PH, PD和PT分子常数理论研究

采用内收缩多参考组态相互作用(MRCI)方法和包含Davidson修正(+Q) 的MRCI方法结合相关一致基aug-cc-pV5Z研究了PH (X³Σ^-, a¹Δ和A³∏)分子的势能曲线. 在同位素质量识别的基础上对势能曲线进行拟合, 得到PH, PD和PT分子各个电子态的光谱常数(T_e, R_e, ω_e, ω_ex_e, α_e和 B_e). 通过与已有实验数据的比较发现, 本文的结果与实验结果非常一致. 对于PH, PD和PT分子的Σ^-电子态, 计算得到了J = 0时的前12个振动态. 对于每一个振动态, 还分别计算了它的振动能级、惯性转动常数和离心畸变常数. 与其他理论结果和实验数据进行比较可知, 本文的结果更精确、更完整. 文中PD和PT分子的光谱常数和分子常数均属首次报导.     

电场中Eu原子电离阈移动的实验研究

提出了一种新方法, 精确确定了稀土Eu原子第一电离阈的位置. 先用脉冲电场对Eu原子的高激发Rydberg态进行延时场电离探测, 再通过反向静电场排除光电离和自电离等其他路径所产生的离子信号的干扰, 观察并研究了Eu原子第一电离阈随着电场移动的规律. 由此所确定的零场下第一电离阈的数值与采用其他方法所确定的文献值^{[1, 2]}相一致, 从而验证了该方法的可靠性.     

Effects of intermodal dispersion on short pulse propagation in multi-core fibers

The effects of intermodal dispersion on ultrashort optical pulse propagation through multi-core fibers are analyzed theoretically, which has been ignored in previous studies. A three-core fiber with collinear and triangular configuration and a four-core fiber are considered. We demonstrate with numerical examples that the intermodal dispersion can cause pulse breakup effect in multi-core fibers.     

First-principles study on the electronic structure and magnetism of layered oxyselenide La2Mn2Se2O3

The electronic structure and magnetism of layered oxyselenide La(2)Mn(2)Se(2)O(3) have been studied by using first-principles calculations within the generalized gradient approximation (GGA) and GGA + U methods. The G-type antiferromagnetic (AF) state is calculated to be the most stable phase among the various magnetic configurations of interest, irrespective of the choice of the functional used, which is in good agreement with the experiments. In contrast to La(2)Fe(2)Se(2)O(3) and La(2)Co(2)Se(2)O(3), in which the AF states show metallic behavior under the GGA method, we predict the ground state of La(2)Mn(2)Se(2)O(3) is a semiconductor with an indirect band gap of ～0.52 eV via the GGA calculations. This is closely related to a closed shell configuration and large exchange splitting (～3.5 eV) in the Mn 3d states. Moreover, the magnetic properties are also discussed in terms of the calculated Heisenberg spin exchange constants, suggesting that La(2)Mn(2)Se(2)O(3) is a strong two-dimensional magnetically frustrated system.     

Biomimetic compound eye with a high numerical aperture and anti-reflective nanostructures on curved surfaces

Biomimetic compound eyes with a high numerical aperture on a curved surface were successfully fabricated by intelligent integration of traditional top-down and bottom-up micro- and nanofabrication methods together. In addition, the new hybrid micro- and nanofabrication method allows us to fabricate the antireflective nanostructures on each ommatidium to increase its vision sensitivity by improving the light transmission. The fabricated compound eye was optically characterized and was shown to have a numerical aperture of 0.77 for each ommatidium. Furthermore, it is shown that the transmission of the compound eye can be improved by 2.3% for the wavelength of 632.8 nm and a clearer image can be formed by the fabricated compound eye with antireflective nanostructures compared with that without antireflective nanostructures. In addition, the developed hybrid manufacturing method can be adapted to the fabrication of other complex micro- and nanodevices for photonics or other research areas.     

High-power ultraviolet 278 nm laser from fourth-harmonic generation of a Nd:YAG laser in CsB3O5

We demonstrate a high-power UV 278 nm laser by fourth-harmonic generation (FHG) of a 1112 nm Nd:YAG laser in a nonlinear optical (NLO) crystal CsB3O5 (CBO) for the first time, to our best knowledge. A 30 W level diode-pumped Q-switched Nd:YAG laser at 1112 nm with beam quality factor M2=1.2 was used as the fundamental light source at a pulse width of 500 ns. With an LiB3O5 crystal, the 1112 nm laser was first frequency-doubled to 556 nm with an average output power of 13.5 W. It was then frequency doubled again in a CBO crystal to obtain the FHG output at 278 nm. The maximum average output power of the 278 nm laser is up to 1.5 W. The results demonstrated that CBO crystal is a promising NLO material for UV high-power lasers below 300 nm.     

制冷系统的广义预测控制方法研究

制冷系统的蒸发器过热度的控制对于制冷系统稳定、高效运行具有重要作用。文中通过实验辨识了基于过热度和蒸发温度的制冷系统多输入多输出模型,并采用广义模型预测控制方法,针对制冷系统的变负荷运行工况下进行了实验研究。结果表明,该方法很好的适应了制冷系统变过热度、变蒸发温度的控制要求,相比常规的单输入单输出PID控制,跟踪性能良好、动态控制精度高,可以适应制冷系统负荷大范围变动的控制需求。     

增压输送过程中卧式贮罐液氢温度分层研究

分析了大型卧式液氢贮罐增压输出过程中低温介质传热数学模型,揭示了贮罐内液氢温度分布规律,说明了液氢温度分层形成的原因及过程,给出了输出液氢品质保障方法。研究表明:大型卧式液氢贮罐输出过程中液氢温度分布可用修正后的半无限大平板非稳态导热方程描述;在增压压力一定情况下,热液层厚度随着输送时间的增加而增大,且热液层厚度及其温度分布受卧式贮罐截面形状影响;液氢贮罐输出品质与贮罐内热液层厚度密切相关,可通过计算热液层厚度从而确定贮罐留底余量的方法,保证贮罐输出品质。     

用于诊断纳秒脉冲电流的微分环现场标定技术

分析了用于纳秒脉冲电流测量的微分环标定难点,提出微分环现场标定方法。通过脉冲形成线脉冲充电以解决微分环标定中信噪比较低、可信度较差等问题;分析了脉冲形成线充电时间、充电电压及脉冲形成开关击穿电压等回路参数对标定结果的影响。基于闪光二号加速器,对测量二极管电流的微分环进行了现场标定,前级隔离开关平均击穿电压为25 kV时,微分环标定回路电流达到1.3 kA,微分环灵敏度为9.311010,方差为0.151010。     

基于LabVIEW的高功率微波驱动源监控系统

针对高功率微波源对前级驱动电源的计算机自动控制要求,设计了一套1 200 kV高功率微波驱动电源监控系统。系统采用多功能数据采集卡控制大功率调压器产生连续可调的工频电压,再经过环氧高压变压器和整流硅堆等转换为直流高压,对储能电容进行充电控制;采用高速数据输入输出卡控制触发系统按时序进行工作;监测计算机通过RS-485串口方式对直流高压、闸流管阳极电压、闸流管对地电流等进行实时状态监测;控制主机通过以太网与中央控制计算机实现通讯,可以单独控制电源工作,也可以通过中央计算机统一协调工作;采用LabVIEW作为软件开发平台,利用图形控件完成整个电源系统的控制监测等功能的设计;为了解决因电磁干扰强而引起的地电位抬高、高压采集不正常等问题,系统的软硬件都融入了可靠性设计。实验结果表明,该系统工作可靠稳定,实时性强,界面友好,操作简单,具有良好的可扩展性和移植性。