全文获取类型
收费全文 | 56188篇 |
免费 | 18519篇 |
国内免费 | 2455篇 |
专业分类
化学 | 63925篇 |
晶体学 | 221篇 |
力学 | 2365篇 |
综合类 | 159篇 |
数学 | 2916篇 |
物理学 | 7576篇 |
出版年
2024年 | 452篇 |
2023年 | 4402篇 |
2022年 | 2006篇 |
2021年 | 3021篇 |
2020年 | 5256篇 |
2019年 | 2818篇 |
2018年 | 2878篇 |
2017年 | 1098篇 |
2016年 | 6211篇 |
2015年 | 6185篇 |
2014年 | 5812篇 |
2013年 | 6126篇 |
2012年 | 4559篇 |
2011年 | 2558篇 |
2010年 | 4337篇 |
2009年 | 4213篇 |
2008年 | 2134篇 |
2007年 | 1662篇 |
2006年 | 1131篇 |
2005年 | 910篇 |
2004年 | 718篇 |
2003年 | 604篇 |
2002年 | 580篇 |
2001年 | 492篇 |
2000年 | 405篇 |
1999年 | 470篇 |
1998年 | 327篇 |
1997年 | 340篇 |
1996年 | 386篇 |
1995年 | 393篇 |
1994年 | 339篇 |
1993年 | 385篇 |
1992年 | 255篇 |
1991年 | 212篇 |
1990年 | 172篇 |
1989年 | 157篇 |
1988年 | 183篇 |
1987年 | 126篇 |
1981年 | 102篇 |
1980年 | 110篇 |
1977年 | 162篇 |
1976年 | 181篇 |
1975年 | 185篇 |
1974年 | 194篇 |
1973年 | 110篇 |
1972年 | 153篇 |
1971年 | 122篇 |
1970年 | 207篇 |
1969年 | 125篇 |
1968年 | 133篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
41.
The central zinc(II) atom in the title complex is tetrahedrally coordinated by four nitrogen atoms derived from 4‐methyl‐5‐imidazolecarboxyaldehyde ligands with Zn? N in the range 2.007(3) to 2.026(4) Å. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
42.
Zheng Yu 《manuscripta mathematica》2003,111(2):163-186
In this paper, the negative gradient flow for the L
2-integral of Ricci curvature on a 3-manifold is considered. It is not known whether the solution to this fourth order geometric
evolution equation exists, and whether it will develop singularities in finite time. Based on the trick of De Turck and the
idea of Hamilton on the flow of Ricci curvature, the local existence on any compact Riemannian manifold is obtained. In addition,
the conditions for the occurences of singularities in finite time during the evolution and the asymptotic behavior of the
flow on a 3-manifold are discussed.
Received: 22 April 2002 / Revised version: 5 January 2003
Published online: 24 April 2003
This work is partially supported by the Foundations of NNSF of China, the Foundation for University Key Teacher by MEC and
Shanghai Priority Academic Discipline. 相似文献
43.
The field of medicinal inorganic chemistry is rapidly advancing. In particular organometallic complexes have much potential as therapeutic and diagnostic agents. The carbon‐bound and other ligands allow the thermodynamic and kinetic reactivity of the metal ion to be controlled and also provide a scaffold for functionalization. The establishment of structure–activity relationships and elucidation of the speciation of complexes under conditions relevant to drug testing and formulation are crucial for the further development of promising medicinal applications of organometallic complexes. Specific examples involving the design of ruthenium and osmium arene complexes as anticancer agents are discussed. 相似文献
44.
In this study, a genetically encoded bioluminescent indicator for ERK2 dimer was developed with the split Renilla luciferase complementation method, in which the formation of ERK2 dimer induces a spontaneous emission of bioluminescence in living cells. In response to extracellular stimuli, such as epidermal growth factor (EGF) or 17β‐estradiol (E2), extracellular signal‐regulated kinase 2 (ERK2) is phosphorylated by its upstream kinase MEK, and also phosphorylates its substrates in various regions of the cell, including the nucleus. Phosphorylated ERK2 is led to form its dimer, thereby transporting itself into the nucleus. We demonstrated with the indicator that stimulation with EGF or E2 induces the formation of ERK2 dimer in living MCF‐7 cells. The dynamics of this dimer formation was examined and discussed. 相似文献
45.
46.
Gallin Peter Prof. Dr. 《ZDM》2003,35(3):110-119
In order to emphasize functional thinking in mathematical education, arguments are brought forward for an early and frequent use of tree diagrams in teaching stochastics. Since set and tree diagrams can be regarded as two sides of the same matter, Bayes’ theorem, which is strongly associated with predicative set diagrams, need not be dealt with explicitly any longer. Set diagrams are replaced by tree diagrams that are labelled in detail and by tree inversion as a functional instrument of dealing with conditioned probabilities. This technique is demonstrated by three typical problems in the context of conditioned probability. Finally, two letters by Pascal to Fermat are analysed in order to illustrate that predicative and functional approaches were already pursued in the early stages of probability calculus in the 17th century. 相似文献
47.
Jin Sun Yihu Song Qiang Zheng Hong Tan Jie Yu Hong Li 《Journal of Polymer Science.Polymer Physics》2007,45(18):2594-2602
The reinforcement and nonlinear viscoelastic behavior have been investigated for silica (SiO2) filled solution‐polymerized styrene butadiene rubber (SSBR). Experimental results reveal that the nonlinear viscoelastic behavior of the filled rubber is similar to that of unfilled SSBR, which is inconsistent with the general concept that this characteristic comes from the breakdown and reformation of the filler network. It is interesting that the curves of either dynamic storage modulus (G′) or loss tangent (tan δ) versus strain amplitude (γ) for the filled rubber can be superposed, respectively, on those for the unfilled one, suggesting that the primary mechanism for the Payne effect is mainly involved in the nature of the entanglement network in rubbery matrix. It is believed there exists a cooperation between the breakdown and reformation of the filler network and the molecular disentanglement, resulting in enhancing the Payne effect and improving the mechanical hysteresis at high strain amplitudes. Moreover, the vertical and the horizontal shift factors for constructing the master curves could be well understood on the basis of the reinforcement factor f(φ) and the strain amplification factor A(φ), respectively. The surface modification of SiO2 causes a decrease in f(φ), which is ascribed to weakeness of the filler–filler interaction and improvement of the filler dispersion. However, the surface nature of SiO2 hardly affects A(φ). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2594‐2602, 2007 相似文献
48.
Da-Zhi Li Li Gan Zi-Qiang Yang Zheng Liang Jia-Yin Li 《International Journal of Infrared and Millimeter Waves》1997,18(10):1885-1896
The dispersion characteristic of the plasma-loaded relativistic backward wave oscillator has been analyzed. The theoretical
model has been established and the numerical calculations accord with the experimental results, which provides some useful
suggestions on the designing of slow-wave structure of BWO. 相似文献
49.
Polyphenylsilsesquioxane (PPSQ) was incorporated into an epoxy resin to prepare organic–inorganic composites, and two strategies were adopted to afford composites with different morphologies. Phase separation induced by polymerization occurred in the physical blending system. However, nanostructured composites were obtained when a catalytic amount of aluminum triacetylacetonate was added to mediate the reaction between PPSQ and diglycidyl ether of bisphenol A (DGEBA). The intercomponent reaction significantly suppressed the phase separation on the micrometer scale. Organic–inorganic composites with different morphologies displayed quite different thermomechanical properties. Both differential scanning calorimetry and dynamic mechanical analysis showed that the nanostructured composites possessed higher glass‐transition temperatures than the phase‐separated composites with the same loading of PPSQ, although the intercomponent reaction between PPSQ and DGEBA reduced the crosslinking density of the epoxy matrix. This result was ascribed to the presence of nanosized PPSQ domains in the nanostructured composites, which acted as physical crosslinking sites and thus reinforced the epoxy networks. The nanoreinforcement of the PPSQ domains afforded the enhanced dynamic storage modulus for the nanostructured composites in comparison with the phase‐separated composites with a PPSQ concentration less than 15 wt %. In terms of thermogravimetric analysis, the organic–inorganic composites displayed improved thermal stability and flame retardancy. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1093–1105, 2006 相似文献
50.
Wen-Chen Zheng 《Physica B: Condensed Matter》1993,190(4):413-416
The zero-field splittings of sites I and II for Mn2+ in guanidinium aluminum sulfate hexahydrate (GASH) are calculated from the superposition model by using the normal intrinsic parameter
2(R0) obtained from Mn2+ ions in many oxygen octahedra. The results are in good agreement with the experimental findings. Based on this, the local compressibilities and local thermal expansion coefficients in the vicinity of the impurity ion Mn2+ have been studied from the stress and temperature dependence of zero-field splitting and are found to be half of the host ones. The reasonableness of these local values is discussed. 相似文献