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61.
A novel method for the determination of proteins in aqueous solutions has been developed based on the enhancement of resonance light scattering (RLS) of Ag nanoparticles in the presence of proteins. Factors including acidity of the media, concentration of Ag hydrosol, reaction time, temperature, and interference of non-protein substances were investigated. Under the optimal conditions, with the enhanced RLS signals at 452nm, the linear ranges of calibration curves were 0–0.8µgmL–1 for bovine serum albumin (BSA), 0–1.2µgmL–1 for human serum albumin (HSA), and 0–2.5µgmL–1 for human -IgG (-IgG), respectively. The detection limits were 1.3ngmL–1 for BSA, 10ngmL–1 for HAS, and 5.7ngmL–1 for -IgG.This method has been applied to the analysis of synthetic samples and real human serum samples, and the results were in good agreement with those reported by the hospital, indicating that the method presented here is not only sensitive and simple, but also reliable and suitable for practical applications. 相似文献
62.
Qiang Xu Prof. Dr. Nobuko Tsumori Prof. Dr. Ling Jiang Masanobu Kondo Ryuichi Arakawa Prof. Dr. 《化学:亚洲杂志》2007,2(5):599-608
Carbonyldinitrosyltris(fluorosulfato)tungstate(II) and ‐molybdate‐(II) anions, [fac‐M(CO)(NO)2(SO3F)3]? (M=W, Mo), which are novel weakly coordinating anions that contain a metal carbonyl/nitrosyl moiety, have been generated in fluorosulfonic acid and completely characterized by multinuclear NMR, IR, and Raman spectroscopy as well as ESI mass spectrometry. ESI MS measurements performed for the first time on a superacidic solution system unambiguously reveal the formation of the monoanionic, mononuclear W and Mo complexes formulated as [M(CO)(NO)2(SO3F)3]? (M=W, Mo). Multinuclear NMR spectroscopic studies at natural abundance and 13C and 15N enrichment clearly indicate the presence of one CO ligand, two equivalent NO ligands, and two types of nonequivalent SO3F? groups in a 2:1 ratio. The IR and Raman spectra reveal that the two equivalent NO ligands have a cis conformation, thus indicating a fac structure. Density functional calculations at the B3LYP level of theory predict that these anions have a singlet ground state (1A′) with a Cs symmetry along with C–O and N–O vibrational frequencies that are in agreement with the experimental observations. Mulliken population analysis shows that the monovalent negative charge is dispersed on the bulky sphere, the surface of which is covered by all the negatively charged O and F atoms with charge densities much lower than SO3F?, suggesting that [fac‐M(CO)(NO)2(SO3F)3]? (M=W, Mo) are weakly nucleophilic and poorly coordinating anions. 相似文献
63.
O. Reuter R. Langley Dr. Wan Manshol Bin W. Zn 《Radiation Physics and Chemistry》1998,52(1-6):429-432
This paper presents anew design concept for a gamma irradiation plant for the continuous processing of pumpable liquids. Typical applications of such a plant include
- • * the irradiation vulcanisation of natural latex rubber
- • * disinfection of municipal sewage sludge for agricultural use
- • * sterilisation of liquids in the pharmaceutical and cosmetics industries
- • * industrial processing of bulk liquids
The authors describe the design and operation of the latex irradiator now operating on a small production scale in Malaysia and proposed developments.
The design allows irradiation processing to be carried out under an inert or other gaseous environment.
State-of-the-art computer control system ensures the fully automatic processing operation needed by industrial computers. 相似文献
64.
Prof. Dr. H. G. Kilian 《Colloid and polymer science》1977,255(8):740-754
Summary A thermodynamic treatment of homo-polymer systems out of linear chains with folded chain crystals is developed outgoing from appropriate models for single component systems. An expansion of thermodynamics to multi-micro-phase systems the structure of which is partially or totaly frozen is indispensable. General properties of melt crystallized homopolymers with folded chain crystals can be recognized indeed when the thermodynamic formalisms developed are applied.
Notation g c (y);g m (Y) molar Gibbs-free energy of a chain of a lengthy within an extended chain crystal and the melt rsp - g o c ;g o m molar free enthalpy of the unit in the crystal lattice and the melt rsp - g(y,y, f) molar Gibbs-function of an ideally folded chain crystal with the fold heighty f - gco(y, y ef,y f) molar free enthalpy of the crystal corey co - g 0 ex ((yef) excess free enthalpy of the longitudinal layers of folded chain crystals - g f(yef,g o ex ) molar free enthalpy of the longitudinal layers of the folded chain crystals - g tot molar free enthalpy of a chain of the lengthy within a folded chain crystal with longitudinal layers - h o 1c ,h o m molar enthalpy of the chain unit within the crystal lattice and the melt rsp - h =h o m -h o c molar heat of fusion of the unit - C p=C p m -C p c difference of the molar specific heat of a unit within the melt and within the chain crystal - h D molar defect enthalpy of local defects within the crystal lattice - h D molar defect enthalpy of the unit - s o c ,s o m molar entropy of the chain unit within the crystal lattice and the melt rsp - s c m conformational entropy of a chain in the melt - s gk conformational entropy of a chain of lengthy within a super-lattice as indicated in figure 5, - s molar entropy of fusion of the melt - s n c nematic configurational entropy - T absolute temperature - T M melting temperature of extended chain crystals of infinite size - T M(y) melting temperature of extended chain crystals containing only chains of the lengthy - T M (y, y f) melting temperatureof folded chain crystals of the thicknessy f composed of chains of the lengthy - T M(y f) melting temperature of folded chain crystals of the thicknessy fy - eh excess free enthalpy of the chain ends occupying crystallographic places - ef excess free enthalpy of a single fold loop - z coordination number of the lattice - 7 Euler's constant - R Boltzmann's constant - y number of chain units - y f height of lamelliform folded chain crystals - f=(y/y f - 1) number of fold loops of a chain of a lengthy when being built into a folded chain crystal of the thicknessy f - y co thickness of the crystal core of the simplified twophase model - y et average thickness of the surface layers of folded chain crystals - N c number of crystallized units of a chain of the lengthy - x c molar number of crystallized units of a chain of the lengthy - x nc molar number of noncrystallized units - excess free enthalpy parameter - (y f) thickness distribution of the fold heightsy f With 15 figures and 2 tables 相似文献
Zusammenfassung Das Schmelzen in polymeren Einteilchensystemen mit Faltungskristallen einheitlicher Dicke kann thermodynamisch als Umwandlung 1. Ordnung in einer Richtung behandelt werden, wenn die Faltungslänge bis zur Umwandlungstemperatur konstant bleibt (Faltungslänge als innerer Zusatzparameter). Eine wesentliche begriffliche Erweiterung ist für eine phänomenologische Beschreibung mit den Mitteln der Thermodynamik unumgänglich, wenn eine Faltungskristallit-Dickenverteilung existiert, weil dann prinzipiell nur noch partielle Koexistenz bestimmter Fraktionen metastabiler autonomer Mikrophasen mit der Schmelze möglich ist. Partielles Aufschmelzen und Rektistallisation können so dann auch in Betracht genommen werden. Die entwickelten Konzeptionen bewähren sich in der Anwendung auf bekannte Experimente.
Notation g c (y);g m (Y) molar Gibbs-free energy of a chain of a lengthy within an extended chain crystal and the melt rsp - g o c ;g o m molar free enthalpy of the unit in the crystal lattice and the melt rsp - g(y,y, f) molar Gibbs-function of an ideally folded chain crystal with the fold heighty f - gco(y, y ef,y f) molar free enthalpy of the crystal corey co - g 0 ex ((yef) excess free enthalpy of the longitudinal layers of folded chain crystals - g f(yef,g o ex ) molar free enthalpy of the longitudinal layers of the folded chain crystals - g tot molar free enthalpy of a chain of the lengthy within a folded chain crystal with longitudinal layers - h o 1c ,h o m molar enthalpy of the chain unit within the crystal lattice and the melt rsp - h =h o m -h o c molar heat of fusion of the unit - C p=C p m -C p c difference of the molar specific heat of a unit within the melt and within the chain crystal - h D molar defect enthalpy of local defects within the crystal lattice - h D molar defect enthalpy of the unit - s o c ,s o m molar entropy of the chain unit within the crystal lattice and the melt rsp - s c m conformational entropy of a chain in the melt - s gk conformational entropy of a chain of lengthy within a super-lattice as indicated in figure 5, - s molar entropy of fusion of the melt - s n c nematic configurational entropy - T absolute temperature - T M melting temperature of extended chain crystals of infinite size - T M(y) melting temperature of extended chain crystals containing only chains of the lengthy - T M (y, y f) melting temperatureof folded chain crystals of the thicknessy f composed of chains of the lengthy - T M(y f) melting temperature of folded chain crystals of the thicknessy fy - eh excess free enthalpy of the chain ends occupying crystallographic places - ef excess free enthalpy of a single fold loop - z coordination number of the lattice - 7 Euler's constant - R Boltzmann's constant - y number of chain units - y f height of lamelliform folded chain crystals - f=(y/y f - 1) number of fold loops of a chain of a lengthy when being built into a folded chain crystal of the thicknessy f - y co thickness of the crystal core of the simplified twophase model - y et average thickness of the surface layers of folded chain crystals - N c number of crystallized units of a chain of the lengthy - x c molar number of crystallized units of a chain of the lengthy - x nc molar number of noncrystallized units - excess free enthalpy parameter - (y f) thickness distribution of the fold heightsy f With 15 figures and 2 tables 相似文献
65.
Prof. Dr. G. Zigeuner W. Galatik W. -B. Lintschinger F. Wede 《Monatshefte für Chemie / Chemical Monthly》1975,106(5):1219-1233
The title compounds7 are formed in a general reaction by heating β-isothiocyanoketones3 with primary amines in inert solvents, or by thermal elimination of water from tetrahydro-6-hydroxy-6-methyl-2(1H)-pyrimidinethiones5, also in inert solvents. The 1-alkyl compounds can also be prepared under similar conditions from α,β-unsaturated ketones by reaction with alkylammonium rhodanides. The NMR-spectra show that the 1-substituted dihydro-6-methyl-2(1H)-pyrimidinethiones are in tautomeric equilibrium with the tetrahydro-6-methylene-2(1H)-pyrimidinethiones13. The reactivity of 1-alkyl and 1-aryldihydro-6-methyl-2(1H)-pyrimidinethiones is similar to that of dihydro-4,4,6-trimethyl-2(1H)-pyrimidinethione7 j, although their ring stability is certainly less. 相似文献
66.
Prof. Dr. E. Nachbaur A. Popitsch P. Burkert 《Monatshefte für Chemie / Chemical Monthly》1974,105(4):822-833
According to spectroscopic (IR, broadline proton NMR) and chemical (alkylation) investigations of disilver sulphamide the following molecular structure is assumed: $$\begin{gathered} O \hfill \\ || \hfill \\ H_2 N\_\_S\_\_NAg| \hfill \\ OAg \hfill \\ \end{gathered}$$ From the IR and NMR data deduction concerning the nature of the chemical bonds in this compound is possible. The instability of the still unknown mono-and trisilver sulphamide is discussed with regard to the structure of disilver sulphamide. 相似文献
67.
Prof. Dr. Maximilian Pöhm Harald Kolassa Kurt Jentzsch 《Monatshefte für Chemie / Chemical Monthly》1977,108(2):393-395
It is well known that in the ergot alkaloids of the peptide type the proline appears in thel-configuration. Different methods of acid hydrolysis may lead to various cleavage products; hydrolysis by HCl yieldsd-proline, on the other hand hydrolytic cleavage by means of strongly acid cation exchange resin preserved the orginall-configuration.
Teilveröffentlichung der Dissertation vonH. Kolassa, Univ. Wien, 1973. 相似文献
Teilveröffentlichung der Dissertation vonH. Kolassa, Univ. Wien, 1973. 相似文献
68.
Zusammenfassung Acenaphthylen wurde durch Anpolymerisation und zweifache Hochvakuumsublimation gereinigt. Die Reinigungsmethode wird ausführlich beschrieben.Bei verschiedenen Temperaturen wurde mit einer dilatometrischen Methode die thermische Bruttogeschwindigkeit gemessen. Zwischen 95 und 105 °C giltk
br=7,08·1010 exp (– 30,9 kcal/RT).Die beträchtliche Aktivierungsenergie der Bruttoreaktion ist sowohl auf eine große Aktivierungsenergie der thermischen Startreaktion als auch auf eine relativ hohe Wachstumsaktivierungsenergie zurückzuführen.Das Polymerisationsverhalten von Acenaphthylen kann vermutlich aufgrund seiner sterischen Eigenschaften erklärt werden.
Summary Acenaphthylene was purified by partial polymerisation, followed by double stage high vacuum sublimation. The method of purification is described in detail.The thermal overall rate was measured at different temperatures by a dilatometric method. Between 95 and 105 °C the following relation holds:k th=7,08 · 1010 exp (– 30,9 kcal/RT).The considerable energy of activation of the overall reaction depends on a relatively high energy of activation of both the thermal initiation and the propagation reaction.It is supposed, that the polymerisation behaviour of acenaphthylene depends mainly on its steric properties.相似文献
69.
Bin XIN Dan PU Shao Xiang XIONG* Guang Hui WANG Beijing Mass Spectrometry Center Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2003,14(2)
Recently, capillary electrophoresis/electrospray ionization mass spectrometry (CE/ESI- MS) has been rapidly developed as a powerful analytical tool for charged species ranged from small molecules such as carboxylic acids1, phenolic compounds2, metal species3, tetramines4, herbicides5, drugs and drug metabolites6 to peptides and proteins7, 8. The ESI mode has proven to be sensitive, versatile and relatively easy to use in combination with CE. CE confers rapid analysis and efficient separ… 相似文献
70.
Summary An electrical assembly for the oxygen-flask combustion of lubricants and similar petroleum products is described. The pyrolysis is performed in two consecutive steps. After the ignition and burning of the sample (sorbed on sodium carbonate) the combustion is completed by further heating. The sample weight should not exceed 140 mg. In this way the sensitivity of phosphorus determination of the tentative IP standard procedure is enhanced from 0.01 to 0.001% phosphorus if the volume of solution for the final spectrophotometric measurement is reduced.
Herrn Professor Dr. H. Lieb zum 90. Geburtstag gewidmet. 相似文献
Zusammenfassung Ein elektrisches Gerät für die Verbrennung von Schmierölen und ähnlichen Erdölprodukten im Schöniger-Kolben wurde beschrieben. Die Pyrolyse erfolgt in zwei aufeinander folgenden Schritten. Nach der Entflammung der an Natriumcarbonat adsorbierten Probe und nach Erlöschen der Flamme erfolgt die vollständige Verbrennung von Einwaagen, die 140 mg nicht überschreiten. So konnte die Empfindlichkeit der Phosphorbestimmung nach der tentativen IP-Standardmethode von 0,01% auf 0,001% Phosphor gesteigert werden, wenn man die spektrophotometrische Messung mit vermindertem Lösungsvolumen durchführt.
Herrn Professor Dr. H. Lieb zum 90. Geburtstag gewidmet. 相似文献