenzophenazine acceptor group, presenting thermally activated delayed fluorescent (TADF) properties and their application in the assembly of highly efficient electroluminescent devices. Herein, we focus on the characterisation of charge carrier species through UV-Vis-NIR spectroelectrochemical and potentiostatic EPR techniques, in addition to the investigation of electropolymerisation properties of some compounds depicted in this study. The promising electrochromic features of both small molecules and conjugated polymers led to the assembly and investigation of electrochromic devices, evidencing the materials’ versatility, applied in such different approaches as electrochromic windows and electroluminescent devices. Furthermore, the assembled OLEDs provided high efficiencies, with small roll-off, EQEs up to 20.5 % and luminance values up to 85 000 cd/m2. 相似文献
104.
Anna Kozinska Andrzej Zadlo Przemyslaw Labuz Agnieszka Broniec Pawel Pabisz Tadeusz Sarna 《Photochemistry and photobiology》2019,95(1):227-236
Photochemical properties of a new class of inorganic nanoparticles, namely a cationic C60 fullerene substituted with three quaternary pyrrolidinium groups (BB6) and a surface‐modified nanocrystalline TiO2 with bromopyrogallol red (Brp@TiO2) were examined for their effectiveness in photogenerating singlet oxygen and free radicals. In particular, their ability to photosensitize peroxidation of unsaturated lipids was analyzed in POPC:cholesterol liposomes and B16 mouse melanoma cells employing a range of spectroscopic and analytical methods. Because melanoma cells typically are pigmented, we examined the effect of melanin on the photosensitized peroxidation of lipids in liposomes and B16 melanoma cells, mediated by BB6 and Brp@TiO2 nanoparticles. The obtained results suggest that peroxidation of unsaturated lipids, photosensitized by BB6 occurs mainly, although not exclusively, via Type II mechanism involving singlet oxygen. On the other hand, if surface‐modified TiO2 is used as a photosensitizer, Type I mechanism of lipid peroxidation dominates, as indicated by the predominant formation of the free radical‐dependent cholesterol oxidation products. The protective effect of melanin was particularly evident when BB6 was used as a photosensitizer, suggesting that melanin could efficiently interfere with Type II processes. 相似文献
105.
The goal of this work has been to examine a possibility to measure a liquid level and its viscosity by the vibro-acoustic methods. Preliminary laboratory investigations were completed on a glass vessel filled with solutions of various viscosity and level, excited by a hammer. A microphone and four accelerometers were used as sensors. Few criteria symptoms were checked. For the level and viscosity estimation there were used the placement and values of the Fourier's spectra maximum of the acoustic signal, and of the vibration signals from sensors. (© 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
106.
107.
Simultaneous three-photon excited stimulated emission at (cavityless lasing) approximately 610 nm has been achieved in an organic chromophore solution pumped by approximately 1.5-microm ultrashort coherent radiation. The stimulated emission can be observed only in the forward and backward directions and is characterized by its high directionality and spectral narrowing. The divergence angle for the backward stimulated emission is considerably smaller than that for the forward stimulated emission, which resembles optical phase conjugation. 相似文献
108.
Przemyslaw Herman 《Meccanica》2009,44(1):61-70
A method for investigation of the dynamical couplings between the manipulator links is presented in this paper. The method
is based on quasi velocities introduced originally by Hurtado (2004) and on a diagonalized Poincaré form of the Hamel representation
described by Sovinsky et al. (2005). Some observations and a heuristic algorithm are proposed to determine the dynamical couplings
between the rigid manipulator links. The presented strategy can be used in the design phase of manipulators and it can be
realized via a simulation test. It is validated here on a 3 d.o.f. spatial manipulator. 相似文献
109.
Classical initiation induces polymerization through cyclic tertiary oxonium ions which are responsible for the formation of an important quantity of cyclic oligomers. The activated monomer mechanism, i.e. polymerization in the presence of a diol, has been successful in the case of some substituted oxiranes such as epichlorohydrine and propylene oxide. It has also been used in the case of cyclic acetals [1,3-dioxolane (DXL) and 1,3-dioxepane (DXP)] and allows the preparation of dihydroxylated homopolymers as well as that of triblock copolymers. It was nevertheless shown that transacetalization leads to complications at the onset of the reaction. In order to shed some light on the reactions involved, we used a monoalcohol - methanol - instead of a diol. The products were separated and characterized: a monoadduct (methanol-DXL) was observed, confirming the occurence of the active monomer mechanism, but dimethoxymethane was also observed, evidence of transacetalization between methanol and DXL. It was shown that fast equilibration takes place between the following compounds: (methanol + DXL), (monoadduct of methanol and DXL), (dimethoxymethane + ethyleneglycol). When p-isopropenylbenzyl alcohol was used, it was possible to prepare macromonomers, i.e. poly(DXL) chains carrying polymerizable double bonds at their ends. Nevertheless because of the transacetalization reaction described above, a mixture of products was obtained. 相似文献
110.
Tadeusz Biedron Ryszard Szymanski Przemyslaw Kubisa Stanislaw Penczek 《Macromolecular Symposia》1990,32(1):155-168
Polymerization of cyclic ethers by activated monomer mechanism involves consecutive additions of protonated monomer molecules to the growing macromolecules fitted with hydroxyl groups at their ends. For oxirane itself and symmetrically substituted oxiranes there is only one kind of hydroxyl groups and one, unique way of ring-opening. Unsymmetrically substituted oxiranes provide however two sites of attack and two different hydroxyls, resulting from these ring-openings. Kinetics of polymerization of epichlorohydrin (chloromethyloxirane) has been studied and all four rate constants determined, namely rate constants of the primary and secondary alcoholate chain ends with a protonated monomer, opening in result of the attack on substituted or unsubstituted carbon atom. These rate constants are (in mol−1·1·s−1 at 25°C, in CH2Cl2 solvent): k11 = 0.055, k12 = = 0.41, k22 = 0.135, and k21 = 0.0011 (e.g. k12 is the rate of reaction of the primary alcohol producing the secondary alcohol). Thus, polymerization proceeds almost exclusively on the secondary alcoholate groups, reproducing themselves (k22). 相似文献