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1.
In quasi-steady operation, convection currents in a Bridgmandevice, used for producing a semi-conductor crystal, createinhomogeneities that may make the crystal unusable. It has oftenbeen suggested that additional forces due to rotation or magnetismmight be efficacious in reducing the segregation of the elementsof the alloy. It has been found that, over a wide range of rotationrates, there is no improvement in performance due to rotationabout the vertical axis. However, numerical results that havebeen obtained previously (Lee & Pearlstein, J. Crys. Growth240, 2002) indicate that, when effects of centrifugal buoyancyare introduced, a substantial reduction in segregation is achieved.In the work reported here, by contrast, in which we extend previouslarge-Rayleigh-number asymptotic analysis to include centrifugalbuoyancy, we find no improvement in radial segregation, butrather increasing segregation with increasing rotation rate. 相似文献
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S.D. Gopal Ram G. Ravi MR. Manikandan T. Mahalingam M. Anbu Kulandainathan 《Superlattices and Microstructures》2011,50(4):296-302
In the present work, a controlled growth of ZnO nanostructures by manipulating Zn metal ion concentration by the chelating action of ethylene diaminetetra acetic acid in hydrothermal method is studied. EDTA produces metal–chelate complex by the formation of bidentate ligand with Zn2+ in the solution and diminishes the reactivity of Zn metal cations. Concentration of EDTA in the mother solution was varied in different ranges like 3, 5 and 10 mM while retaining the zinc metal salt and the NaOH concentration the same. Three different morphologies of wurtzite structured ZnO nanostructures such as nanorods-bunch, separate/discrete uniformly sized hexagonal nanorods and tapered flower petals like shapes are achieved by 3, 5 and 10 mM strengths of EDTA, respectively. The medium concentration 5 mM of EDTA is found to have moderate control over producing ZnO nanostructures of uniform diameter and a high aspect (length to diameter) ratio. An array of vertically aligned free standing ZnO nanorods with uniform spacing is successfully achieved by the addition of 5 mM of EDTA in the mother solution and the same is studied for its fluorescence property at an excitation of 325 nm and it has exhibited a characteristic UV emission of ZnO around 383 nm. 相似文献
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Keith B. Dillon Judith A. K. Howard Philippa K. Monks Michael R. Probert Helena J. Shepherd 《Acta Crystallographica. Section C, Structural Chemistry》2011,67(4):m111-m114
The title compound, cis‐dichloridobis(triethylphosphane)platinum(II) chloroform monosolvate, [PtCl2(C6H15P)2]·CHCl3, has been obtained from ligand scrambling in the cis‐[PtCl2(Cyp2PCl)(PEt3)] (Cyp = cyclopentyl) system in CHCl3 solvent. Unlike the two previously reported unsolvated polymorphs, which are both monoclinic, the compound crystallizes in an orthorhombic setting. Furthermore, the system exhibits a reversible temperature‐dependent structural phase transition, coupling a reduction in anisotropic displacement parameters and a reduction in crystallographic symmetry on cooling. The high‐temperature phase adopts space group Pnma with the complex and solvent molecules sitting across a crystallographic mirror plane (Z′ = 0.5). The low‐temperature phase adopts the space group P212121 with Z′ = 1. 相似文献
4.
Akutsu H Akutsu-Sato A Turner SS Le Pevelen D Day P Laukhin V Klehe AK Singleton J Tocher DA Probert MR Howard JA 《Journal of the American Chemical Society》2002,124(42):12430-12431
Normal state conductivity and superconductivity together with bulk magnetic susceptibility and magnetization measurements have been measured for two molecular charge-transfer salts: beta' '-(ET)4[(H3O)Ga(C2O4)3]G (ET = bis(ethylenedithio)tetrathiafulvalene, G = pyridine for compound I and nitrobenzene for compound II). With the exception of the included guest molecules (G) the crystal structures are almost identical. Both show minima in their electrical transport at 130 K for I and at 160 K for II, but at lower temperatures their behaviors differ markedly. The resistance of I reaches a maximum at 50 K with a further small peak at 2 K and possible superconductivity only below 2 K, whereas that of II increases continuously down to 7.5 K, where an abrupt transition to a superconducting state occurs. 相似文献
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Locating Gases in Porous Materials: Cryogenic Loading of Fuel‐Related Gases Into a Sc‐based Metal–Organic Framework under Extreme Pressures 下载免费PDF全文
Jorge Sotelo Dr. Christopher H. Woodall Dr. Dave R. Allan Eugene Gregoryanz Dr. Ross T. Howie Konstantin V. Kamenev Dr. Michael R. Probert Prof. Paul A. Wright Dr. Stephen A. Moggach 《Angewandte Chemie (International ed. in English)》2015,54(45):13332-13336
An alternative approach to loading metal organic frameworks with gas molecules at high (kbar) pressures is reported. The technique, which uses liquefied gases as pressure transmitting media within a diamond anvil cell along with a single‐crystal of a porous metal–organic framework, is demonstrated to have considerable advantages over other gas‐loading methods when investigating host–guest interactions. Specifically, loading the metal–organic framework Sc2BDC3 with liquefied CO2 at 2 kbar reveals the presence of three adsorption sites, one previously unreported, and resolves previous inconsistencies between structural data and adsorption isotherms. A further study with supercritical CH4 at 3–25 kbar demonstrates hyperfilling of the Sc2BDC3 and two high‐pressure displacive and reversible phase transitions are induced as the filled MOF adapts to reduce the volume of the system. 相似文献
8.
Ahmed Waqar Chowdhury Z. Z. Kazi S. N. Johan MR. Akram Naveed Oon C. S. Abdelrazek Ali H. 《Journal of Thermal Analysis and Calorimetry》2021,144(4):1517-1534
Journal of Thermal Analysis and Calorimetry - In recent decades, the growth of heat transfer using nanomaterials in the conventional base fluid has caught the attention of researchers... 相似文献
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C. F. Doubleday D. E. Probert 《The Journal of the Operational Research Society》1985,36(12):1083-1093
This paper describes aspects of a project in which a computer model (I.C.D.M.) of the longer-term trends in demand for telecommunications media in the U.K. was developed and implemented. The work was undertaken by Cambridge University Engineering Department for the Long Range and Strategic Studies Division of British Telecom. The paper concentrates on the processes of developing and implementing the model as an aid in the formulation of robust investment and marketing strategies for British Telecom in the face of a rapidly changing technological environment and emergent competition. The value of the integrative and dynamic characteristics of the I.C.D.M. in this context is emphasized, and the role of a user-friendly colour graphics interface in encouraging managerial acceptance of the new tool is noted. 相似文献