首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   270269篇
  免费   16831篇
  国内免费   786篇
化学   179957篇
晶体学   3456篇
力学   9661篇
综合类   7篇
数学   27180篇
物理学   67625篇
  2023年   4456篇
  2022年   2696篇
  2021年   4193篇
  2020年   6650篇
  2019年   4592篇
  2018年   5617篇
  2017年   3839篇
  2016年   9844篇
  2015年   7835篇
  2014年   8824篇
  2013年   14827篇
  2012年   10591篇
  2011年   10456篇
  2010年   9711篇
  2009年   9413篇
  2008年   9966篇
  2007年   9770篇
  2006年   8668篇
  2005年   7920篇
  2004年   6988篇
  2003年   6331篇
  2002年   6183篇
  2001年   6178篇
  2000年   4933篇
  1999年   3698篇
  1998年   3219篇
  1997年   3304篇
  1996年   3116篇
  1995年   2623篇
  1994年   2678篇
  1993年   2844篇
  1992年   2838篇
  1991年   2874篇
  1990年   2751篇
  1989年   2698篇
  1988年   2658篇
  1987年   2645篇
  1985年   3262篇
  1984年   3474篇
  1983年   2780篇
  1982年   3093篇
  1981年   3007篇
  1980年   2763篇
  1979年   2968篇
  1978年   3121篇
  1977年   3154篇
  1976年   3148篇
  1975年   2998篇
  1974年   2979篇
  1973年   3044篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
102.
We show that, in dimensions equal or greater than three, classical strings do not join or split. This is part of a no-interaction theorem that is also proved. The quantum theory is considered.  相似文献   
103.
104.
Crystalline materials that are transparent in the vacuum UV spectral region and currently used have been reviewed. Transmission of crystals of solid solutions with the fluorite structure Ca1?x R xF2+x (R = Sc, Y, La, Yb, Lu) in the UV and vacuum UV spectral regions has been investigated. It is shown that application of different methods of purification of fluorides from some impurities can significantly improve the optical quality of fluoride multicomponent crystals in the short-wavelength spectral region.  相似文献   
105.
The semi‐iterative method (SIM) is applied to the hyper‐power (HP) iteration, and necessary and sufficient conditions are given for the convergence of the semi‐iterative–hyper‐power (SIM–HP) iteration. The root convergence rate is computed for both the HP and SIM–HP methods, and the quotient convergence rate is given for the HP iteration. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
106.
A mixed problem is considered for a system of partial differential equations modeling the process of adsorption dynamics. An existence and uniqueness theorem is proved for this problem, and the solution properties are investigated. The inverse problem is posed, involving the determination of the system coefficient given additional information about the solution. A uniqueness theorem is proved for the solution of the inverse problem.__________Translated from Prikladnaya Matematika i Informatika, No. 16, pp. 5 – 14, 2004.  相似文献   
107.
108.
A three-dimensional examination of blood vessels is provided using MR data from seven cases. The vascular surfaces are constructed with an algorithm that automatically follows the selected artery or vein and generates a projected three-dimensional gradient shaded image. Fast 3DFT pulse sequences were optimized to enhance the time-of-flight contrast of the intravascular region. By increasing the surface threshold value in a three-dimensional head study, the flesh of a patient's face was peeled away to demonstrate the superfacial temporal artery. Gated cardiac images show the great vessels and cardiac chambers. A three-dimensional view of the aorta shows an irregular surface in the vicinity of an adrenal tumor. 3D MR exams provide a non-invasive technique for assessing vascular morphology in a clinical setting.  相似文献   
109.
Calculations are performed, using a basis of two-center functions described previously, for excited states of the following three-and four-electron compounds: H2 , He2 +, He2, Li2 +2. High efficiency is demonstrated for the frozen ionic core approximation and the nonorthogonal orbital method in such calculations. For four-electron systems the practical feasibility of the frozen hybrid core approximation is demonstrated.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 53–56, August, 1987.  相似文献   
110.
Molecular electroactive monolayers have been produced from vinylferrocene (VFC) via light-assisted surface anchoring to H-terminated n- and p-Si(1 0 0) wafers prepared via wet chemistry, in a controlled atmosphere. The resulting Si-C bound hybrids have been characterized by means of XPS and AFM. Their performance as semiconductor functionalized electrodes and their surface composition have been followed by combining electrochemical and XPS measurements on the same samples, before and after use in an electrochemical cell. White-light photoactivated anchoring at short (1 h) exposure times has resulted in a mild route, with a very limited impact on the initial quality of the silicon substrate. In fact, the functionalized Si surface results negligibly oxidized, and the C/Fe atomic ratio is close to the value expected for the pure molecular species. The VFC/Si hybrids can be described as (η5-C5H5)Fe2+(η5-C5H4)-CH2-CH2-Si species, on the basis of XPS results. Electrochemical methods have been applied in order to investigate the role played by a robust, covalent Si-C anchoring mode towards substrate-molecule electronic communication, a crucial issue for a perspective development of molecular electronics devices. The response found from cyclic voltammograms for p-Si(1 0 0) functionalized electrodes, run in the dark and under illumination, has shown that the electron transfer is not limited by the number of charge carriers, confirming the occurrence of electron transfer via the Si valence band. The hybrids have shown a noticeable electrochemical stability and reversibility under cyclic voltammetry (cv), and the trend in peak current intensity vs. the scan rate was linear. The molecule-Si bond is preserved even after thousands of voltammetric cycles, although the surface coverage, evaluated from cv and XPS, decreases in the same sequence. An increasingly larger surface concentration of Fe3+ at the expenses of Fe2+ redox centers has been found at increasing number of cv’s, experimentally associated with the growth of silicon oxide. Surface SiO groups from deprotonated silanol termination, induced by the electrochemical treatments, are proposed as the associated counterions for the Fe3+ species. They could be responsible for the observed decrease in the electron transfer rate constant with electrode ageing.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号