Viscoelastic properties of amorphous polymers 3: low molecular weight poly(methylphenylsiloxane)

By making creep and recoverable creep measurements of a nearly monodisperse low molecular weight poly(methyl phenyl siloxane) sample, we have found on decreasing temperature towardsT _g that there is continuously a change in the viscoelastic spectrum concomitant with a decrease of the steadystate recoverable compliance. This behavior is exactly the same as previously observed in low molecular weight poly(styrene), proving that this spectacular anomaly in the viscoelasticity of low molecular weight polymers is general and deserves an explanation. Photon correlation spectroscopic measurements performed on the same sample have extended the observation of the viscoelastic response to shorter times and the result corroborates the trend of variation established by the creep data.Dedicated to Prof.Dr. E. W. Fischer on his 65th Birthday. Prof.Dr. Fischer is known for his valuable contribution to fosterine, international collaboration of research in polymer science. This work is an example of his contribution because it would not be possible without him bringing us together. One of us (KLN) would like to take this opportunity to thank Prof. Dr. Fischer for his unwaiving support of the 1st (Crete) and the 2nd (Alicante) International Discussion Meeting on Relaxations in Complex Systems     

Correlation of modified crack tip opening distance with heat input to the heat affected zone of high-strength low-alloy steels

Investigated is the dependency of the crack tip opening displacement (CTOD) on the local microstructure of the heat affected zone in high-strength low-alloy (HSLA) microalloyed steel. Since the initiation of the crack tip location could not be controlled in fatigue, any possible correlation between heat iput in welding and fracture toughness could be smeared. Modified CTOD data are defined; they show that the fracture resistance of the weld joint decreased as the heat input increased.     

On S-Normal Spaces and Pre GS-Closed Functions

In this paper the notion of pre gs-closed functions is introduced and investigated. Presemiclosed functions are pre gs-closed but not conversely. It is shown that s-normality is preserved under continuous pre gs-closed surjections.     

Structure and stability of 0° domain walls localized at defects in a (001)-crystal plate with combined anisotropy

An analysis is made of the conditions of formation and the stability region of static-soliton-type magnetic nonuniformities in a (001)-crystal plate with combined anisotropy. It is shown that if demagnetizing fields in the plate are taken into account, static solitons can localize at certain defects for appropriate parameters of the material. The soliton stability region was found to be bounded by two extreme values of the material parameters, namely, those at which the soliton is unstable against collapse and at which it expands. It was also found that the soliton stability region differs considerably from that predicted theoretically in the model disregarding the finite size of the sample and the presence of defects. Fiz. Tverd. Tela (St. Petersburg) 40, 1498–1502 (August 1998)     

Effect of phonon scattering from neutral and charged impurity centers on the lattice heat conductivity of PbTe:(Tl, Na)

Experimental data on the effect of thallium and sodium impurities on the lattice heat conductivity of PbTe at room temperature are reported. Because the lattice of lead chalcogenides is strongly polarized near charged impurities, the effect of impurities on the lattice heat conductivity depends substantially on their charge state. This property of the material has been used to determine the charge state of the thallium impurity in PbTe. The results obtained argue for a model of quasi-local thallium-impurity states which assumes low electron-correlation energy at an impurity center. Fiz. Tverd. Tela (St. Petersburg) 40, 1206–1208 (July 1998)     

Parameters for the inclined-path sensing of molecular hydrogen in the atmosphere by lidar with a YAG:Nd laser

The lidar equation for the vibrational backscattering of neodymium laser radiation and its harmonics by hydrogen molecules is solved numerically. Inclined paths in the atmosphere are investigated with the aim of selecting the transmitter wavelength for detecting the lowest concentrations of hydrogen. Zh. Tekh. Fiz. 68, 20–22 (January 1998)     

Electron as the eigenstate of curvilinear space with torsion

Ideas previously enunciated by the author about the physical interpretation of curvilinear space with torsion are developed. With the new equations describing the eigenstates of such a space, the static centrosymmetric solution for gravitational and electric fields can be made consistent with the Newton and Coulomb laws. The asymptotic behavior of the axisymmetric solution at infinity is studied. The gyromagnetic ratio obtained is characteristic of the electron. Ural State University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, p. 56–60, May, 1998.     

T1Effects in Sequential Dynamic Susceptibility Contrast Experiments

Residual effects of an initial bolus of gadolinium contrast agent have been previously demonstrated in sequential dynamic susceptibility contrast MR experiments. While these residual effects quickly reach a saturation steady state, their etiology is uncertain, and they can lead to spurious estimates of hemodynamic parameters in activation experiments. The possible influence ofT₁effects is now investigated with experiments in whichT₁weighting is varied as well as with serial regionalT₁measurements. Little evidence for significant residualT₁effects is found, suggesting instead that susceptibility effects underlie these observations. An initial saturation dose of contrast agent minimizes this effect.     

Electrostatic field of a thin, unclosed spherical shell and a torus

The electrostatic problem for a thin, unclosed spherical shell and a torus is reduced to paired summation equations in the Legendre polynomials by means of formulas relating the spherical and toroidal harmonic functions. The paired equations are transformed to a Fredholm integral equation of the second kind. Formulas are obtained for computing the charges of the conductors in the form of a series in a small parameter. The capacitance is computed for certain geometrical parameters of the conductors. Zh. Tekh. Fiz. 68, 1–6 (July 1998)     

Orthogonal modules and nonlinear cohomologies

Ordinary cohomologies in an algebra most often exhibit themselves either as objects that describe extensions (of algebras, groups, or modules) or as subjects hindering the existence of algebraic constructions. We introduce the notion of nonlinear cohomologies at a level of cochain complexes, furnish particular examples for Lie algebras, and give an interpretation of first nonlinear cohomologies in terms of “quasiextensions” of orthogonal modules. Translated fromAlgebra i Logika, Vol. 37, No. 5, pp. 522–541, September–October, 1998.