全文获取类型
收费全文 | 9102篇 |
免费 | 290篇 |
国内免费 | 7篇 |
专业分类
化学 | 5438篇 |
晶体学 | 178篇 |
力学 | 194篇 |
数学 | 1740篇 |
物理学 | 1849篇 |
出版年
2023年 | 42篇 |
2022年 | 157篇 |
2021年 | 163篇 |
2020年 | 149篇 |
2019年 | 179篇 |
2018年 | 203篇 |
2017年 | 224篇 |
2016年 | 439篇 |
2015年 | 340篇 |
2014年 | 417篇 |
2013年 | 781篇 |
2012年 | 499篇 |
2011年 | 538篇 |
2010年 | 401篇 |
2009年 | 339篇 |
2008年 | 536篇 |
2007年 | 452篇 |
2006年 | 412篇 |
2005年 | 337篇 |
2004年 | 286篇 |
2003年 | 220篇 |
2002年 | 170篇 |
2001年 | 130篇 |
2000年 | 127篇 |
1999年 | 78篇 |
1998年 | 88篇 |
1997年 | 74篇 |
1996年 | 72篇 |
1995年 | 68篇 |
1994年 | 48篇 |
1993年 | 37篇 |
1992年 | 46篇 |
1991年 | 73篇 |
1990年 | 51篇 |
1989年 | 62篇 |
1988年 | 57篇 |
1987年 | 58篇 |
1986年 | 60篇 |
1985年 | 123篇 |
1984年 | 124篇 |
1983年 | 72篇 |
1982年 | 67篇 |
1981年 | 80篇 |
1980年 | 74篇 |
1979年 | 70篇 |
1978年 | 50篇 |
1977年 | 44篇 |
1976年 | 44篇 |
1975年 | 45篇 |
1974年 | 37篇 |
排序方式: 共有9399条查询结果,搜索用时 10 毫秒
881.
Agata Krakowska Witold Reczyński Włodzimierz Opoka Waldemar Turski 《International journal of environmental analytical chemistry》2015,95(9):855-866
Honey is a sweet product made by bees using nectar from flowers. Concentrations of Ca, K, Mg, Fe, Zn, Mn, Cu, Pb and Cd were determined in 13 honey samples from the selected regions around the world. Levels of Ca, Mg, Cu, Fe, Zn and Mn were measured using flame atomic absorption spectrometry (FAAS). Potassium concentration was determined via flame photometry. Concentrations of Cd and Pb were determined using the electrothermal technique (ETAAS). It was estimated that the examined samples of honey from Greece, Turkey, Spain, Poland, Mexico, Argentina and Italy were of good quality in terms of metal concentrations (compliant with the norms referring to food products – WHO, Fifty-third Report of the joint FAO/WHO Expert Committee on Food Additives; Technical Report Series 776, Geneva), although the analysed samples were not free of heavy metals. The concentrations of the elements in the honey samples ranged from 2.38 to 9.31 μg · g?1 for Zn, from 3.86 to 35.10 μg · g?1 for Fe, from 0.19 to 21.64 μg · g?1 for Mn, from 49.53 to 1006.90 μg · g?1 for Ca, from 388.25 to 4761.50 μg · g?1 for K and from 0.20 to 1.53 μg · g?1 for Cu and regarding heavy metals from 0.11 to 2.78 μg · g?1 for Pb and from 0.02 to 0.44 μg · g?1 for Cd. According to these results it was found that the concentrations of heavy metals in the honey samples (except for alfalfa honey and eucalyptus honey from Italy) were under the acceptable limits for foods set out by the FAO/WHO. It was confirmed that the application of chemometric tools supports the extraction of significant information from analytical data, even though the availability of samples is not fully sufficient (this problem is often encountered in environmental analyses). 相似文献
882.
Robert Szczęsny Tadeusz M. Muzioł Duncan H. Gregory Edward Szłyk 《Chemical Papers》2015,69(4):569-579
Four copper(II) oxime complexes, [Cu(HPPK)(PPK)X] (HPPK = phenyl-2-pyridylketoxime and X = CI? (I), CF3COO? (II), C3F7COO? (III), and [Cu(PPK)2]2 (IV)), were synthesized and characterized by elemental analysis, infrared spectroscopy (IR), and single-crystal X-ray diffraction (XRD). XRD analysis revealed that I–III contain copper(II) coordinated by four nitrogen atoms from two oxime molecules in the basal plane and one monodentate anion X in the apical position of a distorted square pyramid. Complex IV is dimeric and it is formed by two Cu(PPK)2 units. Bridges between these units are formed by the two oxygen atoms of the deprotonated oxime groups. Thermal stability of I–IV was investigated by thermogravimetric analysis (TGA) in air and in nitrogen atmosphere, respectively. Evolved gaseous decomposition products were characterized by IR. I–IV decompose via multistep processes. Fluorocarbons and CO2 were observed to be the most abundant gaseous species evolved. Preliminary ammonolysis experiments were performed to examine the possibility of using II and IV as precursors for the synthesis of copper nitride. Moreover, solutions of IV were spin-coated onto silicon substrates. Surface structure and morphology of the resulting films were studied by scanning electron microscopy (SEM) and atomic force microscopy (AFM) and layers with island-like distribution of material were observed. 相似文献
883.
Alina Sionkowska Sławomir Skrzyński Krzysztof Śmiechowski Agata Kołodziejczak 《先进技术聚合物》2017,28(1):4-9
This review reports recent advances in the versatile application of collagen. Collagen materials have attracted great attention because they exhibit properties required in cosmetic preparations, in the biomedical field, and in the tanning industry leading to leather production. Herein, the structure and application of collagen are discussed in general, and detailed examples are also drawn from scientific literature and practical work. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
884.
Rafał Ślusarz Justyna Samaszko-Fiertek Barbara Dmochowska Janusz Madaj 《Journal of carbohydrate chemistry》2017,36(1):45-58
Computational investigations were performed to examine the effects of the addition of 2-acetamido-2-deoxy-β-D-galactopyranosylamine or 1-amino-1-deoxy-D-glucitol connected to the C-terminus of vancomycin with different linkers. The purpose of this modification was to find more effective vancomycin derivatives by providing alternative interactions between vancomycin moiety and the peptidoglycan precursor. Each prepared vancomycin–peptidoglycan complex was optimized and submitted to the molecular dynamics study and analysis. The analysis of overall root mean square deviation, changes in position and interactions involving modified part of vancomycin as well as cluster analysis were carried out. One of the proposed vancomycin analogues seems to be efficient vancomycin substitute. 相似文献
885.
Synthesis of β-cyclodextrin-lysozyme conjugates and their physicochemical and biochemical properties
Tomasz Marek Goszczyński Maciej Gawłowski Beata Girek Konrad Kowalski Janusz Boratyński Tomasz Girek 《Journal of inclusion phenomena and macrocyclic chemistry》2017,87(3-4):341-348
Recently a great interest in the field of protein engineering and the design of innovative drug delivery systems employing specific ligands such as cyclodextrins is observed. The paper reports the solid state, thermal method for protein coupling with β-cyclodextrin and the physicochemical and biological properties of the obtained conjugates. The structure of the obtained conjugates was investigated via liquid chromatography-mass spectrometry, dynamic light scattering and circular dichroism analysis. The presented conjugates were biologically active and covalently bound β-cyclodextrin preserved the ability to form inclusion complexes with the model compound. This report demonstrates the great potential of cyclodextrin as a modifying unit that can be used to modulate the properties of therapeutic proteins, additionally giving such conjugates the possibility to transport many therapeutic substances in the form of inclusion complexes. In addition, the paper presents the potential of protein-cyclodextrin conjugates to construct innovative bioactive molecules for biological and medical applications. 相似文献
886.
This study describes the influence of melamine polyphosphate (MPP) flame retardant addition on layered structure of virgin sodium montmorillonite (MMT) in PA6/MMT system obtained in extrusion process. It was found that the extrusion of the PA6/MMT binary system in co‐rotating twin screw extruder gives intercalated clay nanocomposites, while during extrusion of ternary PA6/MMT/MPP composite, full exfoliation of clay was obtained in the system. Structure of the composites was proved utilizing wide angle X‐ray scattering and transmission electron microscopy techniques. Exfoliation of MMT in ternary PA6/MMT/MPP system was also confirmed by rheological studies (viscosity and creep measurements) which were carried out using rotational rheometer. Young's modulus of PA6/MMT/MPP was found to be ~25% greater comparing to PA6/MPP of the same filling level. Cone calorimetry experiments proved decrease of heat release rate peak of PA6/MMT/MPP by ~55% comparing to PA6/MPP with the same total filling level. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
887.
Tomasz Pospieszny Marta Pakiet Iwona Kowalczyk Bogumił Brycki 《Supramolecular chemistry》2017,29(2):81-93
New dimers have been obtained from propargyl ester of bile acids and α,α′-diazide-m-xylene by intermolecular 1,3-dipolar cycloaddition. These compounds have been used as ligands to form intermolecular hydrogen bonds with various aromatic acids. The structures of all products were confirmed by spectroscopic (1H NMR, 13C NMR and FT-IR) analysis, mass spectrometry (ESI, MALDI) and PM5 semiempirical methods. 相似文献
888.
Moxifloxacin is a representative of the fourth generation of fluoroquinolones. It possesses bacteriostatic activity against Gram-positive and Gram-negative bacteria. A simple and fast high performance liquid chromatography-ultraviolet detection (HPLC-UV) method was developed for moxifloxacin analysis. The separation was performed on C18 column. The mobile phase was a mixture of acetonitrile and 0.4% triethylamine solution. The regression curve was linear over the range 0.2–10.0?µg/mL. The validation parameters obey the European Medicine Agency limits. The in vivo study confirmed the practical application of the method. 相似文献
889.
This paper is concerned with estimates of important factorization constants that appear in Banach space theory. We prove upper bounds of the Hilbertian norm of projections on finite-dimensional spaces of interpolation spaces generated by certain abstract interpolation functors and show applications to Calderón–Lozanovskii spaces. We also prove estimates of the p-factorization norm and projection constants for finite-dimensional Banach lattices. We show as a consequence of our results that in a large class of n-dimensional Banach sequence lattices \(E_n\) the projection constants \(\lambda (E_n)\) satisfy \(\lim _{n\rightarrow \infty }\lambda (E_n)/\sqrt{n} = c\), where \(c=\sqrt{2/\pi }\) in the real case and \(c= \sqrt{\pi }/2\) in the complex case. Applications are given to vector-valued sequence spaces. 相似文献
890.
Agata Górska Karolina Szulc Ewa Ostrowska-Ligęza Joanna Bryś Magdalena Wirkowska-Wojdyła 《Journal of Thermal Analysis and Calorimetry》2017,128(1):177-183
Epoxy-based nanocomposites containing different concentrations (0–3%) of surface-modified graphene nanosheets (GNS) with 3-aminopropyltriethoxysilane were prepared and their thermal and mechanical properties including dynamic mechanical analysis, tensile strength, hardness, and abrasion tests were evaluated in order to have a database for thermo-mechanical properties of epoxy nanocomposites. The main aim of this study was to understand the optimum percentage of GNS which would perform the best reinforcing influence on mechanical and physical performance of an epoxy nanocomposite. The results explain how applying the analysis of variance (ANOVA) method as a useful tool in optimization of GNS concentration in preparation of high-performance epoxy-based nanocomposites. 相似文献