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91.
92.
A turnout switch machine is key equipment in a railway, and its fault condition has an enormous impact on the safety of train operation. Electrohydraulic switch machines are increasingly used in high-speed railways, and how to extract effective fault features from their working condition monitoring signal is a difficult problem. This paper focuses on the sectionalized feature extraction method of the oil pressure signal of the electrohydraulic switch machine and realizes the fault detection of the switch machine based on this method. First, the oil pressure signal is divided into three stages according to the working principle and action process of the switch machine, and multiple features of each stage are extracted. Then the max-relevance and min-redundancy (mRMR) algorithm is applied to select the effective features. Finally, the mini batch k-means method is used to achieve unsupervised fault diagnosis. Through experimental verification, this method can not only derive the best sectionalization mode and feature types of the oil pressure signal, but also achieve the fault diagnosis and the prediction of the status of the electrohydraulic switch machine. 相似文献
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95.
The optical properties of two-dimensional (2D) perovskites recently receive numerous research focus thanks to the strong quantum and dielectric confinement effects. In addition to the strong excitonic effect at room temperature, 2D perovskites also have appealing features that their optical properties can be flexibly tuned by alternating organic or inorganic layers. Particularly, 2D chiral perovskites and 2D perovskites based heterostructures are emerging as new platforms to extend their functionalities. To optimize performance of 2D perovskites-based optoelectronic devices, it is critical to understand the fundamentals and explore the strategies to engineer their optical properties. This review begins with an introduction to the excitons and self-trapped excitons of 2D perovskites. Subsequently, inorganic/organic layer effects on optical properties and 2D perovskites based heterostructures are discussed. We also discussed the nonlinear optical properties of 2D perovskite. We are looking forward to that this review can stimulate more efforts to understand and optimize the optical properties of 2D perovskites. 相似文献
96.
One series of two-ring and two series of three-ring mesogens with 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-heptadecafluorodecaoxy terminal chains containing tolane or biphenyl units have been synthesized. Their mesomorphic properties were observed and measured by optical polarizing microscopy and differential scanning calorimetry. The three-ring mesogens only exhibit a wide smectic C phase when the length of their hydrocarbon chains is intermediate. 相似文献
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98.
Experimental observations of dislocation decoration with self-interstitial atom (SIA) clusters and of SIA cluster rafts are analysed to establish the mechanisms controlling these phenomena in bcc metals. The elastic interaction between SIA clusters, and between clusters and dislocations is included in kinetic Monte Carlo (KMC) simulations of damage evolution in irradiated bcc metals. The results indicate that SIA clusters, which normally migrate by 1D glide, rotate due to their elastic interactions, and that this rotation is necessary to explain experimentally-observed dislocation decoration and raft formation in neutron-irradiated pure iron. The critical dose for raft formation in iron is shown to depend on the intrinsic glide/rotation characteristics of SIA clusters. The model is compared with experimental observations for the evolution of defect cluster densities (sessile SIA clusters and nano-voids), dislocation decoration characteristics and the conditions for raft formation. 相似文献
99.
A solid state metathesis (SSM) reaction was investigated with respect to the formation of rare‐earth carbodiimides, the role of the co‐produced salt (LiCl), and the eutectic flux medium (LiCl/KCl). A SSM reaction is characterized by an exothermic reaction in which a salt (often LiCl) is coproduced. When the salt melts, it can serve as a useful medium for the crystallization of a desired product. An improved crystal growth can be observed by using an eutectic flux. However, the composition of an eutectic LiCl/KCl flux is altered when LiCl is produced during the reaction. The thermal effects concerning the endothermic melting of the flux and the exothermic ingnition of the SSM reaction may compensate each other, which is not necessarily a drawback for the reaction to proceed. 相似文献
100.
Maurits Kuiper Manfred Speldrich Helmut Schilder Prof. Dr. Heiko Lueken 《无机化学与普通化学杂志》2012,638(10):1432-1436
Abstract. The magnetic behavior of the mononuclear nd1 systems MCp2Cl2 (M = V4+[3d1], Nb4+[4d1], Ta4+[5d1], space group P21/c, pseudosymmetry of the molecules C2v) deviates from pure single ion spin magnetism on account of ligand field effect (Hlf), spin‐orbit coupling (Hso), and intermolecular spin‐spin exchange interactions (Hex). For both VCp2Cl2 and NbCp2Cl2 excellent adaptations to the measured susceptibility data were obtained (2 K ≤ T ≤ 300 K) on the basis of spectroscopic data (lf, so) and cooperative metal–metal interactions (ex) of antiferromagnetic nature [molecular field model (mf)]. For TaCp2Cl2 experimental term structure data are not available. Therefore, Jørgensen's spectroscopical series (g‐factor of the central ion) was applied to extrapolate the data set for TaCp2Cl2. Hlf, Hso, and Hex (antiferromagnetic) increase in the order 3d1 → 4d1 → 5d1 leading, with rising atomic number of the metals, to a distinct enhancement of the magnetic anisotropy. At 4 K the μeff components μeff,y (oriented perpendicular to the cg–M–cg plane; “cg” = center of gravity of the Cp ring), μeff,z (oriented along the twofold pseudoaxis), and μeff,x are 1.73, 1.69, 1.68 (V), 1.73, 1.62, 1.59 (Nb), and 1.71, 1.59, 1.49 (Ta). While μeff,y is independent of T, both μeff,z and μeff,x decrease with decreasing T. 相似文献