Large deviation estimates for a conditional probability distribution. Applications to random interaction Gibbs measures

Summary Let (X _i ,Y _i ) ^d , be independent identically distributed random variables with arbitrary distribution. We show that, for almost every(Y _i ) _i , the conditional law of the empirical field given(Y _i ) _i satisfies to large deviation inequalities. This applies to the study of Gibbs measures with random interaction, in the case of some mean-field models as well as of short range summable interaction. We show that the pressure is nonrandom, and is given by a variational formula. These random Gibbs measures have the same large deviation rate, which does not depend on the particular realization of the interaction; their local behaviour is described in terms of conditional probabilities given the interaction of solutions to the variational formula.     

On the dynamics of cosmological particle production

The time evolution of the particle number density and spectrum of massive scalar particles, coupled conformally to a classical Friedman-Robertson-Walker gravitational field is followed numerically. Not only for a pure radiation cosmos, but also for one with an inflationary interlude, the density of particles produced remains constant in time. This results in a constant equivalent temperature scale up to the Compton time of the massive particles, and opens the possibility that during a sufficiently long inflation the energy density of the particles produced can exceed that of the radiation background.     

Crystal structure oftrans-[PtCl2(Me2PhP)(cis-2,5-dimethylpyrrolidine)]

The complextrans-[PtCl₂ (Me₂PhP)(cis-2,4-dimethylpyrrolidine)] has been characterized by X-ray crystallography. It crystallizes in the monoclinic space group P 2₂/c witha=8.762(3),b=16.034(5),c=12.600(4)Å,=93.43(3)° andZ=4. The structure was solved by heavy atom method and refined toR=0.052 for 3251 observed counter reflections. The coordination sphere of the Pt atom is square-planar with a geometry very similar to that of the studied complexes of the type trans-[PtCl₂(R₃P)L] whereL is either one of the possible isomers of theC,C-dimethylpyrrolidine or the unsubstituted pyrrolidine. In the present complex the puckered five-membered ring of the dimethylpyrrolidine ligand assumes an envelope conformation with the maximum puckering at the N atom.     

Variation of the instability index on stationary curves of elliptic equations depending on a parameter

The set of solutions of the equation A(u, )=0 in the case of general position consists of smooth curves. Solutions of a quasilinear elliptic equation with large instability index are constructed and an estimate obtained for the number of turning points of the solution curves.Translated from Trudy Seminara imeni I. G. Petrovskogo, No. 12, pp. 47–58, 1987.     

Index formulas for generalized Wiener-Hopf operators and boson-fermion correspondence in 2N dimensions

The kernels of operators associated with special chiral gauge transformations (kinks) in the 2N-dimensional Dirac theory are explicitly determined. The result is used to obtain index formulas for Fredholm operators corresponding to continuous chiral gauge transformations. Moreover, the Fock space quadratic forms corresponding to the kinks are proved to converge to the Dirac field as the kink size goes to zero. It is also shown that forN 1, 2(mod 4) the Majorana field can be reached in a similar fashion.Work supported by the Netherlands Organisation for the Advancement of Research (NWO)     

Disorder arising from the location of enantiomers in a twist-boat structure: 2,6-trans-2,4,6-tris(trichloromethyl)-1-oxa-3,5-dithian

Crystals of the title compound are orthorhombic, Pca2₁;a=27.586(4),b=10.509(3),c=11.080(2) Å,V=3212(1) ų,Z=8. The structure was solved by direct methods, from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer, and refined by full-matrix least squares to a finalR value of 0.055 using 2043 reflections. One of the two independent molecules in the asymmetric unit is disordered. The disorder is manifested mainly between the oxygen atom and one sulfur atom and is caused by opposite enantiomers occupying corresponding positions in different unit cells. The endocyclic torsion angles in both independent molecules are very similar but the disposition of the heteroatoms on the twist-boat framework is different in the two molecules. Site occupancy of the two models on this framework in the disordered molecule is in the ratio 2179 with the smaller proportion being very similar to the ordered molecule and the remainder similar to that found in the normal molecule oftrans-4-chloro-2,4,6-tris(trichloromethyl)-1-oxa-3,5-dithian (Irving and Irving, 1988).     

Effect of the flow regime in an underexpanded jet issuing into a subsonic counterstream on the pressure distribution on a body

The pressure distribution on a cone with a half-angle =75°, from which a single central underexpanded jet issues into a subsonic counterstream, has been experimentally investigated. The effect of the flow regime in the jet on the pressure distribution is demonstrated. Generalized relations for the pressure on the body are obtained for various jet-flow momentum ratios J and flow Mach numbers M = 0.35–0.9; the Mach number M_a at the exit of the conical nozzle with half-angle _a=10° was equal to 2.9. The working medium of the jet and the flow was air with stagnation temperatures T_0a = T₀ 260–265°K. The ratio of the nozzle outlet radius to the radius of the maximum cross section of the cone _a/R_M=0.1.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 182–185, January-February, 1988.     

On 2-spannedness for the adjunction mapping

LetL be a line bundle on a smooth connected projective manifold X of dimension n. We extend to any dimension the definition of k-spannedness forL; this is a notion of k-th order embedding which was recently given in the case of curves and surfaces. Then, by a reduction to the surfaces case, we prove that the adjoint bundle K_x+(n–1)L is 2-spanned ifL is (at least) 3-spanned.     

Intra- versus intermolecular hydrogen bonds in salicylamide derivatives

The crystal structures, solid-state infrared patterns, and thermal properties of two polymorphs of 4-nitrosalicylanilide are presented. In both polymorphs, intramolecular hydrogen bonds are found between the phenol oxygen and the amide proton, and intermolecular hydrogen bonds are found between the amide carbonyl oxygen and the phenol proton. These hydrogen bond patterns are compared to those found in other known salicylamide derivatives and an analysis is given of the factors contributing to preferences for intra- or intermolecular hydrogen bonds in these structures. Crystal data: polymorph, orthorhombic,Pbca,a=11.003(4),b=27.959(7),c=7.622(5) Å,Z=4,V=2345(3) ų, andR=0.038 (1351 reflections); polymorph, monoclinic,P2₁/a,a=28.36(1),b=11.64(1),c=7.293(8) Å,=90.68(6)°,Z=8,V=2408 ų, andR=0.043 (2425 reflections).     

Forces of a fluid in a rotating straight pipe

The fluid flow through a rotating straight pipe is considered, the axis of rotation being perpendicular to the pipe axis. The flow of the fluid is taken as fully developed, i.e. the velocity field is assumed to be the same in all transverse cross sections of the pipe. The derivation presented applies to viscous and nonviscous incompressible fluids. For constant angular pipe velocity a simple and exact (Coriolis type) relationF=2Q(t) is derived between the forceF by which the fluid acts on the (unit length of the) pipe in the direction perpendicular to the two axes, the fluid mass flow rateQ(t) through the pipe, and the angular velocity. Variable angular velocities, i.e. , introduce an additional term into the expression for the inertial forceF, which depends only on and on known (constant) parameters; this term is known for given angular velocity(t). The flow configuration investigated here is an idealization of those appearing (over short space and time intervals) in the devices measuring mass flow rateQ(t) through the (Coriolis) forceF. Therefore the exact results derived here cast some light on the degree of precision one expects in these devices, where more complicated flow configurations are present than those looked at in this paper.