Multifarious injection chamber for molecular structure study (MICOSS) system: development and application for serial femtosecond crystallography at Pohang Accelerator Laboratory X‐ray Free‐Electron Laser

The multifarious injection chamber for molecular structure study (MICOSS) experimental system has been developed at the Pohang Accelerator Laboratory X‐ray Free‐Electron Laser for conducting serial femtosecond crystallography. This system comprises several instruments such as a dedicated sample chamber, sample injectors, sample environment diagnostic system and detector stage for convenient distance manipulation. Serial femtosecond crystallography experiments of lysozyme crystals have been conducted successfully. The diffraction peaks have reached to ～1.8 Å resolution at the photon energy of 9.785 keV.     

In situ deposition behavior of silica-based layers and its effect on thermal degradation of IN713 turbine blades during operation of a micro-gas turbine

This study examined the in situ deposition behavior of silica-based layers on IN713 turbine blades during the operation of a 13 kgf-class gas turbine at a rotation speed of 20,000/min as well as its effect on the degradation of the metallic substrate. Tetraethylorthosilicate (TEOS) was mixed with the fuel (liquid petroleum gas, LPG) and burned to generate silica-based coating precursors for deposition from the flame. Two deposition conditions were adopted. For condition 1 (C1), the silicon-to-carbon ratio in the mixed fuel was set at 0.1 mol% for the first 5 min and at zero mol% for the final 95 min in a 100-min operation. For condition 2 (C2), the ratio was set at 0.005 mol% during the entire 100 min operation. The total TEOS feed was the same under both conditions. C1 resulted in a rather uniform and thicker (5-10 μm on the pressure side) porous silica-based coating on the blade than C2. The in situ deposited layer of C1 was well preserved on the blade and protected the underlying metallic substrate from oxidation during the entire 100 min operation. The layer on the C2 blades was ∼5 μm thick at the region near to root, but was too thin in the other areas on the blade to be protective. The early build-up of a porous layer to an effective thickness on the blades produced a thermal barrier toward the substrate as well as a diffusion barrier toward the oxidizing elements during operation.     

Polarized Raman scattering and lattice eigenmodes of antiferromagnetic NdFeO3

The first‐ and second‐order Raman‐active phonons in the orthorhombic Pbnm NdFeO₃ single crystals were studied by means of polarized Raman scattering and lattice dynamics computations (LDC). The zone‐center phonons of A_g symmetry were distinguished from the B_1g eigenmodes by performing polarized Raman scattering experiments using two parallel polarization configurations, X′(ZZ)X′ and Z(X′X′)Z. With the help of LDC, we were able to assign most of the observed Raman‐active modes, including phonons of B_2g and B_3g symmetry. The LDC results indicated that among the 16 force constants employed, the one corresponding to the stretching vibration between the central Fe cation and the axial oxygen atom in a FeO₆ octahedron unit had the largest value. This suggests that the B‐site Fe cation is more tightly bound to the axial O1 ion than the other two equatorial O2 ions. It was further shown that at higher wavenumbers, the displacement of oxygen atoms contributed dominantly to the zone‐center vibrations. Copyright © 2008 John Wiley & Sons, Ltd.     

Observation of a new DsJ meson in B+-->D0D0K+ decays

We report the observation of a new DsJ meson produced in B+-->D0DsJ-->D0D0K+. This state has a mass of M=2708+/-9(-10)(+11) MeV/c2, a width Gamma=108+/-23(-31)(+36) MeV/c2 and a 1- spin-parity. The statistical significance of this observation is 8.4 sigma. The results are based on an analysis of 449 x 10(6) BB events collected at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e+e- collider.     

Direct comparison of self-excited instabilities in mesoscale multinozzle flames and conventional large-scale swirl-stabilized flames

The present experimental investigation demonstrates important trends and offers physical insights into self-excited combustion instabilities in mesoscale multinozzle flames composed of sixty small injectors. Here we focus on the response of a prototypical micromixer-type injector assembly, fabricated using an additive manufacturing technique, in comparison with the behavior of conventional large-scale swirl-stabilized flames. Our results highlight that the development of self-excited instabilities in unconventional mesoscale flames is fundamentally different from that in large-scale swirl flames, in terms of the onset of instabilities, nonlinear modal dynamics, and amplitude/frequency of limit cycle oscillations under the same operating conditions. These differences are attributable to the alteration in local flow/flame structures and the resulting flame-to-flame/flame-wall interaction mechanisms. An integrated analysis of large datasets reveals that the two interacting swirl-stabilized flames tend to couple strongly with a low-frequency L1 mode at about 220 Hz, whereas the sixty-injector small-scale flames are capable of triggering multiple higher-frequency instabilities at ～ 310, ～ 470, and ～ 600 Hz. That is, the use of the micromixer-type injector assembly in a lean-premixed system causes the occurrence of combustion instabilities to shift toward a higher equivalence ratio. However, due to the absence of a large recirculation zone near the primary reaction region, the combustion system equipped with the small-scale multinozzle injectors was found to suffer from lean blowoff phenomena at low equivalence ratio.     

Experimental investigation of combustion instabilities of a mesoscale multinozzle array in a lean-premixed combustor

Self-excited combustion instabilities in a mesoscale multinozzle array, also referred to as a micromixer-type injector, have been experimentally investigated in a lean-premixed tunable combustor operating with preheated methane and air. The injector assembly consists of sixty identical swirl injectors of 6.5 mm inner diameter, which are evenly distributed across the combustor dump plane. Their flow paths are divided into two groups – inner and outer stages – to form radially stratified reactant stoichiometry for the control of self-excited instabilities. OH PLIF measurements of stable flames reveal that the presence of radial staging has a remarkable influence on stabilization mechanisms, reactant jet penetration/merging, and interactions between adjacent flame fronts. In an inner enrichment case, two outer (leaner) streams merge into a single jet structure, whereas the inner (richer) reactant jets penetrate far downstream without noticeable interactions between neighboring flames. The constructed stability map in the 〈?_i, ?_o〉 domain indicates that strong self-excited instabilities occur under even split and outer enrichment conditions at relatively high global equivalence ratios. This is attributed to large-scale flame surface deformation in the streamwise direction, as manifested by vigorous detachment/attachment movements. The use of the inner fuel staging method was found, however, to limit the growth of large-amplitude heat release rate fluctuations, because the center flames are securely anchored during the whole period of oscillation, giving rise to a moderate lateral motion. We demonstrate that the collective motion of sixty flames – rather than the individual local flame dynamics – play a central role in the development of limit cycle oscillations. This suggests that the distribution pattern of the injector array, in combination with the radial fuel staging scheme, is the key to the control of the instabilities.     

Pore Structure Analysis of Porous Particles by Equivalent Model

Starting from Wheeler's composite theory, which takes both the multilayer adsorption and the capillary condensation into consideration, and assuming the equivalent cylindrical model, we have deduced a strict and relatively simpler formula for the calculation of pore size distribution by solving the integral equation directly. The formula is more convenient for application because of its recursion form. Following the same line of reasoning and using the mean value theorem of definite integrals under different conditions, we have unified the equations of Barrett-Joyner-Halenda, Dubinin, Cranston-Inkley, Dollimore-Heal and Roberts. A table of parameters which is required in the calculation is given. Besides the adsorption of nitrogen, the adsorption with water vapor as the adsorbate is investigated and the corresponding empirical equation of adsorption thickness is given.     

One-dimensional structures of Bi2O3 synthesized via metalorganic chemical vapor deposition process

We have demonstrated the synthesis of one-dimensional (1D) structures of bismuth oxide (Bi₂O₃) by a reaction of a trimethylbismuth (TMBi) and oxygen (O₂) mixture at 450 °C. Scanning electron microscopy showed that the product consisted of 1D materials with width or diameters less than 1 μm and lengths up to several tens of micrometers. The X-ray energy dispersive spectroscopy revealed that the materials contained elements of Bi and O. The results of X-ray diffraction and selected area electron diffraction pattern indicated that the obtained Bi₂O₃ were crystalline with monoclinic structure.     

Pulse-amplitude equalization using a polarization-maintaining laser resonator

For the first time to our knowledge, pulse-amplitude equalization of rational-harmonically mode-locked fiber ring laser pulses has been experimentally demonstrated using a polarization-maintaining laser resonator without any additional device. The pulse-amplitude distribution of the laser pulses was controlled by the modulator driving power, and stable pulse-amplitude-equalized pulses with repetition rates of 20, 30, and 40 GHz have been obtained in the linear region of the modulator.