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941.
Adducts of the conjugate addition of benzylamine to enantiopure amides of aroylacrylic acid possess high enantiomeric and diastereomeric purity. A high degree of stereoselectivity has been achieved by means of crystallization-induced asymmetric transformation. A practical synthesis leading to dipeptides containing homophenylalanine is depicted. 相似文献
942.
The orientational relaxation of optically induced anisotropy in rarefied gases and at a damped rotation has been investigated. It has been found that the anisotropy relaxation in rarefied gases is described by a reduced kinetic equation depending only on free rotation integrals. The behavior of the integral anisotropy of luminescence for free symmetric and asymmetric top molecules has been elucidated. The law of luminescence depolarization has been obtained for asymmetric top molecules in the Gordon J-diffusion model. It represents the sum of two Stern–Volmer-type dependences, whose relative contribution is determined by the orientation of the dipole moments of transitions with absorption and emission of light in the molecular coordinate system and by the principal moments of inertia of the molecular top. It has been established that in the limit of a strongly damped rotation, kinetic equations of the general form reduce to equations of rotational diffusion. A number of modified diffusion equations correctly describing the contribution of inertial effects to the orientational relaxation of anisotropy have been obtained. 相似文献
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S. N. Dorogovtsev A. V. Goltsev J. F. F. Mendes 《The European Physical Journal B - Condensed Matter and Complex Systems》2004,38(2):177-182
We consider the general p-state Potts model on random networks with a given degree distribution (random Bethe lattices). We find the effect of the suppression of a first order phase transition in this model when the degree distribution of the network is fat-tailed, that is, in more precise terms, when the second moment of the distribution diverges. In this situation the transition is continuous and of infinite order, and size effect is anomalously strong. In particular, in the case of p = 1, we arrive at the exact solution, which coincides with the known solution of the percolation problem on these networks.Received: 3 December 2003, Published online: 17 February 2004PACS:
05.10.-a Computational methods in statistical physics and nonlinear dynamics - 05.40.-a Fluctuation phenomena, random processes, noise, and Brownian motion - 05.50. + q Lattice theory and statistics (Ising, Potts, etc.) - 87.18.Sn Neural networks 相似文献
946.
P. Budrugeac J. M. Criado F. J. Gotor J. Malek L. A. Prez‐Maqueda E. Segal 《国际化学动力学杂志》2004,36(6):309-315
The isoconversional method suggested by Friedman and the invariant kinetic parameters method (IKP) were used in order to examine the kinetics of the nonisothermal crystallization of (GeS2)0.3(Sb2S3)0.7. The objective of the paper is to show the usefulness of the IKP method both for determining the activation parameters as well as the model of the investigated process. It was shown that the kinetic triplet [(E, A, f(α), where E is the activation energy, A is the preexponential factor, and f(α) is the differential function of conversion], which results through the application of the IKP method, depends on the set of kinetic models considered. For different sets of kinetic models, proportional values of f(α) are obtained. A criterion for the selection of this set, the use of which lead to the true kinetic triplet corresponding to the analyzed process (E = 163.2 kJ mol?1; A = 2.47 × 1012 min?1 and the Avrami‐Erofeev model, Am, for m = 2.5–2.6 was suggested. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 36: 309–315, 2004 相似文献
947.
In this paper, we present a new algorithm to estimate a regression function in a fixed design regression model, by piecewise
(standard and trigonometric) polynomials computed with an automatic choice of the knots of the subdivision and of the degrees
of the polynomials on each sub-interval. First we give the theoretical background underlying the method: the theoretical performances
of our penalized least-squares estimator are based on non-asymptotic evaluations of a mean-square type risk. Then we explain
how the algorithm is built and possibly accelerated (to face the case when the number of observations is great), how the penalty
term is chosen and why it contains some constants requiring an empirical calibration. Lastly, a comparison with some well-known
or recent wavelet methods is made: this brings out that our algorithm behaves in a very competitive way in term of denoising
and of compression. 相似文献
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A. Deptuła T. Olczak W. Łada B. Sartowska A.G. Chmielewski C. Alvani P.L. Carconi A. Di Bartolomeo F. Pierdominici S. Casadio 《Journal of Sol-Gel Science and Technology》2003,26(1-3):207-212
Microspheres of Li2TiO3 were fabricated by a classical, inorganic sol-gel process from commercially available TiCl4. Elaborated process consists of the following main steps: (1) dissolving of TiCl4 in concentrated aqueous HCl and addition of LiOH; (2) formation of sol emulsion in 2-ethylhexanol-1 containing the surfactant SPAN-80 (EH); (3) gelation of emulsion drops by extraction of water with partially dehydrated EH; (4) impregnation of gel to Li:Ti molar ratio MR = 2; (5) thermal treatment at 1200°C in order to receive chloride free product. This temperature can be significantly lowered (to 750°C) by dechlorination starting solution TiCl4 by chemical treatment of the with nitric acid to form of nitrate-stabilized titania sols. Tritium release from sol-gel made Li2TiO3 microspheres were found very close to that observed for other traditional materials, however for the first sample process starts slightly earlier. 相似文献