全文获取类型
收费全文 | 104680篇 |
免费 | 23480篇 |
国内免费 | 4471篇 |
专业分类
化学 | 106900篇 |
晶体学 | 703篇 |
力学 | 4108篇 |
综合类 | 234篇 |
数学 | 8346篇 |
物理学 | 12340篇 |
出版年
2024年 | 511篇 |
2023年 | 4988篇 |
2022年 | 2360篇 |
2021年 | 3725篇 |
2020年 | 7000篇 |
2019年 | 5789篇 |
2018年 | 3483篇 |
2017年 | 1966篇 |
2016年 | 8580篇 |
2015年 | 8730篇 |
2014年 | 8427篇 |
2013年 | 9660篇 |
2012年 | 7328篇 |
2011年 | 5172篇 |
2010年 | 6965篇 |
2009年 | 6880篇 |
2008年 | 4833篇 |
2007年 | 3864篇 |
2006年 | 2907篇 |
2005年 | 2881篇 |
2004年 | 2389篇 |
2003年 | 2093篇 |
2002年 | 2750篇 |
2001年 | 2033篇 |
2000年 | 1816篇 |
1999年 | 931篇 |
1998年 | 556篇 |
1997年 | 554篇 |
1996年 | 573篇 |
1995年 | 568篇 |
1994年 | 482篇 |
1993年 | 589篇 |
1992年 | 448篇 |
1991年 | 371篇 |
1990年 | 298篇 |
1989年 | 275篇 |
1988年 | 303篇 |
1985年 | 264篇 |
1979年 | 264篇 |
1978年 | 259篇 |
1977年 | 366篇 |
1976年 | 432篇 |
1975年 | 511篇 |
1974年 | 542篇 |
1973年 | 368篇 |
1972年 | 476篇 |
1971年 | 430篇 |
1970年 | 638篇 |
1969年 | 471篇 |
1968年 | 504篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
231.
The mass spectra of the pyrrolidides of some long-chain carboxylic acids with alicyclic residues attached to their ω-end are discussed and compared with the spectra of the corresponding esters. Fragmentation triggered by the pyrrolidide group generates a series of peaks, which clearly exhibits the size and the structure of the carbon chain. 相似文献
232.
Dr. P. Thornton Greenland 《Theoretical chemistry accounts》1975,38(3):185-197
We give the continuum wave function solutions to the Schrödinger equation for an electron moving field of two point nuclei, as an expansion in terms of one centre Coulomb wave functions in a prolate elliptical coordinate system. These solutions may be chosen to have a convenient asymptotic behaviour, and tend to the conventional solutions of the Helmholtz equation in the limit that the nuclear charge goes to zero. In symmetric systems, where both nuclei have the same charge the angular wave functions are found to be identical with those occurring in the free case, and the expansion coefficients for the corresponding radial solutions are given for selected values of electron energy and nuclear separation.[/p] 相似文献
233.
Summary X-ray diffraction and electron microscopic results on several crystalline polymers which demonstrate elastic properties (polypropylene, Celcon®, poly-4-methyl-pentene) are reported. Photographic small angle X-ray diffraction techniques provided considerable qualitative information, concerning the morphological features of these elastic materials both as extruded, annealed and during extension. Lamellar thickness, thickness distribution and perfection of lamellae could be estimated. Lateral order features and orientation of the lamellar structures were obtainable from the sharpness and length of the equatorial wide angle diffraction arcs. Electron microscopic results essentially confirm the morphological features postulated on the basis of the X-ray results. These morphological features are discussed in terms of a general structural model which appears consistent with the mechanical properties of these materials.
Zusammenfassung Röntgenbeugung und elektronenmikroskopische Daten von einigen kristallinen Polymerprodukten mit elastischen Eigenschaften (Polypropylen, Celcon, Poly-4-methylpenten) werden berichtet. Die photographische Röntgen-Kleinwinkelmethode liefert wichtige qualitative Messungen der morphologischen Struktur dieser elastischen Materialien in den Zuständen sowohl wie hergestellt als auch nach Tempern und während des Dehnungsprozesses. Die Dicke der Lamellen, ihre Dikkenverteilung und die Güte der Lamellen konnten abgeschätzt werden. Die laterale Ordnung und die Orientierung der Lamellen kann aus Weitwinkelbeugungsdaten abgeleitet werden. Die Elektronenmikroskopie bestätigt die Morphologie, die aus Röntgendaten folgt. Ein allgemeines Strukturmodel dieser Morphologie, das im Einklang mit den mechanischen Eigenschaften dieser Produkte steht, wird diskutiert.相似文献
234.
Various levels of approximation (Hartree-Fock, configuration interaction and double-configuration Hartree-Fock method) are compared for extensive and limited exponent optimization of the atomic orbitals of the wavefunctions. The potential energy curves for the lowest-lying 1
u, 3
u, 1
g, 3
g states of the hydrogen molecule are presented. The shapes of the curves on the highest level of approximation, i.e. with the optimal double-configuration wavefunction, are basically in agreement with previous, more sophisticated and time-consuming work. The influence of the various approximations is also studied for several one-electron properties: charge distribution of the wavefunction along and perpendicular to the molecular axis, quadrupole moment and core attraction energy distribution. Differences arise to the work of Zemke et al. [1], who used a limited exponent optimization with a larger basis set, in the
g states where the orbitals are very diffuse. The differences concern magnitude and location of minima and maxima of potential curves, as well as considerable changes in one-electron properties which depend strongly on the spatial distribution of the orbitals.
On leave to: Institut für Theoretische Chemie, Universität Stuttgart.
On leave to: Office of Computing Activities, National Science Foundation, Washington, D.C. 相似文献
Zusammenfassung Verschiedene Approximationsstufen (Hartree-Fock, Konfigurationenwechselwirkung und Doppelkonfigurationen-Hartree-Fock-Methode) werden für ausgedehnte und begrenzte Exponentenoptimisierung von Atomorbitalen der Wellenfunktionen verglichen. Die Potentialkurven für die niedrigsten 1 u, 3 u, 1 g, 3 g Zustände des Wasserstoffmoleküls werden angegeben. Die Form der Kurven im Rahmen der besten Näherung, d. h. mit Doppelkonfiguration, stimmen im wesentlichen mit früheren aufwendigeren Rechnungen überein. Der Einfluß der verschiedenen Approximationen wird auch an einigen Einelektroneneigenschaften studiert: Ladungsverteilung der Wellenfunktion längs und senkrecht zur Molekülachse, Quadrupolmoment und Verteilung der Rumpfenergie. Unterschiede erscheinen zur Arbeit von Zemke et al. [1], die einen größeren Basissatz mit begrenzter Optimisierung verwandten, bei den g Zuständen, wo die -Orbitale sehr diffus sind. Die Unterschiede betreffen Größe und Lage der Minima und Maxima der Potentialkurven sowie beträchtliche Änderungen in solchen Einelektroneneigenschaften, die stark von der räumlichen Verteilung der Orbitale abhängen.
Résumé Comparaison de différents niveaux d'approximation (Hartree-Fock, interaction de configuration et Hartree-Fock à deux configurations) pour des optimisations étendues et limitées des orbitales atomiques de base. Calcul des courbes d'énergie potentielle pour les plus bas états 1 u, 3 u, 1 g, 3 g de la molécule d'hydrogène. Pour la fonction d'onde la plus raffinée: H.F. à deux configurations, la forme des courbes est en accord avec les résultats obtenus dans des travaux précédents plus complexes et plus coûteux. On étudie aussi l'influence des diverses approximations sur plusieurs propriétés monoélectroniques: distribution de charge le long de l'axe moléculaire et perpendiculairement à celui-ci, moment quadrupolaire et distribution de l'énergie d'attraction de coeur. On trouve des différences avec le travail de Zemke et al. (1), qui utilisent une plus grande base partiellement optimisée, pour les états g où les orbitales sont très diffuses. Les différences concernent la grandeur et la position des extrema des courbes de potentiel, ainsi que des variations importantes des propriétés monoélectroniques qui dépendent fortement de la distribution spatiale des orbitales.
On leave to: Institut für Theoretische Chemie, Universität Stuttgart.
On leave to: Office of Computing Activities, National Science Foundation, Washington, D.C. 相似文献
235.
Coupling of tris(trimethylsilyl)guanine (4) with 1,2-di--acetyl-3-chloromethyl glycerol (3), followed by removal of the protecting groups afforded 9-(2,3-dihydroxy-1-propoxy)guanine (1). Compound 1 exhibited potent antiviral activity. 相似文献
236.
Prof. Dr. B. Korte Prof. Dr. L. Lovász 《Mathematical Methods of Operations Research》1985,29(7):249-267
In previous papers many different classes and constructions of greedoids have been defined and studied. This paper documents inclusion relations among all subclasses of greedoids which are known so far. It will be shown that all inclusion relations are proper and that all but one subclasses of interval greedoids are distinct.
Supported by the joint research project Algorithmic Aspects of Combinatorial Optimization of the Hungarian Academy of Sciences (Magyar Tudományos Akadémia) and the German Research Association (Deutsche Forschungsgemeinschaft, SFB 21). Part of this research was done while the first author was visiting the Department of Combinatorics and Optimization, University of Waterloo. 相似文献
Zusammenfassung In früheren Arbeiten wurden viele verschiedene Klassen und Konstruktionen für Greedoide eingeführt und studiert. In dieser Arbeit werden alle bekannten Inklusionsbeziehungen zwischen Unterklassen von Greedoiden dokumentiert. Es wird gezeigt, daß alle Inklusionsbeziehungen echt und alle Unterklassen mit einer Ausnahme tatsächlich verschieden sind.
Supported by the joint research project Algorithmic Aspects of Combinatorial Optimization of the Hungarian Academy of Sciences (Magyar Tudományos Akadémia) and the German Research Association (Deutsche Forschungsgemeinschaft, SFB 21). Part of this research was done while the first author was visiting the Department of Combinatorics and Optimization, University of Waterloo. 相似文献
237.
M. E. Umstead S. A. Lloyd J. W. Fleming M. C. Lin 《Applied physics. B, Lasers and optics》1985,38(4):219-224
The reaction of NO2 with isobutane, induced by 488 nm laser radiation, to form 2-nitro-2-methylpropane has been investigated and the results computer-modeled according to two possible reaction mechanisms. The first scheme involves the direct abstraction of H from isobutane by vibronically excited NO2 (NO
2
*
), and the second, abstraction by an intermediate NO3 radial produced by NO
2
*
+NO2. The modeling results strongly support the NO
2
*
scheme as the dominant reaction mechanism. 相似文献
238.
G. Gritzner P. Rechberger Prof. Dr. Viktor Gutmann 《Monatshefte für Chemie / Chemical Monthly》1976,107(3):809-814
The influence of solvents on the redox behaviour of bistriphenylphosphinomercury perchlorate has been investigated by polarographic, voltammetric and potentiometric methods. The electrode process was found to be reversible in acetonitrile, propylene carbonate, N,N-dimethylformamide and dimethyl sulfoxide. An irreversible process was observed in nitromethane employing the dropping mercury electrode as well as in N,N-dimethylthioformamide and N-methyl-2-thiopyrrolidinone employing the rotating platinum electrode. Half wave potentials and diffusion coefficients have been measured. A linear relationship between theE
1/2 and the donor number (DN) of the solvent has been found for the reversible electrode reactions. Ligand replacement occurs in N,N-dimethylthioformamide and N-methyl-2-thiopyrrolidinone.
Mit 1 Abbildung 相似文献
Mit 1 Abbildung 相似文献
239.
Conjugated linoleic acids (CLA) have been a subject of extensive investigation for their anticarcinogenic, hypolipidemic, antiatherosclerotic and immune-enhancing activities. Stability of CLA in foods has not received much attention by both academics and industry. Although CLA has shown many beneficial effects, its decomposition must be prevented when CLA in foods is processed, stored and transported. However, no study to date has addressed the stability of CLA in foods. The present study was carried out further to examine the stability of CLA in egg yolk during the storage and frying, using gas liquid chromatography (GLC) and silver ion high-performance liquid chromatography (Agt-HPLC). The eggs, containing 4.0% CLA per gramme of egg yolk, were 40s. Either storage for 6 months or frying for 40 s did not significantly change the composition of CLA in egg yolk. However, the degradation of CLA was statistically significant when the CLA components of egg yolk protected CLA from degradation. It is concluded that CLA is well preserved in egg before it is consumed. 相似文献
240.
Zhong Lin Wang 《Microscopy and microanalysis》2004,10(1):158-166
Characterizing the physical properties of individual nanostructures is challenging because of the difficulty in manipulating the objects of sizes from nanometers to micrometers. Most nanomeasurements have been carried using scanning probe microscopy. In this article, we demonstrate that transmission electron microscopy can be a powerful tool for quantitative measurements of the mechanical and electrical properties of a single nanostructure. Dual-mode resonance of an oxide nanobelt has been observed, and its bending modulus has been measured. An in situ technique was demonstrated for measuring the work function at the tip of a carbon nanotube. The ballistic quantum conductance of a multiwalled carbon nanotube was observed at room temperature using the setup in TEM. It is concluded that in situ measurement by directly linking structure with property is a future direction of electron microscopy. 相似文献