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891.
用恒定光电导法测量了纳米硅(其晶粒尺寸为3-5nm,晶态成分比Xc为45%—50%)薄膜在0.9—2.5eV范围的光吸收谱。分析了在不同光子能量范围可能存在的对光电导作主要贡献的几种光跃迁过程,以及随着Xc的增加,材料由非晶、微晶转变为纳米硅薄膜时光吸收谱的变化。发现纳米硅晶粒之间的界面区(平均厚度约为1nm)中载流子的跃迁及传输过程对整个范围的光吸收谱起主导作用。联系纳米硅的这种特殊结构解释了有关实验结果。
关键词: 相似文献
892.
The solid transitions of C21, C23 and C25
n-paraffins are examined from a piezothermal point of view. The paper is divided into two parts. The first is a report of the main features of a piezothermal analyzer when pressure scanning allows the continuous record of the expansivity as a function of pressure up to 5 Kilobars. Small samples are required and the scanning speeds vary from 0.3 to 16 Kilobars per hour. The second part describes the experimental procedure appropriate for solid state determinations. The resulting piezothermograms are presented and entropies of transformation are determined. A model allows a crude statistical approach giving the entropies of transformation with the correct order of magnitude. Problems related with phase transformations under a shearing stress are considered.
Zusammenfassung Feststoffumwandlungen bei C21, C23 und C25 n-Paraffinen wurden unter dem Gesichtspunkt der Piezowärme untersucht. Im ersten Teil vorliegender Arbeit werden die Haupteigenschaften eines piezothermischen Analysators beschrieben, bei dem durch Druck-Scanning die kontinuierliche Aufzeichnung des Ausdehnungsvermögens als Punktion des Druckes bis zu 5 kbar ermöglicht wird. Es werden nur kleine Proben benötigt, die Scanning-Geschwindigkeit variiert zwischen 0,3 und 16 kbar/h. Der zweite Teil beschreibt das geeignete experimentelle Verfahren zur Feststoffzustandsbestimmung. Die erhaltenen Piezothermogramme werden dargestellt und die Entropien der Umwandlung bestimmt. Ein Modell liefert eine grobe statistische Näherung, die die Entropien der Umwandlung in der richtigen Grö\enordnung liefert. Probleme in Zusammenhang mit Phasenumwandlungen bei Scherbeanspruchungen werden betrachtet.相似文献
893.
The reaction of CH3 with OH has been studied near 1200 K and 1 atmosphere pressure in shock tube experiments in which UV absorption was used to monitor [OH]. A rate coefficient of (1.1 ± 0.3) × 1013 cm3/mol-s was measured for removal of OH by CH3. This measured value is compared with previous experimental data and calculations. Several possible reaction channels are discussed, and although products were not monitored, it seems probable, on the basis of other work and theoretical estimates, that the primary mechanism (?75%) for the removal of OH by CH3 at these conditions is their combination to form CH3OH. Rate coefficients of (5.3 ± 0.8) × 1012 and (9.0 ± 1.4) × 1012 cm3/mol-s were measured for the reactions of OH with acetone and ethane, respectively, at the same temperature and pressure. 相似文献
894.
M. Ferro-Luzzi Z.-L. Zhou J.F.J. van den Brand H.J. Bulten J. Lang H.R. Poolman 《Hyperfine Interactions》1997,110(3-4):239-257
We present data showing hyperfine transitions in an atomic deuterium beam induced by the (476 MHz) radio-frequency field of
a 704 MeV electron beam in a storage ring. A polarized deuterium beam, produced in an atomic beam source, was crossed with
a stored electron beam and analyzed with a Breit--Rabi polarimeter. Electron-beam induced transitions were singled out by
injecting different combinations of hyperfine states. Transition probabilities as high as 70% were measured at large currents
(~ 100 mA). All possible deuterium transitions for a radio-frequency of 476 MHz were observed. In addition, a 1--6 transition
resulting from the first harmonic (952 MHz) was observed.
The effects of these transitions are of general importance for the polarized internal target technique applied in nuclear
and particle physics experiments. The data are reasonably described by numerical estimates. The observed mechanism can be
exploited to create nuclear polarized atoms when injecting electron polarized atoms with no net nuclear polarization into
a storage cell. However, when nuclear polarized atoms are injected, care should be taken to avoid this mechanism, since it
would result in depolarization of the atoms. The studies enabled us to choose the magnetic guide field during our spin-dependent
electron--deuteron scattering experiments, such that electron-beam induced depolarizing effects were avoided.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
895.
896.
897.
898.
G. M. Luke L. P. Le B. J. Sternlieb Y. J. Uemura J. H. Brewer R. Kadono R. F. Kiefl S. R. Kreitzman T. M. Riseman C. E. Stronach M. Davis S. Uchida H. Takagi Y. Tokura Y. Hidaka T. Murakami E. A. Early J. T. Markert M. B. Maple C. L. Seaman 《Hyperfine Interactions》1991,63(1-4):311-317
We report muon spin relaxation/rotation measurements on sintered powder samples of Nd2−x
Ce
x
CuO4−y
and a large single crystal of Nd2CuO4−y
. We find an electronic phase diagram which is quite similar to that of hole-doped superconductors such as La2−x
Sr
x
CuO4−y
, although the doping of electrons into the system is less efficient in destroying the static moments on the copper spins.
Static magnetic order in Nd2CuO4−y
appears below about 250 K, and two spin reorientations are seen atT=75 K andT=35 K. Measurements of the magnetic field penetration depth have been unsuccessful due to the rare-earth paramagnetism of
these materials. 相似文献
899.
G. Principi A. Maddalena Ajay Gupta R. Dal Maschio S. Diré 《Hyperfine Interactions》1992,69(1-4):619-622
Conversion electron Mössbauer spectroscopy (CEMS) has been used to study tin oxide films prepared by sol-gel dipping and sputtering. The spectra of films prepared by sol-gel route result close to that of crystalline SnO2 after heat treatment at a temperature as low as 150°C. The Mössbauer parameters of as sputter deposited films indicate that the structure of the deposited stannic oxide has an amorphous character more pronounced for thinner samples. The structure becomes predominantly that of crystalline SnO2 by heating at 550°C for 30 min provided the film thickness is higher than 10 nm. 相似文献
900.
Dr.-Ing. M. Millies Dipl.-Ing. St. v. Bose Dipl.-Ing. A. Tokarz Univ.-Prof.Dr.-Ing. D. Mewes 《Heat and Mass Transfer》1994,30(1):17-25
The common methods for calculating the mass transfer across liquid-liquid interfaces in technical applications take into account the mass transfer resistances within the bulk phases. The transfer resistance of the interface and a possible coupling between the momentum and the mass transport is not taken into account. In the present paper a survey is given of theoretical approaches which can describe this coupling and the additional mass transfer resistance. A theory is proposed by Hampe which can be used to explain the coupling between momentum and mass transport employing thermodynamics of irreversible processes. On the basis of this work, the influence of the dilatation of a flat interface on the mass transfer is deduced. It is also concluded from this theory that the diffusion coefficients within the bulk phases are coupled near the thermodynamic equilibrium. 相似文献