On the magnetic and crystallization behaviour of iron based amorphous alloys determined by nuclei quenched in

The tendency of boron-containing, iron-based glasses to show non monotonic changes of Curie Temperature (T _c ) and room temperature saturation magnetization (SM) was examined by magnetic measurements and Mossbauer spectroscopy. Depending on B/Fe ratio theT _c and SM first increased up to a maximum value and then steadily decreased, probably because of a shortrange ordering, due to the strong chemical interaction between iron and boron atoms, leading iron atoms in vicinity with Fe-atoms rather than another TM-atom. Finally, the phenomenon becomes analogous to the order-disorder phenomenon in crystalline alloys. An observed unusual crystallization behaviour, consisting of heterogeneous nucleation, was also ascribed to this ordering, which leads to the formation of associations, acting as the first nuclei of crystallization.     

Distribution of melamine in polyester–melamine surface coatings cured under nonisothermal conditions

The influence of experimental cure parameters on the diffusion of reactive species in polyester–melamine thermoset coatings during curing has been investigated with X‐ray photoelectron spectroscopy and attenuated total reflectance Fourier transform infrared. The diffusion of melamine plays a vital role in the curing process and, therefore, in the ultimate properties of coatings. At a low (<20%) hexamethoxymethylmelamine (HMMM) crosslinker concentration, the matrix composition is uniform, but at high HMMM concentrations, excess HMMM rapidly segregates to the air–coating interface. The rate of migration is governed by the difference in the surface free energies of polyester and HMMM and the concentration gradient of HMMM between the bulk and the surface. An increased rate of energy absorption also increases the rate of migration of HMMM to the surface. A physical model has been proposed to explain this surface segregation phenomenon in terms of cocondensation and self‐condensation reactions. It suggests that an appropriate amount of melamine can be segregated on the surface and allowed to self‐condense to form a desired thickness of a melamine topcoat through the control of the binder composition and cure conditions. This technique can be implemented to apply a melamine topcoat during cure. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 83–91, 2004     

RESTRICTION RESPECTUEUSE ET RECONSTRUCTION DES CHAINES ET DES RELATIONS INFINITES

We show a faithful restriction theorem among infinite chains which implies a reconstructibility conjecture of Halin. This incite us to study the reconstructibility in the sense of Fraïssé and to prove it for orders of cardinality infinite or ≥ 3 and for multirelations of cardinality infinite or ≥ 7, what improves the theory obtained by G. Lopez in the finite case. For this work we had to study the infinite classes of difference which have to be a linear order of type ω, ω* or ω* + ω; this complete the theory made by G. Lopez for the finite case ([13]). We show also Ulam-reconstructibility for linear orders which have a fixed point.     

The automatic conversion of spinor equations to dyad form in MAPLE

A new package in the symbolic algebra system MAPLE is presented for the conversion of complicated spinor equations to their expansions with respect to a normalized spinor dyad. By following a simple index convention, we obtain a powerful computational tool with a straightforward and easy to use syntax. A number of examples, including nontrivial applications of the package to recent research, are provided.     

Periodic solutions of second-order quasilinear hyperbolic equations

We study a periodic boundary-value problem for a quasilinear equation with the d'Alembert operator on the left-hand side and a nonlinear operator on the right-hand side and establish conditions under which the solution of the indicated problem is unique.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 47, No. 10, pp. 1370–1375, October, 1995.     

Smectic liquid-crystalline phases of F(CF2)7(CHOH)(CH2)8H and F(CF2)9(CHOH)(CH2)10H Comparison with other partially fluorinated molecules

Partially fluorinated alcohols F(CF₂)_m(CHOH)(CH₂)_nH (where m = 7, n = 8 and m = 9, n = 10) exhibit highly ordered smectic liquid-crystalline phases, as confirmed by optical microscopy and differential scanning calorimetry. Miscibility studies show that the smectic phases of the two alcohols are not of the same type. The related partially fluorinated ketones F(CF₂)_mCO(CH₂)_nH do not form a detectable mesophase. This is rather surprising since the (more polar) corresponding alcohols and the (less polar) analogous iodides and n-alkanes do. A brief discussion of the results and a comparison among partially fluorinated alkanes with various functional groups are presented.